REACTION   DYNAMICS   AND   MATERIALS   IN    EXTREME   ENVIRONMENTS

RDMEE

594.   S. Biswas, D. Paul, N. Dias, K. Kunzler, M. Ahmed, M. L. Pantoya, R. I. Kaiser, Stress-Alteration Enhancement of the Reactivity of Aluminum Nanoparticles in the Catalytic Decomposition of exo-Tetrahydrodicyclopentadiene (JP-10), J. Phys. Chem. A, 128, 3613−3624 (2024).   (PDF)   (Supplemental Information)   (Data Files)

593.   J. H. Marks, X. Bai, A. A. Nikolayev, Q. Gong, C. Zhu, N. F. Kleimeier, A. M. Turner, S. K. Singh, J. Wang, J. Yang, Y. Pan, T. Yang, A. M. Mebel, R. I. Kaiser, Methanetriol--Formation of an Impossible Molecule, J. Am. Chem. Soc., 146, 12174-12184 (2024).   (PDF)   (Supplemental Information)   (Data Files)

592.   G. L. Rizzo, S. Biswas, M. L. Pantoya, R. I. Kaiser, Unraveling the ignition chemistry of singly levitated aluminum iodate hexahydrate (AIH) particles, Chem. Phys. Lett., 842, 141212 (2024).   (PDF)   (Supplemental Information)   (Data Files)

591.   J. Wang, J. H. Marks, R. C. Fortenberry, R. I. Kaiser, Interstellar formation of glyceric acid [HOCH2CH(OH)COOH]—The simplest sugar acid, Sci. Adv., 10, eadl3236 (2024).   (PDF)   (Supplemental Information)   (Data Files)

590.   S. Biswas, D. Paul, N. Dias, W. Lu, M. Ahmed, M. L. Pantoya, R. I. Kaiser, Efficient Oxidative Decomposition of Jet-Fuel exo-Tetrahydrodicyclopentadiene (JP-10) by Aluminum Nanoparticles in a Catalytic Microreactor: An Online Vacuum Ultraviolet Photoionization Study, J. Phys. Chem. A, 128, 1665−1684 (2024).   (PDF)   (Supplemental Information)   (Data Files)

589.   I. A. Medvedkov, A. A. Nikolayev, Z. Yang, S. J. Goettl, A. M. Mebel, R. I. Kaiser, Elucidating the Chemical Dynamics of the Elementary Reactions of the 1-Propynyl Radical (CH3CC; X2A1) with 2-Methylpropene ((CH3)2CCH2; X1A1), Phys. Chem. Chem. Phys., 26, 6448–6457 (2024).   (PDF)   (Supplemental Information)   (Data Files)

588.   J. Wang, J. H. Marks, A. K. Eckhardt, R. I. Kaiser, Bottom-Up Formation of Antiaromatic Cyclobutadiene (c-C4H4) in Interstellar Ice Analogs, J. Phys. Chem. Lett., 15, 1211−1217 (2024).   (PDF)   (Supplemental Information)   (Data Files)

587.   S. J. Goettl, A. M. Turner, B.-J. Sun, A. H. H. Chang, P. Hemberger, R. I. Kaiser, Gas-Phase Preparation of the Dibenzo[e,l]pyrene (C24H14) Butterfly Molecule via a Phenyl Radical-Mediated Ring Annulation, Chem. Commun., 60, 1404-1407 (2024).   (PDF)   (Supplemental Information)   (Data Files)

586.   I. A. Medvedkov, A. A. Nikolayev, C. He, Z. Yang, A. M. Mebel, R. I. Kaiser, One Collision—Two Substituents: Gas-Phase Preparation of Xylenes under Single-Collision Conditions, Angew. Chem. Int. Ed., 63, e202315147 (2024).   (PDF)   (Supplemental Information)   (Data Files)

585.   S. Biswas, K. Fujioka, I. Antonov, G. L. Rizzo, S. D. Chambreau, S. Schneider, R. Sun, R. I. Kaiser, Hypergolic ionic liquids: to be or not to be?, Chem. Sci., 15, 1480−1487 (2024).   (PDF)   (Supplemental Information)   (Data Files)

584.   R. I. Kaiser, Unraveling the complex inventory of biorelevant organics in the plumes of icy moons, PNAS, 120, 52, e2319167120 (2023).   (PDF)  

583.   J. H. Marks, J. Wang, B.-J. Sun, M. McAnally, A. M. Turner, A. H.-H. Chang, R. I. Kaiser, Thermal Synthesis of Carbamic Acid and Its Dimer in Interstellar Ices: A Reservoir of Interstellar Amino Acids, ACS Cent. Sci., 9, 2171-2368 (2023).   (PDF)   (Supplemental Information)   (Data Files)

582.   S. Biswas, D. Paul, C. He, N. Dias, M. Ahmed, M. L. Pantoya, R. I. Kaiser, Counterintuitive Catalytic Reactivity of the Aluminum Oxide “Passivation” Shell of Aluminum Nanoparticles Facilitating the Thermal Decomposition of exo-Tetrahydrodicyclopentadiene (JP-10), J. Phys. Chem. Lett., 14, 9341−9350 (2023).   (PDF)   (Supplemental Information)   (Data Files)

581.   Z. Yang, I. A. Medvedkov, S. J. Goettl, R. I. Kaiser, Low-Temperature Gas-Phase Formation of Methanimine (CH2NH; X1A') – the Simplest Imine - under Single-Collision Conditions, J. Phys. Chem. Lett., 14, 8500-8506 (2023).   (PDF)   (Supplemental Information)   (Data Files)

580.   A. M Turner, J. H. Marks, J. T. Lechner, T. M. Klapotke, R. Sun, R. I. Kaiser, Ultraviolet-Initiated Decomposition of Solid 1,1-Diamino-2,2-dinitroethylene (FOX-7), J. Phys. Chem. A, 127, 37, 7707-7717 (2023).   (PDF)   (Supplemental Information)  

579.   W. Li, J. Yang, L. Zhao, D. Couch, M. S. Marchi, N. Hansen, A. N. Morozov, A. M. Mebel, R. I. Kaiser, Gas-Phase Preparation of Azulene (C10H8) and Naphthalene (C10H8) via the Reaction of the Resonantly Stabilized Fulvenallenyl (C7H5) and Propargyl (C3H3) Radicals, Chem. Sci., 14, 9795-9805 (2023).   (PDF)   (Supplemental Information)  

578.   Z. Yang, G. R. Galimova, C. He, S. J. Goettl, D. Paul, W. Lu, M. Ahmed, A. M. Mebel, X. Li, R. I. Kaiser, Gas-Phase Formation of the Resonantly Stablized 1-Indenyl (C9H7) Radical in the Interstellar Medium, Science Advances, 9, eadi5060 (2023).   (PDF)   (Supplemental Information)   (Data Files)

577.   J. Marks, A. A. Nikolayev, M. M. Evseev, J. Wang, A. M. Turner, N. F. Kleimeier, O. V. Kuznetsov, M. McAnally, A. N. Morozov, I. O. Antonov, A. M. Mebel, R. I. Kaiser, Quantum-Tunneling-Mediated Synthesis of Prebiotic Chelation Agents in Interstellar Analog Ices, Chem, 9, 1-18 (2023).   (PDF)   (Supplemental Information)   (Data Files)

576.   C. Zhang, J. Wang, A. M. Turner, J. H. Marks, S. Chandra, R. C. Fortenberry, R. I. Kaiser, On the Formation of Vinylamine (C2H3NH2) in Interstellar Ice Analogs , Astrophys. J., 952, 132 (2023).   (PDF)   (Supplemental Information)   (Data Files)

575.   I. A. Medvedkov, A. A. Nikolayev, C. He, Z. Yang, A. M. Mebel, R. I. Kaiser, A combined experimental and computational study on the reaction dynamics of the 1-propynyl (CH3CC, X2A1) – propylene (CH3CHCH2, X2A′) system: formation of 1,3-dimethylvinylacetylene (CH3CCCHCHCH3, X1A′) under single collision conditions, Molecular Physics, e2234509 (2023).   (PDF)   (Supplemental Information)   (Data Files)

574.   S. J. Goettl, Z. Yang, S. Kollotzek, D. Paul, R. I. Kaiser, A. Somani, A. Portela-Gonzalez, W. Sander, A. A. Nikolayev, V. N. Azyazov, A. M. Mebel, Exploring the Chemical Dynamics of Phenylethynyl Radical (C6H5CC; X2A1) Reactions with Allene (H2CCCH2; X1A1) and Methylacetylene (CH3CCH; X1A1), J. Phys. Chem. A, 127, 5723-5733 (2023).   (PDF)   (Supplemental Information)   (Data Files)

573.   S. J. Goettl, L. B. Tuli, A. M. Turner, Y. Reyes, A. H. Howlader, S. F. Wnuk, P. Hemberger, A. M. Mebel, R. I. Kaiser, Gas-Phase Synthesis of Coronene through Stepwise Directed Ring Annulation, J. Am. Chem. Soc., 145, 15443-15455 (2023).   (PDF)   (Supplemental Information)   (Data Files)

572.   J. Wang, A. A. Nikolayev, C. Zhang, J. H. Marks, V. N. Azyazov, A. K. Eckhardt, A. M. Mebel, R. I. Kaiser, Synthesis of interstellar propen-2-ol (CH3C(OH)CH2) – the simplest enol tautomer of a ketone, Phys. Chem. Chem. Phys., 25, 17460 (2023).   (PDF)   (Supplemental Information)   (Data Files)

571.   J. Wang, A. A. Nikolayev, J. H. Marks, M. Mcanally, V. N. Azyazov, A. K. Eckhardt, A. M. Mebel, R. I. Kaiser, Quantum Tunneling Mediated Low-Temperature Synthesis of Interstellar Hemiacetals, J. Phys. Chem. Lett., 14, 6078−6085 (2023).   (PDF)   (Supplemental Information)   (Data Files)

570.   C. Zhang, C. Zhu, A. M. Turner, I. O. Antonov, A. D. Garcia, C. Meinert, L. A. Young, D. C. Jewitt, and R. I. Kaiser, Processing of methane and acetylene ices by galactic cosmic rays and implications to the color diversity of Kuiper Belt object, Sci. Adv., 9 (22), eadg6936 (2023).   (PDF)   (Supplemental Information)   (Data Files)

569.   C. He, R. I. Kaiser, W. Lu, M. Ahmed, V. S. Krasnoukhov, P. S. Pivovarov, M. V. Zagidullin, V. N. Azyazov, A. N. Morozov, A. M. Mebel, Unconventional Gas-Phase Preparation of the Prototype Polycyclic Aromatic Hydrocarbon Naphthalene (C10H8) via the Reaction of Benzyl (C7H7) and Propargyl (C3H3) Radicals Coupled with Hydrogen-Atom Assisted Isomerization, Chem. Sci., 14, 5369-5378 (2023).   (PDF)   (Supplemental Information)  (Data Files)  

568.   A. M. Turner, J. H. Marks, Y. Luo, J. T. Lechner, T. M. Klapotke, R. Sun, R. I. Kaiser, Electron-Induced Decomposition of Solid 1,1-Diamino-2,2-dinitroethylene (FOX-7) at Cryogenic Temperatures, J. Phys. Chem. A, 127, 3390-3401 (2023).   (PDF)   (Supplemental Information)   (Data Files)

567.   G. L. Rizzo, S. Biswas, I. Antonov, K. K. Miller, M. L. Pantoya, R. I. Kaiser, Exotic Inverse Kinetic Isotopic Effect in the Thermal Decomposition of Levitated Aluminum Iodate Hexahydrate Particles, J. Phys. Chem. Lett., 14, 2722–2730 (2023).   (PDF)   (Supplemental Information)   (Data Files)

566.   A. M. Mebel, M. Agúndez, J. Cernicharo, R. I. Kaiser, Elucidating the Formation of Ethynylbutatrienylidene (HCCCHCCC; X1A') in the Taurus Molecular Cloud (TMC-1) via the Gas-Phase Reaction of Tricarbon (C3) with the Propargyl Radical (C3H3) Astrophys. J. Lett., 945, L40 (2023).   (PDF)  

565.   L. B. Tuli, S. J. Goettl, A. M. Turner, A. H. Howlader, P. Hemberger, S. F. Wnuk, T. Guo, A. M. Mebel, R. I. Kaiser, Gas Phase Synthesis of the C40 Nano Bowl C40H10 Nat. Commun., 14, 1527 (2023).   (PDF)   (Supplemental Information)   (Data Files)

564.   Z. Yang, S. Doddipatla, C. He, S. J. Goettl, R. I. Kaiser, A. W. Jasper, A. C. R. Gomes, B. R. L. Galvão, Can Third-Body Stabilisation of Bimolecular Collision Complexes in Cold Molecular Clouds Happen? Molecular Physics, e2134832 (2023).   (PDF)   (Supplemental Information)   (Data Files)

563.   J. Wang, J. H. Marks, A. M. Turner, A. M. Mebel, A. K. Eckhardt, R. I. Kaiser, Gas-Phase Detection of Oxirene, Sci. Adv., 9, eadg1134 (2023).   (PDF)   (Supplemental Information)   (Data Files

562.   D. Paul, B.-J. Sun, C. He, Z. Yang, S. J. Goettl, T. Yang, B.-Y. Zhang, A. H. H. Chang, R. I. Kaiser, Competing Si2CH4-H2 and SiCH2-SiH4 Channels in the Bimolecular Reaction of ground-State Atomic Carbon (C(3pj)) with Disilane (Si2H6, X1A1g) under Single Collision Conditions , J. Phys. Chem. A, 127, 1901-1908 (2023).   (PDF)   (Supplemental Information)   (Data Files)  

561.   S. Biswas, I. Antonov, K. Fujioka, G. L. Rizzo, S. D. Chambreau, S. Schneider, R. Sun, R. I. Kaiser, Unraveling the Initial Steps of the Ignition Chemistry of the Hypergolic Ionic Liquid 1-ethyl-3-methylimidazolium cyanoborohydride ([EMIM][CBH]) with Nitric Acid (HNO3) Exploiting Chirped Pulse Triggered Droplet Merging, Phys. Chem. Chem. Phys., 25, 6602-6625 (2023).   (PDF)   (Supplemental Information)   (Data Files)

560.   J. H. Marks, J. Wang, N. F Kleimeier, A. M. Turner, A. K. Eckhardt, R. I. Kaiser, Prebiotic Synthesis and Isomerization in Interstellar Analog Ice: Glycinal, Acetamide, and Their Enol Tautomers, Angew. Chem. Int. Ed. 62, e202218645 (2023).   (PDF)   (Supplemental Information)   (Data Files)

559.   C. Zhang, A. M. Turner, J. Wang, J. H. Marks, R. C. Fortenberry, R. I. Kaiser, Low-Temperature Thermal Formation of the Cyclic Methylphosphonic Acid Trimer [c-(CH3PO2)3], ChemPhysChem 24, e202200660 (2023).   (PDF)   (Supplemental Information)   (Data Files)

558.   C. He, R. I. Kaiser, W. Lu, M. Ahmed, Y. Reyes, S. F. Wnuk, A. M. Mebel, Exotic Reaction Dynamics in the Gas-Phase Preparation of Anthracene (C14H10) via Spiroaromatic Radical Transients in the Indenyl-cyclopentadienyl Radical-Radical Reaction, J. Am. Chem. Soc., 145, 3084-3091 (2023).   (PDF)   (Supplemental Information)  (Data Files)  

557.   C. He, R. I. Kaiser, W. Lu, M. Ahmed, P. S. Pivovarov, O. V. Kuznetsov, M. V. Zagidullin, A. M. Mebel, Unconventional Pathway in the Gas-Phase Synthesis of 9H-Fluorene (C13H10) via the Radical-Radical Reaction of Benzyl (C7H7) with Phenyl (C6H5), Angew. Chem. Int. Ed. 62, e202216972 (2023).   (PDF)   (Supplemental Information)   (Data Files)

556.   K. Fujioka, R. I. Kaiser, R. Sun, Unsupervised Reaction Pathways Search for the Oxidation of Hypergolic Ionic Liquids: 1‑Ethyl-3-methylimidazolium Cyanoborohydride (EMIM+/CBH) as a Case Study, J. Phys. Chem. A, 127, 913-923 (2023).   (PDF)   (Supplemental Information)  

555.   W. Li, L. Zhao, R. I. Kaiser, A Unified Reaction Network on the Formation of Five-Membered Ringed Polycyclic Aromatic Hydrocarbons (PAHs) and Their Role in Ring Expansion Processes Through Radical-Radical Reactions, Phys. Chem. Chem. Phys., 25, 4141-4150 (2023).   (PDF)   (Supplemental Information)  

554.   Z. Yang, B.-J. Sun, C. He, J.-Q Li, A. H. H. Chang, R. I. Kaiser, Gas-Phase Preparation of 1-Germavinylidene (H2CGe; X1A1) – the Isovalent Counterpart of Vinylidene (H2CC; X1A1) - via Non-Adiabatic Dynamics through the Elementary Reaction of Ground State Atomic Carbon (C; 3P) with Germane (GeH4; X1A1), J. Phys. Chem. Lett., 14, 430-436 (2023).   (PDF)   (Supplemental Information)   (Data Files)

553.   J. H. Marks, J. Wang, M. M. Evseev, O. V. Kuznetsov, I. O. Antonov, R. I. Kaiser, Complex Reactive Acids from Methanol and Carbon Dioxide Ice: Glycolic Acid (HOCH2COOH) and Carbonic Acid Monomethyl Ester (CH3OCOOH), Astrophys. J., 942, 43 (2023).   (PDF)   (Data Files

552.   J. Wang, J. H. Marks, A. M. Turner, A. A. Nikolayev, V. N. Azyazov, A. M. Mebel, R. I. Kaiser, Mechanistical study on the formation of hydroxyacetone (CH3COCH2OH), methyl acetate (CH3COOCH3), and 3-hydroxypropanal (HCOCH2CH2OH) along with their enol tautomers (prop-1-ene-1,2-diol (CH3C(OH)CHOH), prop-2-ene-1,2-diol (CH2C(OH)CH2OH), 1-methoxyethen-1-ol (CH3OC(OH)CH2) and prop-1-ene-1,3-diol (HOCH2CHCHOH)) in interstellar ice analogs, Phys. Chem. Chem. Phys., 25, 936-953 (2023).   (PDF)   (Supplemental Information)   (Data Files

551.   J. Wang, J. H. Marks, L. B. Tuli, A. M. Mebel, V. N. Azyazov, R. I. Kaiser, Formation of Thioformic Acid (HCOSH) – The Simplest Thioacid – in Interstellar Ice Analogues, J. Phys. Chem. A, 126, 9699−9708 (2022).   (PDF)   (Supplemental Information)   (Data Files

550.   S. K. Singh, N. F. Kleimeier, A. K. Eckhardt, R. I. Kaiser, A Mechanistic Study on the Formation of Acetone (CH3COCH3), Propanal (CH3CH2CHO), Propylene Oxide (c-CH3CHOCH2) along with Their Propenol Enols (CH3CHCHOH/CH3C(OH)CH2) in Interstellar Analog Ices, Astrophys. J., 941, 103 (2022).   (PDF)   (Data Files)

549.   J. H. Marks, J. Wang, R. C. Fortenberry, R. I. Kaiser, Preparation of methanediamine (CH2(NH2)2) - A precursor to nucleobases in the interstellar medium, PNAS, 119, e2217329119 (2022).   (PDF)   (Supplemental Information)   (Data Files)

548.   Z. Yang, G. R. Galimova, C. He, S. Doddipatla, A. M. Mebel, R. I. Kaiser, Gas Phase Formation of 1,3,5,7-Cyclooctatetraene (C8H8) through Ring Expansion via the Aromatic 1,3,5-Cyclooctatrien-7-yl Radical (C8H9) Transient , J. Am. Chem. Soc., 144, 22470-22478 (2022).   (PDF)   (Supplemental Information)   (Data Files)

547.   Y. Luo, C. Kang, R. I. Kaiser, R. Sun, The potential energy profile of the decomposition of 1,1-diamino-2,2-dinitroethylene (FOX-7) in the gas phase, Phys. Chem. Chem. Phys., 24, 26836-26847 (2022).   (PDF)   (Supplemental Information

546.   C. He, Z. Yang, S. Doddipatla, A. M. Thomas, R. I. Kaiser, G. R. Galimova, A. M. Mebel, K. Fujioka, R. Sun, Directed Gas Phase Preparation of Ethynylallene (H2CCCHCCH; X1A') via the Crossed Molecular Beam Reaction of the Methylidyne Radical (CH; X2Π) with Vinylacetylene (H2CCHCCH; X1A'), Phys. Chem. Chem. Phys., 24, 26499-26510 (2022).   (PDF)   (Supplemental Information)  (Data Files)  

545.   R. I. Kaiser, L. Zhao, W. Lu, M. Ahmed, M. M. Evseev, V. N. Azyazov, A. M. Mebel, R. K. Mohamed, F. R. Fischer, X. Li Gas-phase synthesis of racemic helicenes and their potential role in the enantiomeric enrichment of sugars and amino acids in meteorites†, Phys. Chem. Chem. Phys., 24, 25077-25087 (2022).   (PDF)   (Supplemental Information)    

544.   I. Antonov, A. Chyba, S. D. Perea, A. M. Turner, M. L. Pantoya, M. T. Finn, A. Epshteyn, R. I. Kaiser, Discovery of Discrete Stages in the Oxidation of exo-Tetrahydrodicyclopentadiene (C10H16) Droplets Doped with Titanium–Aluminum–Boron Reactive Mixed-Metal Nanopowder, J. Chem. Phys. Lett., 13, 9777-9785 (2022).   (PDF)   (Supplemental Information)   (Data Files)  

543.   D. Paul, Z. Yang, A. G. Suits, D. H. Parker, R. I. Kaiser, Photodissociation Dynamics of Xylene Isomers C6H4(CH3)2 at 157 nm using an Ultracompact Velocity Map Imaging Spectrometer – The C7H7 Channel., Chem. Phys. Lett., 807, 140064 (2022).   (PDF)   (Supplemental Information)   (Data Files)  

542.   R. C. Fortenberry, R. J. McMahon, R. I. Kaiser, 10 Years of the ACS PHYS Astrochemistry Subdivision, J. Phys. Chem. A, 126, 6571-6574 (2022).   (PDF)    

541.   G. Galimova, A. Mebel, S. J. Goettl, Z. Yang, R. I. Kaiser, A Crossed Molecular Beams and Computational Study on the Unusual Reactivity of Banana Bonds of Cyclopropane (c-C3H6; X1A1') Through Insertion by Ground State Carbon Atoms (C(3Pj)), Phys. Chem. Chem. Phys., 24, 22453-22463 (2022).   (PDF)   (Supplemental Information)   (Data Files)  

540.   D. Paul, Z. Yang, S. J. Goettl, A. M. Thomas, C. He, A. G. Suits, D. H. Parker, R. I. Kaiser, Photodissociation Dynamics of Astrophysically Relevent Propyl Derivatives (C3H7X; X = CN, OH, HCO) at 157 nm Exploiting an Ultracompact Velocity Map Imaging Spectrometer: The (Iso)Propyl Channel, J. Phys. Chem. A, 126, 5768-5775 (2022).   (PDF)   (Data Files)  

539.   C. He, Y. Luo, S. Doddipatla, Z. Yang, T. J. Millar, R. Sun, R. I. Kaiser, Gas-Phase Formation of Silicon Monoxide via Non-Adiabatic Reaction Dynamics and Its Role as a Building Block of Interstellar Silicates, Phys. Chem. Chem. Phys., 24, 19761-19772 (2022).   (PDF)   (Supplemental Information)  (Data Files)  

538.   C. Zhu, H. Wang, I. Medvedkov, J. Marks, M. Xu, J. Yang, T. Yang, Y. Pan, R. I. Kaiser, Exploitation of Synchrotron Radiation Photoionization Mass Spectrometry in the Analysis of Complex Organics in Interstellar Model Ices, J. Phys. Chem. Lett., 13, 6875-6882 (2022).   (PDF)   (Supplemental Information)  (Data Files)  

537.   A. M. Turner, Y. Luo, J. H. Marks, R. Sun, J. T. Lechner, T. M. Klapotke, R. I. Kaiser, Exploring the Photochemistry of Solid 1,1-Diamino-2,2-dinitroethylene (FOX-7) Spanning Simple Bond Ruptures, Nitro-to-Nitrite Isomerization, and Nonadiabatic Dynamics, J. Phys. Chem. A, 126, 29, 4747-4761 (2022).   (PDF)   (Supplemental Information)   (Data Files)  

536.   J. Cernicharo, R. Fuentetaja, M. Agundez, R. I. Kaiser, C. Cabezas, N. Marcelino, B. Tercero, J. R. Pardo, P. de Vicente, Discovery of fulvenallene in TMC-1 with the QUIJOTE line survey, Astron. Astrophys. 663, L9 (2022).   (PDF)  

535.   J. Wang, N. F. Kleimeier, R. N. Johnson, S. Gozem, M. J. Abplanalp, A. M. Turner, J. H. Marks, R. I. Kaiser, Photochemically triggered cheletropic formation of cyclopropenone (c-C3H2O) from carbon monoxide and electronically excited acetylene, Phys. Chem. Chem. Phys., 24, 17449–17461 (2022).   (PDF)   (Supplemental Information)   (Data Files

534.   S. V. Kalenskii, R. I. Kaiser, P. Bergman, A. O. H. Olofsson, K. D. Degtrarev, P. Golysheva, Spectral-line Survey of the Region of Massive Star Formation W51e1/e2 in the 4 mm Wavelength Range, Astrophys. J. 932, 5 (2022).   (PDF)  

533.   C. Zhang, C. Zhu, A. K. Eckhardt, R. I. Kaiser, Formation of the elusive tetrahedral P3N molecule, Science Advances, 8, eabo5792 (2022).   (PDF)   (Supplemental Information)   (Data Files)

532.   C. He, A. M. Thomas, B. B. Dangi, T. Yang, R. I. Kaiser, H.-C. Lee, B.-J. Sun, A. H. H. Chang, Formation of the Elusive Silylenemethyl Radical (HCSiH2; X2B2) via the Unimolecular Decomposition of Triplet Silaethylene (H2CSiH2; a3A''), J. Phys. Chem. A, 126, 3347-3357 (2022).   (PDF)   (Supplemental Information)   (Data Files)  

531.   C. He, S. J. Goettl, Z. Yang, R. I. Kaiser, A. A. Nikolayev, V. N. Azyazov, A. M. Mebel, Gas-Phase Preparation of Subvalent Germanium Monoxide (GeO, X1Σ+) via Non-Adiabatic Reaction Dynamics in the Exit Channel, J. Phys. Chem. Lett., 13, 4589-4597 (2022).   (PDF)   (Supplemental Information)   (Data Files)  

530.   Z. Yang, C. He, S. J. Goettl, D. Paul, R. I. Kaiser, M. X. Silva, B. R. L. Galvão, Gas-Phase Preparation of Silyl Cyanide (SiH3CN) via a Radical Substitution Mechanism, J. Am. Chem. Soc., 144, 8649-8657 (2022).   (PDF)   (Supplemental Information)   (Data Files)

529.   Z. Yang, B.-J. Sun, C. He, S. Fatimah, A. H. H. Chang, R. I. Kaiser, Gas Phase Preparation of the Elusive Monobridged Ge(μ-H)GeH Molecule through Nonadiabatic Reaction Dynamics, Chem. Eur. J., 28, e202103999 (2022).   (PDF)   (Supplemental Information)   (Data Files)

528.   C. Zhang, C. Zhu, A. K. Eckhardt, R. I. Kaiser, Detection of 1H-Triphosphirene (c-HP3) and 2-Triphosphenylidene (HP3): The Isovalent Counterparts of 1H-Triazirine (c-HN3) and Hydrazoic Acid (HN3). J. Phys. Chem. Lett., 13, 2725-2730 (2022).   (PDF)  (Supplemental Information)   (Data Files)

527.   S. J. Goettl, C. He, D. Paul, A. A. Nikolayev, V. N. Azyazov, A. M. Mebel, R. I. Kaiser, Gas-Phase Study of the Elementary Reaction of the D1-Ethynyl Radical (C2D; X2Σ+) with Propylene (C3H6; X1A') under Single-Collision Conditions. J. Phys. Chem. A., 126, 1889-1898 (2022).   (PDF)  (Supplemental Information)   (Data Files)  

526.   S. Gobi, Z. Lin, C. Zhu, M. Head-Gordon, R. I. Kaiser Oxygen Isotope Exchange between Carbon Dioxide and Iron Oxides on Mars’ Surface. J Phys Chem Lett 13, 2600-2606 (2022).   (PDF)  (Supplemental Information)    

525.   R. I. Kaiser, L. Zhao, W. Lu, M. Ahmed, V. S. Krasnoukhov, V. N. Azyazov, A. M. Mebel, Unconventional Excited-State Dynamics in the Concerted Benzyl (C7H7) Radical Self-Reaction to Anthracene (C14H10). Nat. Commun. 13, 786 (2022).   (PDF)  (Supplemental Information)   (Data Files)  

524.   S. K. Singh, C. Zhu, J. L. Jeunesse, R. C. Fortenberry, R. I. Kaiser, Experimental Identification of Aminomethanol (NH2CH2OH) – The Key Intermediate in the Strecker Synthesis, Nat. Commun. 13, 375 (2022).   (PDF)   (Supplemental Information)  (Data Files)  

523.   N. F. Kleimeier, Y. Liu, A. M. Turner, L. A. Young, C. H. Chin, T. Yang, X. He., J. I. Lo, B. M. Cheng, R. I. Kaiser, Excited state photochemically driven surface formation of benzene from acetylene ices on Pluto and in the outer solar system, Phys. Chem. Chem. Phys., 24, 1424-1436 (2022).   (PDF)   (Supplemental Information)  (Data Files)  

522.   S. J. Brotton, S.D. Perera, A. Misra, N. F. Kleimeier, A.M. Turner, R.I. Kaiser, M. Palenik, M. T. Finn, A. Epshteyn, B.-J. Sun, A.H.H. Chang, A Spectroscopic Investigation on the Oxidation of exo-Tetrahydrodicyclopentadiene (JP-10; C10H16) Doped with Titanium-Aluminum-Boron Reactive Metal Nanopowder (RMNP), J. Phys. Chem. A. , 126, 1, 125-144 (2022).   (PDF)   (Supplemental Information)  (Data Files)  

521.   N. F. Kleimeier, R. I. Kaiser, Bottom-Up Synthesis of 1,1-Ethenediol (H2CC(OH)2) - the Simplest Unsaturated Geminal Diol - in Interstellar Analogue Ices, J. Phys. Chem. Lett., 24, 229-235 (2022).   (PDF)  (Supplemental Information)   (Data Files)

520.   R.I. Kaiser, L. Zhao, W. Lu, M. Ahmed, M. V. Zagidullin, V.N. Azyazov, A.M. Mebel, Gas-Phase Formation of Benzene (C6H6) and Naphthalene (C10H8) through Resonantly Stabilized Cyclopentadienyl-Mediated Radical-Radical Reactions. J. Phys. Chem Lett. 13, 208-213 (2022).   (PDF)  (Supplemental Information)   (Data Files)  

519.   C. Zhu, N. F. Kleimeier, A. M. Turner, S. K. Singh, R. C. Fortenberry, R. I. Kaiser, Synthesis of methanediol [CH2(OH)2]: The simplest geminal diol, PNAS, 119, e2111938119 (2022).   (PDF)   (Supplemental Information)  (Data Files)  

518.   C. He, K. Fujioka, A. A. Nikolayev, L. Zhao, S. Doddipatla, V. N. Azyazov, A. M. Mebel, R. Sun, R. I. Kaiser, A Chemical Dynamics Study of the Reaction of the Methylidyne Radical (CH, X2Π) with Dimethylacetylene (CH3CCCH3, X1A1g), Phys. Chem. Chem. Phys., 24, 578 (2022).   (PDF)  (Supplemental Information)   (Data Files)

517.   A. Rettig, M. Head-Gordon, S. Doddipatla, Z. Yang, R. I. Kaiser, Crossed Beam Experiments and Computational Studies of Pathways to the Preparation of Singlet Ethynylsilylene (HCCSiH; X1A′): The Silacarbene Counterpart of Triplet Propargylene (HCCCH; X3B). J. Phys. Chem Lett. 12, 10768-10776 (2021).   (PDF)  (Supplemental Information)   (Data Files)  

516.   J. Cernicharo, M. Agundez, R. I. Kaiser, C. Cabezas, B. Tercero, N. Marcelino, J. R. Pardo, P. de Vicente Discovery of two isomers of ethynyl cyclopentadiene in TMC-1: Abundances of CCH and CN derivatives of hydrocarbon cycles. Astron. Astrophys. 655, L1 (2021).   (PDF)  

515.   A.A. Nikolayev, V.N. Azyazov, R.I. Kaiser, A.M. Mebel, Theoretical Study of the Reaction of the Methylidyne Radical (CH; X2Π) with 1-Butyne (CH3CH2CCH; X1A’). J. Phys. Chem A 125, 9536-9547 (2021).   (PDF)  

514.   A.A. Pershin, A.P. Torbin, P.A. Mikheyev, R.I. Kaiser, A.M. Mebel, V.N. Azyazov, Ozone destruction due to the recombination of oxygen atoms. J. Chem. Phys. 155, 164307 (2021).   (PDF)    

513.   C. He, S. Doddipatla, Z. Yang, S. J. Goettl, R. I. Kaiser, V. N. Azyazov, A. M. Mebel, T. J. Millar, Gas-Phase Synthesis of Silaformaldehyde (H2SiO) and Hydroxysilylene (HSiOH) in Outflows of Oxygen-rich Asymptotic Giant Branch Stars, Astrophys. J. Lett., 921, L7 (2021).   (PDF)   (Data Files)

512.   C. Zhu, A. Bergantini, S. K. Singh, M. J. Abplanalp, R. I. Kaiser, Rapid Radical–Radical Induced Explosive Desorption of Ice-coated Interstellar Nanoparticles, Astrophys. J., 920, 73 (2021).   (PDF)   (Data Files)  

511.   C. Zhu, A. K. Eckhardt, S. Chandra, A. M. Turner, P. R. Schreiner, R. I. Kaiser, Identification of A Prismatic P3N3 Molecule Formed from Electron Irradiated Phosphine-nitrogen Ices, Nat. Commun., 12, 5467 (2021).   (PDF)   (Supplemental Information)  (Data Files)  

510.   Z. Yang, C. He, S. Goettl, R. I. Kaiser, V. N. Azyazov, A. M. Mebel, Directed Gas-Phase Formation of Aminosilylene (HSiNH2; X1A'): The Simplest Silicon Analogue of an Aminocarbene, under Single-Collision Conditions, J. Am. Chem. Soc., 143, 14227-14234 (2021).   (PDF)   (Supplemental Information)  (Data Files)  

509.   L. Zhao, M. Prendergast, R. I. Kaiser, B. Xu, W. Lu, M. Ahmed, A. H. Howlader, S. F. Wnuk, A. S. Korotchenko, M. M. Evseev, E. K. Bashkirov, V. N. Azyazovde, A. M. Mebel, A molecular beam and computational study on the barrierless gas phase formation of (iso)quinoline in low temperature extraterrestrial environments, Phys. Chem. Chem. Phys., 23, 18495 (2021).   (PDF)   (Supplemental Information)   (Data Files)

508.   C. He, S. J. Goettl, Z. Yang, S. Doddipatla, R. I. Kaiser, M. X. Silva, B. R. L. Galvão, Directed Gas-Phase Preparation of the Elusive Phosphinosilylidyne (SiPH2, X2A'') and Cis/Trans Phosphinidenesilyl (HSiPH; X2A') Radicals under Single-Collision Conditions, Phys. Chem. Chem. Phys., 23, 18506 (2021).   (PDF)   (Supplemental Information)   (Data Files)

507.   N. F. Kleimeier, A. K. Eckhardt, R. I. Kaiser, Identification of Glycolaldehyde Enol (HOHC═CHOH) in Interstellar Analogue Ices, J. Am. Chem. Soc., 143, 14009-14018 (2021).   (PDF)   (Supplemental Information)  (Data Files)  

506.   J. Cernicharo, M. Agundez, R. I. Kaiser, C. Cabezas, B. Tercero, N. Marcelino, J. R. Pardo, P. de Vicente, Discovery of Benzyne, o-C6H4, in TMC-1 with the QUIJOTE Line Survey, Astron. Astrophys., 652, L9 (2021).   (PDF)  

505.   A. M. Turner, A. Bergantini, A. S. Koutsogiannis, N. F. Kleimeier, S. K. Singh, C. Zhu, A. K. Eckhardt, R. I. Kaiser, A Photoionization Mass Spectrometry Investigation into Complex Organic Molecules Formed in Interstellar Analog Ices of Carbon Monoxide and Water Exposed to Ionizing Radiation, Astrophys. J., 916, 24 (2021).   (PDF)   (Data Files)  

504.   V. S. Krasnoukhov, V. N. Azyazov, A. M. Mebel, S. Doddipatla, Z. Yang, S. Goettl, R. I. Kaiser, Combined Crossed Molecular Beams and Ab Initio Study of the Bimolecular Reaction of Ground State Atomic Silicon (Si; 3P) with Germane (GeH4; X1A1), ChemPhysChem 22, 1497-1504 (2021).   (PDF)   (Supplemental Information)   (Data Files)

503.   S. K. Singh, V. Vuppuluri, B. J. Sun, B. Y. Chang, A. K. Eckhardt, S. F. Son, A. H. H. Chang and R. I. Kaiser, Identification of Elusive Keto and Enol Intermediates in the Photolysis of 1,3,5-Trinitro-1,3,5-Triazinane, J. Phys. Chem. Lett. 12, 6062-6069 (2021).   (PDF)   (Supplemental Information)   (Data Files)

502.   S. Doddipatla, C. He, S. J. Goettl, R. I. Kaiser, B. R. L. Galvão, T. J. Millar, Nonadiabatic Reaction Dynamics to Silicon Monosulfide (SiS): A Key Molecular Building Block to Sulfur-Rich Interstellar Grains, Science Advances, 7, eabg7003 (2021).   (PDF)   (Supplemental Information)   (Data Files)

501.   N. F. Kleimeier, R. I. Kaiser, Interstellar Enolization-Acetaldehyde (CH3CHO) and Vinyl Alcohol (H2CCH(OH)) as a Case Study, ChemPhysChem, 22, 1229– 1236 (2021).   (PDF)   (Supplemental Information)    (Data Files)

500.   S. J. Goettl, Z. Yang, S. Doddipatla, C. He, M. O. Alves, B. R. L. Galvão, R. I. Kaiser, A Crossed Molecular Beams and Computational Study of the Formation of the Astronomically Elusive Thiosilaformyl Radical (HSiS, X2A'), J. Phys. Chem. Lett., 12, 5979-5986 (2021).   (PDF)   (Supplemental Information)   (Data Files)

499.   S. J. Goettl, S. Doddipatla, Z. Yang, C. He, R. I. Kaiser, M. X. Silva, B. R. L. Galvão, T. J. Millar, Chemical Dynamics Study on the Gas-Phase Reaction of the D1-Silylidyne Radical (SiD; X2Π) with Deuterium Sulfide (D2S) and Hydrogen Sulfide (H2S), Phys. Chem. Chem. Phys., 23, 13647-13661 (2021).   (PDF)   (Supplemental Information)   (Data Files)

498.   Z. Yang, C. He, S. Goettl, R. I. Kaiser, Reaction Dynamics Study of the Molecular Hydrogen Loss Channel in the Elementary Reactions of Ground State Silicon Atoms (Si(3P)) with 1- and 2-Methyl-1,3-Butadiene (C5H8), J. Phys. Chem. A, 125, 5040-5047 (2021).   (PDF)   (Data Files)

497.   S. D. Perera, S. J. Brotton, H. Shinsato, R. I. Kaiser, Y. Choi, K. Na, Catalytic Effects of Zeolite Socony Mobil-5 (ZSM-5) on the Oxidation of Acoustically Levitated exo-Tetrahydrodicyclopentadiene (JP-10) Droplets, J. Phys. Chem. A, 125, 4896-4909 (2021).   (PDF)   (Supplemental Information)   (Data Files)

496.   A. M. Turner, S. Chandra, R. C. Fortenberry, R. I. Kaiser, A Photoionization Reflectron Time-of-Flight Mass Spectrometric Study on the Detection of Ethynamine (HCCNH2) and 2H-Azirine (c-H2CCHN), ChemPhysChem, 22, 985-994 (2021).   (PDF)   (Supplemental Information)   (Data Files)

495.   L. Zhao, W. Lu, M. Ahmed, M. V. Zagidullin, V. N. Azyazov, A. N. Morozov, A. M. Mebel, R. I. Kaiser, Gas-phase synthesis of benzene via the propargyl radical self-reaction, Science Advances, 7, eabf0360 (2021).   (PDF)   (Supplemental Information)   (Data Files)

494.   C. Zhu, A. Bergantini, S. K. Singh, R. I. Kaiser, A. K. Eckhardt, P. R. Schreiner, Y.-S. Huang, B.-J. Sun, A. H. H. Chang, Formation of phosphine imide (HN=PH3) and its phosphinous amide (H2N–PH2) isomer, Chem. Commun., 57, 4958-4961 (2021).   (PDF)   (Supplemental Information)   (Data Files)

493.   S. K. Singh, A. Bergantini, C. Zhu, M. Ferrari, M. C. D. Sanctis, S. D. Angelis, R. I. Kaiser Origin of Ammoniated Phyllosilicates on Dwarf Planet Ceres and Asteroids, Nat. Commun. 12, 2690 (2021).   (PDF)   (Supplemental Information)   (Data Files)

492.   S. J. Brotton, R. I. Kaiser Effects of Nitrogen Dioxide on the Oxidation of Levitated exo-Tetra-hydro-dicyclopentadiene (JP-10) Droplets Doped with Aluminum Nanoparticles, J. Phys. Chem. A, 125, 2727-2742 (2021).   (PDF)   (Supplemental Information)   (Data Files)

491.   N. F. Kleimeier, M. J. Abplanalp, R. N. Johnson, S. Gozem , J. Wandishin, C. N. Shingledecker, R. I. Kaiser Cyclopropenone (c-C3H2O) as a Tracer of the Nonequilibrium Chemistry Mediated by Galactic Cosmic Rays in Interstellar Ices, Astrophys. J., 911, 24 (2021).   (PDF)   (Data Files)

490.   R. I. Kaiser, N. Hansen, An Aromatic Universe−A Physical Chemistry Perspective, J. Phys. Chem. A., 125, 3826-3840 (2021).   (PDF)   (Figure Files)

489.   Z. Yang, B.-J. Sun, C. He, S. Goettl, Y.-T. Lin, A. H. H. Chang, R. I. Kaiser, Combined Experimental and Computational Study on the Reaction Dynamics of the D1-Silylidyne (SiD) - Silane (SiH4) System, J. Phys. Chem. A, 125, 2472-2479 (2021).   (PDF)   (Supplemental Information)   (Data Files)

488.   L. Zhao, S. Doddipatla, R. I. Kaiser, W. Lu, O. Kostko, M. Ahmed, L. B. Tuli, A. N. Morozov, A. H. Howlader, S. F. Wnuk, A. M. Mebel, V. N. Azyazov, R. K. Mohamed, F. R. Fischer, Gas-phase synthesis of corannulene - a molecular building block of fullerenes, Phys. Chem. Chem. Phys., 23, 5740-5749 (2021).   (PDF)   (Supplemental Information)    (Data Files)

487.   S. Chandra, A. K. Eckhardt, A. M. Turner, G. Tarczay, R. I. Kaiser, A Photoionization Study on the Detection of 1-Sila Glycoaldehyde (HSiOCH2OH), 2-Sila Acetic Acid (H3SiCOOH), and 1,2-Disila Acetaldehyde (HSiOSiH3), Chem. Eur. J., 27, 4939-4945 (2021).   (PDF)   (Supplemental Information)   (Data Files)

486.   C. He, Z. Yang, S. Doddipatla, L. Zhao, S. Goettl, R. I. Kaiser, M. X. Silva, B. R. L. Galvão, Non-Adiabatic Reaction Dynamics in the Gas-Phase Formation of Phosphinidenesilylene, the Isovalent Counterpart of Hydrogen Isocyanide, under Single-Collision Conditions, J. Phys. Chem. Lett., 12, 2489-2495 (2021).   (PDF)   (Supplemental Information)   (Data Files)

485.   Z. Yang, S. Doddipatla, R. I. Kaiser, A. A. Nikolayev, V. N. Azyazov, A. M. Mebel, On the Synthesis of the Astronomically Elusive 1-Ethynyl-3-Silacyclopropenylidene (c-SiC4H2) Molecule in Circumstellar Envelopes of Carbon-rich Asymptotic Giant Branch Stars and Its Potential Role in the Formation of the Silicon Tetracarbide Chain (SiC4), Astrophys. J. Lett., 908, L40 (2021).   (PDF)   (Data Files)

484.   S. K. Singh, R. I. Kaiser, A Vacuum Ultraviolet Photoionization Study on the Isomerization, Decomposition, and Molecular Mass Growth Processes in Solid Nitromethane (CH3NO2), Chem. Phys. Lett., 766, 138343 (2021).   (PDF)   (Data Files)

483.   C. He, A. A. Nikolayev, L. Zhao, A. M. Thomas, S. Doddipatla, G. R. Galimova, V. N. Azyazov, A. M. Mebel, R. I. Kaiser, Gas-Phase Formation of C5H6 Isomers via the Crossed Molecular Beam Reaction of the Methylidyne Radical (CH; X2Π) with 1,2-Butadiene (CH3CHCCH2; X1A'), J. Phys. Chem. A 125, 126-138 (2021).   (PDF)   (Supplemental Information)   (Data Files)

482.   S. Doddipatla, G. R. Galimova, H. Wei, A. M. Thomas, C. He, Z. Yang, A. N. Morozov, C. N. Shingledecker, A. M. Mebel, R. I. Kaiser, Low-temperature Gas-phase Formation of Indene in the Interstellar Medium, Science Advances, 7, eabd4044 (2021).   (PDF)   (Supplemental Information)   (Data Files)

481.   Z. Yang, S. Doddipatla, R. I. Kaiser, V. S. Krasnoukhov, V. N. Azyazov, A. M. Mebel, Directed Gas Phase Formation of the Elusive Silylgermylidyne Radical (H3SiGe, X2A''), ChemPhysChem, 22, 184-191 (2021).   (PDF)   (Supplemental Information)   (Data Files)

480.   A. M. Turner, R. I. Kaiser, Exploiting Photoionization Reflectron Time-of-Flight Mass Spectrometry to Explore Molecular Mass Growth Processes to Complex Organic Molecules in Interstellar and Solar System Ice Analogs , Acc. Chem. Res., 53, 2791-2805 (2020).   (PDF)   (Figure Files)

479.   S. K. Singh, J. L. Jeunesse, C. Zhu, N. F. Kleimeier, K. H. Chen, B. J. Sun, A. H. H. Chang, R. I. Kaiser, Gas Phase Identification of the Elusive Oxaziridine (cyclo-H2CONH) – An Optically Active Molecule , Chem. Commun., 56, 15643-15646 (2020).   (PDF)   (Supplemental Information)   (Data Files)

478.   C. He, G. R. Galimova, Y. Luo, L. Zhao, A. K. Eckhardt, R. Sun, A. M. Mebel, R. I. Kaiser, A Chemical Dynamics Study on the Gas-phase Formation of Triplet and Singlet C5H2 Carbenes, PNAS, 117, 30142-30150 (2020).   (PDF)   (Supplemental Information)   (Data Files)

477.   N. F. Kleimeier, A. K. Eckhardt, P. R. Schreiner, R. I. Kaiser, Interstellar Formation of Biorelevant Pyruvic Acid (CH3COCOOH), Chem, 6, 1-11 (2020).   (PDF)   (Supplemental Information)   (Data Files)

476.   A. H. Howlader, K. Diaz, A. M. Mebel, R. I. Kaiser, S. F. Wnuk Iodoindenes: Synthesis and application to cross-coupling, Tetrahedron Lett., 61, 152427 (2020).   (PDF)   (Supplemental Information)  

475.   Z. Yang, S. Doddipatla, C. He, V. S. Krasnoukhov, V. N. Azyazov, A. M. Mebel, R. I. Kaiser, Directed Gas Phase Formation of Silene (H2SiCH2), Chem. Eur. J., 26, 13584-13589 (2020).   (PDF)   (Supplemental Information)   (Data Files)

474.   L. Zhao, R. I. Kaiser, W. Lu, O. Kostko, M. Ahmed, M. M. Evseev, E. K. Bashikirov, A. D. Oleinikov, V. N. Azyazov, A. M. Mebel, A. H. Howlader, S. F. Wnuk, Gas phase formation of cyclopentanaphthalene (benzindene) isomers via reactions of 5- and 6-indenyl radicals with vinylacetylene, Phys. Chem. Chem. Phys. 22, 22493-22500 (2020).   (PDF)   (Supplemental Information)   (Data Files)

473.   N. F. Kleimeier, A. K. Eckhardt, R. I. Kaiser, A Mechanistic Study on the Formation of Acetic Acid (CH3COOH) in Polar Interstellar Analog Ices Exploiting Photoionization Reflectron Time–of–flight Mass Spectrometry , Astrophys. J., 901, 84 (2020).   (PDF)   (Data Files)

472.   S. Doddipatla, Z. Yang, A. M. Thomas, Y. Chen, B. Sun, A. H. H. Chang, A. M. Mebel, R. I. Kaiser, Gas Phase Synthesis of the Elusive Trisilacyclopropyl Radical (Si3H5) via Unimolecular Decomposition of Chemically Activated Doublet Trisilapropyl Radicals (Si3H7), J. Phys. Chem. Lett., 11, 7874-7881 (2020).   (PDF)   (Supplemental Information)   (Data Files)

471.   Z. Yang, C. He, S. Doddipatla, V. S. Krasnoukhov, V. N. Azyazov, A. M. Mebel, R. I. Kaiser, Gas Phase Formation of Methylgermylene (HGeCH3), ChemPhysChem, 21, 1898-1904 (2020).   (PDF)   (Supplemental Information)   (Data Files)

470.   S. K. Singh, V. Vuppuluri, S. F. Son, R. I. Kaiser, Investigating the Photochemical Decomposition of Solid 1,3,5-Trinitro-1,3,5-triazinane (RDX), J. Phys. Chem. A, 124, 6801-6823 (2020).   (PDF)   (Supplemental Information)   (Data Files)

469.   S. Doddipatla, C. He, R. I. Kaiser, Y. Luo, R. Sun, G. R. Galimova, A. M. Mebel, T. J. Millar, A Chemical Dynamics Study on the Gas Phase Formation of Thioformaldehyde (H2CS) and its Thiohydroxycarbene Isomer (HCSH), PNAS, 117, 22712-22719 (2020).   (PDF)   (Supplemental Information)   (Data Files)

468.   C. Zhu, A. M. Turner, M. J. Abplanalp, R. I. Kaiser, B. Webb, G. Siuzdak, R. C. Fortenberry, An Interstellar Synthesis of Glycerol Phosphates, Astrophys. J. Lett., 899, L3 (2020).   (PDF)   (Data Files)

467.   C. Zhu, A. K. Eckhardt, A. Bergantini, S. K. Singh, P. R. Schreiner, R. I. Kaiser, The elusive cyclotriphosphazene molecule and its Dewar benzene–type valence isomer (P3N3), Science Advances, 6, eaba6934 (2020).   (PDF)   (Supplemental Information)   (Data Files)

466.   N. F. Kleimeier, A. M. Turner, R. C. Fortenberry, R. I. Kaiser, On the Formation of the Popcorn Flavorant 2,3-Butanedione (CH3COCOCH3) in Acetaldehyde-Containing Interstellar Ices, ChemPhysChem 21, 1531– 1540 (2020).   (PDF)   (Supplemental Information)   (Data Files)

465.   L. Zhao, R. I. Kaiser, W. Lu, M. Ahmed, A. D. Oleinikov, V. N. Azyazov, A. M. Mebel, A. H. Howlader, S. F. Wnuk, Gas phase formation of phenalene via 10π-aromatic, resonantly stabilized free radical intermediates, Phys. Chem. Chem. Phys. 22, 15381-15388 (2020).   (PDF)   (Supplemental Information)   (Data Files)

464.   L. Zhao, R. I. Kaiser, W. Lu, M. Ahmed, M. M. Evseev, E. K. Bashkirov, V. N. Azyazov, C. Tönshoff, F. Reicherter, H. F. Bettinger, A. M. Mebel, A Free Radical Prompted Barrierless Gas-Phase Synthesis of Pentacene, Angew. Chem. Int. Ed. 59, 11334–11338 (2020).   (PDF)   (Supplemental Information)   (Data Files)

463.   S. K. Singh, T. Y. Tsai, B. J. Sun, A. H. H. Chang, A. M. Mebel, R. I. Kaiser, Gas Phase Identification of the Elusive N-Hydroxyoxaziridine (c-H2CON(OH)): A Chiral Molecule, J. Phys. Chem. Lett., 11, 5383-5389 (2020).   (PDF)   (Supplemental Information)   (Data Files)

462.   C. He, L. Zhao, S. Doddipatla, A. M. Thomas, A. A. Nikolayev, G. R. Galimova, V. N. Azyazov, A. M. Mebel, R. I. Kaiser, Gas-Phase Synthesis of 3-Vinylcyclopropene via the Crossed Beam Reaction of the Methylidyne Radical (CH; X2Π) with 1,3-Butadiene (CH2CHCHCH2; X1Ag), ChemPhysChem, 21, 1295-1309 (2020).   (PDF)   (Supplemental Information)   (Data Files)

461.   A. M. Turner, A. Koutsogiannis, N. F. Kleimeier, A. Bergantini, C. Zhu, R. C. Fortenberry, R. I. Kaiser, An Experimental and Theoretical Investigation into the Formation of Ketene and Ethynol (HCCOH) in Interstellar Analog Ices, Astrophys. J., 896, 88, (2020).   (PDF)   (Data Files)

460.   S. J. Brotton, M. J. Malek, S. L. Anderson, R. I. Kaiser, Effects of acetonitrile-assisted ball-milled aluminum nanoparticles on the ignition of acoustically levitated exo-tetrahydrodicyclopentadiene (JP-10) droplets, Chem. Phys. Lett. 754, 137679 (2020).   (PDF)   (Supplemental Information)   (Data Files)

459.   L. Zhao, W. Y. Chen, H. J. Su, J. Z. Yang, R. I. Kaiser, A vacuum ultraviolet photoionization study on oxidation of JP-10 (exo-Tetrahydrodicyclopentadiene), Chem. Phys. Lett. 754, 137490 (2020).   (PDF)   (Supplemental Information)   (Data Files)

458.   S. J. Brotton and R. I. Kaiser, Controlled Chemistry via Contactless Manipulation and Merging of Droplets in an Acoustic Levitator, Anal. Chem, 92, 8371-8377 (2020).   (PDF)   (Supplemental Information)   (Data Files)

457.   S. K. Singh, J. L. Jeunesse, V. Vuppuluri, S. F. Son, B. J. Sun, Y. L. Chen, A. H. H. Chang, A. M. Mebel, R. I. Kaiser, The Elusive Ketene (H2CCO) Channel in the Infrared Multiphoton Dissociation of Solid 1,3,5-Trinitro-1,3,5-Triazinane (RDX), ChemPhysChem, 21, 837-842 (2020).   (PDF)   (Supplemental Information)   (Data Files)

456.   L. Zhao, R. I. Kaiser, B. Xu, U. Ablikim, M. Ahmed, M. M. Evseev, E. K. Bashkirov, V. N. Azyazov, A. M. Mebel, A Unified Mechanism on the Formation of Acenes, Helicenes, and Phenacenes in the Gas Phase, Angew. Chem. Int. Ed. 59, 4051-4058 (2020).   (PDF)   (Supplemental Information)   (Data Files)

455.   M. Lucas, S. J. Brotton, A. Min, C. Woodruff, M. L. Pantoya, and R. I. Kaiser, Effects of Size and Prestressing of Aluminum Particles on the Oxidation of Levitated exo-Tetrahydrodicyclopentadiene Droplets, J. Phys. Chem. A., 124, 1489-1507 (2020).   (PDF)   (Supplemental Information)   (Data Files)

454.   C. He, A. M. Thomas, G. R. Galimova, A. N. Morozov, A. M. Mebel, R. I. Kaiser, Gas-Phase Formation of Fulvenallene (C7H6) via the Jahn-Teller Distorted Tropyl (C7H7) Radical Intermediate under Single-Collision Conditions, J. Am. Chem. Soc., 142, 3205-3213 (2020).   (PDF)   (Supplemental Information)   (Data Files)

453.   C. Zhu, A. M. Turner, C. Meinert, R. I. Kaiser, On the Production of Polyols and Hydroxycarboxylic Acids in Interstellar Analogous Ices of Methanol, Astrophy. J. 889, 134 (2020).   (PDF)   (Data Files)

452.   M. J. Abplanalp, R. I. Kaiser, Implications for Extraterrestrial Hydrocarbon Chemistry: Analysis of acetylene (C2H2) and D2-acetylene (C2D2) Ices Exposed to Ionizing Radiation via Ultraviolet-Visible Spectroscopy, Infrared Spectroscopy, and Reflectron Time-of-flight Mass Spectrometry, Astrophy. J. 889, 3 (2020).   (PDF)   (Data Files)

451.   C. Zhu, S. Góbi, M. J. Abplanalp, R. Frigge, J. J. Gillis-Davis, R. I. Kaiser, Space Weathering‐Induced Formation of Hydrogen Sulfide (H2S) and Hydrogen Disulfide (H2S2) in the Murchison Meteorite, J. Geophys. Res.-Planet. 124, 2772-2779 (2019).   (PDF)   (Supplemental Information)   (Data Files)

450.   C. He, A. M. Thomas, G. R. Galimova, A. M. Mebel, R. I. Kaiser, Gas-Phase Formation of 1-Methylcyclopropene and 3-Methylcyclopropene via the Reaction of the Methylidyne Radical (CH; X2Π) with Propylene (CH3CHCH2; X1A'), J. Phys. Chem. A 123, 10543-10555 (2019).   (PDF)   (Supplemental Information)   (Data Files)

449.   P. B. Crandall, J. J. Gillis-Davis, R. I. Kaiser, Untangling the Origin of Molecular Hydrogen in the Lunar Exosphere, Astrophys. J. 887, 1 (2019).   (PDF)   (Data Files)

448.   A. M. Thomas, S. Doddipatla, R. I. Kaiser, G. R. Galimova, A. M. Mebel, A Barrierless Pathway Accessing the C9H9 and C9H8 Potential Energy Surfaces via the Elementary Reaction of Benzene with 1-Propynyl, Sci. Rep. 9, 17595 (2019).   (PDF)   (Supplemental Information)   (Data Files)

447.   L. Zhao, M. B. Prendergast, R. I. Kaiser, B. Xu, U. Ablikim, M. Ahmed, B-J Sun, Y-L Chen, A. H. H. Chang, R. K. Mohamed, F. R. Fischer, Synthesis of Polycyclic Aromatic Hydrocarbons by Phenyl Addition–Dehydrocyclization: The Third Way, Angew. Chem., Int. Ed. 58, 17442-17450 (2019).   (PDF)   (Supplemental Information)   (Data Files)

446.   S. K. Singh, C. Zhu, V. Vuppuluri, S. F. Son, R. I. Kaiser, Probing the Reaction Mechanisms Involved in the Decomposition of Solid 1,3,5-Trinitro-1,3,5-triazinane by Energetic Electrons, J. Phys. Chem. A 123, 9479-9497 (2019).   (PDF)   (Supplemental Information)   (Data Files)

445.   C. He, L. Zhao, A. M. Thomas, G. R. Galimova, A. M. Mebel, R. I. Kaiser, A Combined Experimental and Computational Study on the Reaction Dynamics of the 1-Propynyl Radical (CH3CC; X2A1) with Ethylene (H2CCH2; X1A1g) and the Formation of 1-Penten-3-yne (CH2CHCCCH3; X1A'), Phys. Chem. Chem. Phys, 21, 22308-22319 (2019).   (PDF)   (Supplemental Information)   (Data Files)

444.   M. J. Abplanalp, R. Frigge, R. I. Kaiser, Low-temperature synthesis of polycyclic aromatic hydrocarbons in Titan's surface ices and on airless bodies, Science Advances, 5, eaaw5841 (2019).    (PDF)   (Supplemental Information)   (Data Files)

443.   A. M. Thomas, L. Zhao, C. He, G. R. Galimova, A. M. Mebel, R. I. Kaiser, Directed Gas-Phase Synthesis of Triafulvene under Single-Collision Conditions, Angew. Chem., Int. Ed., 58, 15488-15495 (2019).    (PDF)   (Supplemental Information)   (Data Files)

442.   C. Zhu, S. Góbi, M. J. Abplanalp, R. Frigge, J. J. Gillis-Davis, G. Dominguez, K. Miljković, R. I. Kaiser, Regenerative water sources on surfaces of airless bodies, Nat. Astron., 4, 45-52 (2020).    (PDF)   (Supplemental Information)   (Data Files)

441.   M. Lucas, S.J. Brotton, A. Min, M.L. Pantoya, R.I. Kaiser, Oxidation of Levitated exo-Tetrahydrodicyclopentadiene Droplets Doped With Aluminum Nanoparticles, J. Phys.Chem. Lett., 10, 5756-5763 (2019).   (PDF)   (Supplemental Information)   (Data Files)

440.   C. Zhu, R. Frigge, A. Bergantini, R. C. Fortenberry, R. I. Kaiser, Untangling the Formation of Methoxymethanol (CH3OCH2OH) and Dimethyl Peroxide (CH3OOCH3) in Star-forming Regions, Astrophys. J., 881, 156 (2019).    (PDF)   (Data Files)

439.   R.I. Kaiser Reaction Dynamics in Extreme Environments and Astrochemistry, ChemPhysChem, 20, 2014-2015 (2019).   (PDF)  

438.   L. Zhao, R.I. Kaiser, W. Lu, B. Xu, M. Ahmed, A.N. Morozov, A.M. Mebel, A.H. Howlader, S.F. Wnuk, Molecular mass growth through ring expansion in polycyclic aromatic hydrocarbons via radical–radical reactions, Nat. Commun. 10, 3689 (2019).   (PDF)   (Supplemental Information)   (Data Files)

437.   A. M. Turner, M. J. Abplanalp, A. Bergantini, R. Frigge, C. Zhu, B.-J. Sun, C.-T. Hsiao, A. H. H. Chang, C. Meinert, R.I. Kaiser, Origin of alkylphosphonic acids in the interstellar medium, Science Advances, 5, eaaw4307 (2019).   (PDF)   (Supplemental Information)   (Data Files)

436.   M. J. Abplanalp, R.I. Kaiser, On the formation of complex organic molecules in the interstellar medium: untangling the chemical complexity of carbon monoxide-hydrocarbon containing ice analogues exposed to ionizing radiation via a combined infrared and reflectron time-of-flight analysis, Phys. Chem. Chem. Phys., 21, 16949-16980 (2019).   (PDF)   (Supplemental Information)   (Data Files)

435.   C. He, A. M. Thomas, G. R. Galimova, A.M. Mebel, R.I. Kaiser, Gas Phase Formation of the Interstellar Molecule Methyltriacetylene, ChemPhysChem, 20, 1912-1917 (2019).   (PDF)   (Supplemental Information)   (Data Files)

434.   L. Zhao, M. Prendergast, R.I. Kaiser, B. Xu, U. Ablikim, W. Lu, M. Ahmed, A.D. Oleinikov, V.N. Azyazov, A.H. Howlader, S.F. Wnuk, A.M. Mebel, How to add a five-membered ring to polycyclic aromatic hydrocarbons (PAHs) – molecular mass growth of the 2-naphthyl radical (C10H7) to benzindenes (C13H10) as a case study, Phys. Chem. Chem. Phys. 21, 16737-16750 (2019).   (PDF)   (Supplemental Information)   (Data Files)

433.   T. Yang, L. Bertels, B.B. Dangi, X. Li, M. Head-Gordon, R.I. Kaiser, Gas phase formation of c-SiC3 molecules in the circumstellar envelope of carbon stars, PNAS 116, 14471-14478 (2019).   (PDF)   (Supplemental Information)   (Data Files)

432.   C. He, L. Zhao, A. M. Thomas, A. N. Morozov, A. M. Mebel, R. I. Kaiser, Elucidating the Chemical Dynamics of the Elementary Reactions of the 1-Propynyl Radical (CH3CC; X2A1) with Methylacetylene (H3CCCH; X1A1) and Allene (H2CCCH2; X1A1), J. Phys. Chem. A, 123, 5446-5462 (2019).   (PDF)   (Supplemental Information)   (Data Files)

431.   L. Zhao, M.B. Prendergast, R.I. Kaiser, B. Xu, W. Lu, U. Ablikim, M. Ahmed, A.D. Oleinikov, V.N. Azyazov, A.M. Mebel, A.H. Howlader, S.F. Wnuk, Reactivity of the Indenyl Radical (C9H7) with Acetylene (C2H2) and Vinylacetylene (C4H4), ChemPhysChem, 20, 1437-1447 (2019).   (PDF)   (Supplemental Information)   (Data Files)

430.   C. Zhu, P.B. Crandall, J. J. Gillis-Davis, H. A. Ishii, J. P. Bradley, L. M. Corley, R. I. Kaiser, Untangling the Formation and Liberation of Water in the Lunar Regolith, PNAS, 116, 11165-11170 (2019).   (PDF)   (Supplemental Information)   (Data Files)

429.   A. M. Thomas, C. He, L. Zhao, G. R. Galimova, A. M. Mebel, R. I. Kaiser, Combined Experimental and Computational Study on the Reaction Dynamics of the 1-Propynyl (CH3CC)-1,3-Butadiene (CH2CHCHCH2) System and the Formation of Toluene under Single Collision Conditions, J. Phys. Chem. A, 123, 4104-4118 (2019).   (PDF)   (Supplemental Information)   (Data Files)

428.   A. Eckhardt, A. Bergantini, S. Singh, P.R. Schreiner, R.I. Kaiser, Formation of Glyoxylic Acid in Interstellar Ices: A Key Entry Point for Prebiotic Chemistry, Angew. Chem., Int. Ed. 58, 17, 5663-5667 (2019).   (PDF)   (Supplemental Information)   (Data Files)

427.   L. Zhao, R.I. Kaiser, B. Xu, U. Ablikim, W. Lu, M. Ahmed, M.M. Evseev, E.K. Bashkirov, V.N. Azyazov, M.V. Zagidullin, A.N. Morozov, A.H. Howlader, S.F. Wnuk, A.M. Mebel, D. Joshi, G. Veber, F.R. Fischer, Gas phase synthesis of [4]-helicene, Nat. Commun. 10, 1510-1517 (2019).   (PDF)   (Supplemental Information)   (Data Files)

426.   L. Zhao, R.I. Kaiser, B. Xu, U. Ablikim, W. Lu, M. Ahmed, M.M. Evseev, E.K. Bashkirov, V.N. Azyazov, A.H. Howlader, S.F. Wnuk, A.M. Mebel, Gas-Phase Synthesis of Triphenylene (C18H12), ChemPhysChem 20, 791-797 (2019).   (PDF)   (Supplemental Information)   (Data Files)

425.   M.J. Abplanalp, S. Góbi, R.I. Kaiser, On the Formation and the Isomer Specific Detection of Methylacetylene (CH3CCH), Propene (CH3CHCH2), Cyclopropane (c-C3H6), Vinylacetylene (CH2CHCCH), and 1,3-Butadiene (CH2CHCHCH2) from Interstellar Methane Ice Analogues, Phys. Chem. Chem. Phys. 21, 5378-5393 (2019).   (PDF)   (Supplemental Information)   (Data Files)

424.   A. M. Thomas, B. B. Dangi, T. Yang, G. Tarczay, R. I. Kaiser, B.-J. Sun, S.-Y. Chen, A. H. H. Chang, T. L Nguyen, J. F. Stanton, A. M. Mebel, Directed Gas-Phase Formation of the Germaniumsilylene Butterfly Molecule (Ge(μ-H2)Si), J. Phys. Chem. Lett. 10, 1264−1271 (2019).   (PDF)   (Supplemental Information)   (Data Files)

423.   S. J. Brotton, R. I. Kaiser, Spectroscopic Study on the Polymer Condensates Formed via Pyrolysis of Levitated Droplets of Dicyanamide-Containing Ionic Liquids, J. Phys. Chem. A 123, 1153−1167 (2019).   (PDF)   (Supplemental Information)   (Data Files)

422.   M. Lucas, S.J. Brotton, J.A.P. Sprenger, M. Finze, S.K. Sharma, R.I. Kaiser, Oxidation of a Levitated 1-Butyl-3-methylimidazolium Dicyanoborate Droplet by Nitrogen Dioxide, J. Phys. Chem. A 123, 780-795 (2019).   (PDF)   (Supplemental Information)   (Data Files)

421.   C. Zhu, R. Frigge, A.M. Turner, M.J. Abplanalp, B.-J. Sun, Y.-L. Chen, A.H.H. Chang, R.I. Kaiser, A vacuum ultraviolet photoionization study on the formation of methanimine (CH2NH) and ethylenediamine (NH2CH2CH2NH2) in low temperature interstellar model ices exposed to ionizing radiation, Phys. Chem. Chem. Phys. 21, 1952-1962, (2019).   (PDF)   (Supplemental Information)  (Data Files)

420.   A. M. Thomas, B.B. Dangi, T. Yang, R.I. Kaiser, B.-J. Sun, T.-J. Chou, A.H.H. Chang, A Crossed Molecular Beams Investigation of the Reactions of Atomic Silicon (Si(3P)) with C4H6 Isomers (1,3-Butadiene, 1,2-Butadiene, and 1-Butyne), Chem. Phys. 520, 70-80, (2019).   (PDF)   (Supplemental Information)   (Data Files)

419.   M. Lucas, S.J. Brotton, S.K. Shukla, J. Yu, S.L. Anderson, R.I. Kaiser, Oxidation of a Levitated Droplet of 1-Allyl-3-methylimidazolium Dicyanamide by Nitrogen Dioxide, J. Phys. Chem. A 123, 400-416, (2019).   (PDF)   (Supplemental Information)   (Data Files)

418.   M.V. Zagidullin, R.I. Kaiser, D.P. Porfiriev, I.P. Zavershinskiy, M. Ahmed, V.N. Azyazov, A.M. Mebel, Functional Relationships between Kinetic, Flow, and Geometrical Parameters in a High-Temperature Chemical Microreactor, J. Phys. Chem. A, 8819–8827, (2018).   (PDF)   (Supplemental Information)

417.   L. Zhao, R.I. Kaiser, B. Xu, U. Ablikim, M. Ahmed, M.M. Evseev, E.K. Bashkirov, V.N. Azyazov, A.M. Mebel, Low-Temperature Formation of Polycyclic Aromatic Hydrocarbons in Titan's Atmosphere, Nat. Astron. 2, 973–979, (2018).   (PDF)   (Supplemental Information)   (Data Files)

416.   S.J. Brotton, M. Lucas, T.N. Jensen, S.L. Anderson, R.I. Kaiser, Spectroscopic Study on the Intermediates and Reaction Rates in the Oxidation of Levitated Droplets of Energetic Ionic Liquids by Nitrogen Dioxide, J. Phys. Chem. A 122, 7351-7377 (2018).   (PDF)   (Data Files)

415.   A.M. Turner, A. Bergantini, M.J. Abplanalp, C. Zhu, S. Góbi, B-J Sun, K-H Chao, A.H.H. Chang, C. Meinert, R.I. Kaiser An interstellar synthesis of phosphorus oxoacids, Nat. Commun. 9, 3851 (2018).   (PDF)   (Supplemental Information)   (Data Files)

414.   R. Frigge, C. Zhu, A.M. Turner, M.J. Abplanalp, B-J Sun, Y-S Huang, A.H.H. Chang, R.I. Kaiser, Synthesis of the hitherto elusive formylphosphine (HCOPH2) in the interstellar medium - a molecule with an exotic phosphorus peptide bond, Chem. Comm. 54, 10152-10155 (2018).   (PDF)   (Supplemental Information)   (Data Files)

413.   M. Lucas, A. M. Thomas, T. Yang, R. I. Kaiser, A. M. Mebel, D. Hait, and M. Head-Gordon, Bimolecular Reaction Dynamics in the Phenyl-Silane System: Exploring the Prototype of a Radical Subsitition Mechanism, J. Phys. Chem. Lett. 9, 5135-5142 (2018).   (PDF)   (Supplemental Information)   (Data Files)

412.   A. M. Thomas, L. Zhao, C. He, A.M. Mebel, R.I. Kaiser, A Combined Experimental and Computational Study on the Reaction Dynamics of the 1-Propynyl (CH3CC)-Acetylene (HCCH) System and the Formation of Methyldiacetylene (CH3CCCCH), J. Phys. Chem. A 122, 6663-6672 (2018).   (PDF)   (Data Files)

411.   A. Bergantini, C. Zhu, R.I. Kaiser, A Photoionization Reflectron Time-of-flight Mass Spectrometric Study on the Formation of Acetic Acid (CH3COOH) in Interstellar Analog Ices, Astrophys. J. 862, 140  (2018).   (PDF)   (Data Files)

410.   R. Frigge, C. Zhu, A.M. Turner, M.J. Abplanalp, A. Bergantini, B-J Sun, Y-L Chen, A.H.H. Chang, R. I. Kaiser, A Vacuum Ultraviolet Photoionization Study on the Formation of N-methyl Formamide (HCONHCH3) in Deep Space: A Potential Interstellar Molecule with a Peptide Bond, Astrophys. J. 862, 84  (2018).   (PDF)   (Data Files)

409.   A. Bergantini, M.J. Abplanalp, P. Pokhilko, A.I. Krylov, C.N. Shingledecker, E. Herbst, R.I. Kaiser, A Combined Experimental and Theoretical Study on the Formation of Interstellar Propylene Oxide (CH3CHCH2O)-A Chiral Molecule, Astrophys. J. 860, 108  (2018).   (PDF)   (Data Files)

408.   A.N. Morozov, A.M. Mebel, R.I. Kaiser A Theoretical Study of Pyrolysis of exo-Tetrahydrodicyclopentadiene and Its Primary and Secondary Unimolecular Decomposition Products, J. Phys. Chem. A. 122, 4920-4934  (2018).   (PDF)   (Supplemental Information)

407.   A. M. Thomas, B.B. Dangi, T. Yang, R.I. Kaiser, L. Lin, T-J Chou, A.H.H. Chang Are Nonadiabatic Reaction Dynamics the Key to Novel Organosilicon Molecules? The Silicon (Si(3P))-Dimethylacetylene (C4H6(X1A1g)) System as a Case Study, J. Phys. Chem. Lett. 9, 3340-3347  (2018).   (PDF)   (Supplemental Information)   (Data Files)

406.   C. Zhu, R. Frigge, A.M. Turner, R.I. Kaiser, B-J Sun, S-Y Chen, A.H.H. Chang First identification of unstable phosphino formic acid (H2PCOOH), Chem. Comm. 54, 5716-5719  (2018).   (PDF)   (Supplemental Information)   (Data Files)

405.   A. Bergantini, R. Frigge, R.I. Kaiser Constraining the Molecular Complexity in the Interstellar Medium-The Formation of Ethyl Methyl Ether (CH3OCH2CH3) in Star-forming Regions, Astrophys. J. 859, 59  (2018).   (PDF)   (Data Files)

404.   L. Zhao, R.I. Kaiser, B. Xu, U. Ablikim, M. Ahmed, M.V. Zagidullin, V.N. Azyazov, A.H. Howlader, S.F. Wnuk, A.M. Mebel VUV Photoionization Study on the Formation of the Simplest Polycyclic Aromatic Hydrocarbon: Naphthalene (C10H8), J. Phys. Chem. Lett. 9, 2620-2626  (2018).   (PDF)   (Supplemental Information)   (Data Files)

403.   D. Belisario-Lara, A.M. Mebel, R.I. Kaiser Computational Study on the Unimolecular Decomposition of JP-8 Jet Fuel Surrogates III: Butylbenzene Isomers (n-, s-, and t-C14H10), J. Phys. Chem. A, 122, 3980-4001  (2018).   (PDF)

402.   L. Zhao; R.I. Kaiser, B. Xu, U. Ablikim, M. Ahmed, D. Joshi, G. Veber, F.R. Fischer, A.M. Mebel Pyrene synthesis in circumstellar envelopes and its role in the formation of 2D nanostructures, Nat. Astron. 2, 413-419  (2018).   (PDF)   (Supplemental Information)   (Data Files)

401.   A. M. Thomas, M. Lucas, L. Zhao, J. Liddiard, R.I. Kaiser, A.M. Mebel A combined crossed molecular beams and computational study on the formation of distinct resonantly stabilized C5H3 radicals via chemically activated C5H4 and C6H6 intermediates, Phys. Chem. Chem. Phys. 20, 10906-10925  (2018).   (PDF)   (Supplemental Information)   (Data Files)

400.   M. Lucas, A. M. Thomas, R.I. Kaiser, E.K. Bashkirov, V.N. Azyazov, A.M. Mebel Combined Experimental and Computational Investigation of the Elementary Reaction of Ground State Atomic Carbon (C; 3Pj) with Pyridine (C5H5N; X1A1) via Ring Expansion and Ring Degradation Pathways, J. Phys. Chem. A 122, 3128-3139  (2018).   (PDF)   (Supplemental Information)   (Data Files)

399.   S. Góbi, Parker B. Crandall, P. Maksyutenko, M. Förstel, R.I. Kaiser, Accessing the Nitromethane (CH3NO2) Potential Energy Surface in Methanol (CH3OH)–Nitrogen Monoxide (NO) Ices Exposed to Ionizing Radiation: An FTIR and PI-ReTOF-MS Investigation, J. Phys. Chem. A 122, 2329-2343  (2018).   (PDF)   (Supplemental Information)   (Data Files)

398.   M.J. Abplanalp, S. Góbi, A.Bergantini, A.M. Turner, R.I. Kaiser, On the Synthesis of Chocolate Flavonoids (Propanols, Butanals) in the Interstellar Medium, ChemPhysChem 19, 556-560  (2018).   (PDF)   (Supplemental Information)   (Data Files)

397.   T. Yang, A. M. Thomas, B.B. Dangi, R.I. Kaiser, A.M. Mebel, T.J. Millar, Directed Gas Phase Formation of Silicon Dioxide and Implications for the Formation of Interstellar Silicates, Nat. Commun., 9, 774  (2018).   (PDF)   (Data Files)

396.   C. Zhu, A.M. Turner, M.J. Abplanalp, R.I. Kaiser, Formation of High-order Carboxylic Acids (RCOOH) in Interstellar Analogous Ices of Carbon Dioxide (CO2) and Methane(CH4), Astrophys. J. Suppl. Ser., 234, 15  (2018).   (PDF)   (Data Files)

395.   A.M. Turner, M.J. Abplanalp, T.J. Blair, R. Dayuha, R.I. Kaiser, An Infrared Spectroscopic Study Toward the Formation of Alkylphosphonic Acids and Their Precursors in Extraterrestrial Environments, Astrophys. J., Suppl. Ser., 234, 6  (2018).   (PDF)   (Data Files)

394.   A. Bergantini, S. Góbi, M.J. Abplanalp, R.I. Kaiser, A Mechanistical Study on the Formation of Dimethyl Ether (CH3OCH3) and Ethanol (CH3CH2OH) in Methanol-containing Ices and Implications for the Chemistry of Star-forming Regions, Astrophys. J., 852, 70  (2018).   (PDF)   (Data Files)

393.   S.J. Brotton, M. Lucas, S.D. Chambreau, G.L. Vaghjiani, J. Yu, S.L. Anderson, R.I. Kaiser, Spectroscopic Investigation of the Primary Reaction Intermediates in the Oxidation of Levitated Droplets of Energetic Ionic Liquids, J. Phys. Chem. Lett., 8, 6053-6059  (2018).   (PDF)   (Supplemental Information)   (Data Files)

392.   S. Góbi, L. Zhao, B. Xu, U. Ablikim, M. Ahmed, R.I. Kaiser, A vacuum ultraviolet photoionization study on the thermal decomposition of ammonium perchlorate, Chem. Phys. Lett., 691, 250-257  (2018).   (PDF)   (Supplemental Information)   (Data Files)

391.   M. Lucas, A. M. Thomas, L. Zhao, R.I. Kaiser, G-S Kim, A.M. Mebel, Gas-Phase Synthesis of the Elusive Cyclooctatetraenyl Radical (C8H7) via Triplet Aromatic Cyclooctatetraene (C8H8) and Non-Aromatic Cyclooctatriene (C8H8) Intermediates, Angew. Chem., Int. Ed., 56, 13655-13660  (2017).   (PDF)   (Supplemental Information)   (Data Files)

390.   Y.A. Tsegaw, S. Góbi, M. Förstel, P. Maksyutenko, W. Sander, R.I. Kaiser, Formation of Hydroxylamine in Low-Temperature Interstellar Model Ices, J. Phys. Chem. A, 121, 7477-7493  (2017).   (PDF)   (Supplemental Information)   (Data Files)

389.   P.B. Crandall, S. Góbi, J. Gillis-Davis, R.I. Kaiser, Can perchlorates be transformed to hydrogen peroxide (H2O2) products by cosmic rays on the Martian surface?, J. Geophys. Res. Planets, 122, 1880-1892  (2017).   (PDF)   (Data Files)

388.   M.J. Abplanalp, B.M. Jones, R.I. Kaiser, Untangling the methane chemistry in interstellar and solar system ices toward ionizing radiation: a combined infrared and reflectron time-of-flight analysis, Phys. Chem. Chem. Phys., 20, 5435-5468  (2018).   (PDF)   (Supplemental Information)   (Data Files)

387.   M. Förstel, A. Bergantini, P. Maksyutenko, S. Góbi, R.I. Kaiser, Formation of Methylamine and Ethylamine in Extraterrestrial Ices and Their Role as Fundamental Building Blocks of Proteinogenic α-amino Acids, Astrophys. J., 845, 83  (2017).   (PDF)   (Data Files)

386.   A. M. Thomas, M. Lucas, T. Yang, R.I. Kaiser, L. Fuentes, D. Belisario-Lara, A.M. Mebel, A Free-Radical Pathway to Hydrogenated Phenanthrene in Molecular Clouds — Low Temperature Growth of Polycyclic Aromatic Hydrocarbons, ChemPhysChem, 18, 1971-1976  (2017).   (PDF)   (Supplemental Information)   (Data Files)

385.   L. Zhao, T. Yang, R.I. Kaiser, T.P. Troy, B. Xu, M. Ahmed, J.M. Ribero, D. Belisario-Lara, A.M. Mebel, Y. Zhang, C.C. Cao, J.B. Zou, A Vacuum Ultraviolet Photoionization Study on High-Temperature decomposition of JP-10 (exo-tetrahydrodicyclopentadiene), Phys. Chem. Chem. Phys., 19, 15780-15807  (2017).   (PDF)   (Supplemental Information)   (Data Files)

384.   A. Bergantini, Pavlo Maksyutenko, R.I. Kaiser, On the Formation of the C2H6O Isomers Ethanol (C2H5OH) and Dimethyl Ether (CH3OCH3) in Star-forming Regions, Astrophys. J., 841:96, 1-24  (2017).   (PDF)   (Data Files)

383.   S. Góbi, A. Bergantini, A.M. Turner, R.I. Kaiser, Electron Radiolysis of Ammonium Perchlorate: A Reflectron Time-of-Flight Mass Spectrometric Study, J. Phys. Chem. A 121, 3879-3890  (2017).   (PDF)   (Data Files)

382.   R.I. Kaiser, N. Balucani, Exploring the Gas Phase Synthesis of the Elusive Class of Boronyls and the Mechanism of Boronyl Radical Reactions under Single Collision Conditions, Accounts of Chemical Research. 50, 1154-1162  (2017).   (PDF)

381.   G. Tarczay, M. Förstel, S. Góbi, P. Maksyutenko, R.I. Kaiser, Synthesis of the Smallest Member of the Silylketene Family: H3SiC(H)CO, ChemPhysChem 18, 882-889  (2017).   (PDF)   (Data Files)

380.   T. Yang, R.I. Kaiser, T.P. Troy, B. Xu, O. Kostko, M. Ahmed, A.M. Mebel, M.V. Zagidullin, V.N. Azyazov, HACA's Heritage: A Free-Radical Pathway to Phenanthrene in Circumstellar Envelopes of Asymptotic Giant Branch Stars, Angew. Chem., Int. Ed., 56, 4515-4519  (2017).   (PDF)   (Supplemental Information)   (Data Files)

379.   S. Góbi, A. Bergantini, R.I. Kaiser, Degradation of Adenine on the Martian Surface in the Presence of Perchlorates and Ionizing Radiation: A Reflectron Time-of-flight Mass Spectrometric Study, Astrophys. J., 838, 84  (2017).   (PDF)   (Data Files)

378.   M.J. Abplanalp, R.I. Kaiser, Implications for Extraterrestrial Hydrocarbon Chemistry: Analysis of Ethylene (C2H4) and D4-Ethylene (C2D4) Ices Exposed to Ionizing Radiation via Combined Infrared Spectroscopy and Reflectron Time-of-flight Mass Spectrometry, Astrophys. J., 836, 195  (2017).   (PDF)   (Data Files)

377.   A.M. Mebel, A. Landera, R.I. Kaiser, Formation Mechanisms of Naphthalene and Indene: From the Interstellar Medium to Combustion Flames, J. Phys. Chem. A, 121, 901-926  (2017).   (PDF)   (Supplemental Information)

376.   L. Zhao, T. Yang, R.I. Kaiser, T.P. Troy, M. Ahmed, J.M. Ribero, D. Belisario-Lara, A.M. Mebel, Combined Experimental and Computational Study on the Unimolecular Decomposition of JP-8 Jet Fuel Surrogates. II. n-Dodecane (n-C12H26), J. Phys. Chem. A, 121, 1281-1297  (2017).   (PDF)   (Supplemental Information)   (Data Files)

375.   L. Zhao, T. Yang, R.I. Kaiser, T.P. Troy, M. Ahmed, D. Belisario-Lara, J.M. Ribero, A.M. Mebel, Combined Experimental and Computational Study on the Unimolecular Decomposition of JP-8 Jet Fuel Surrogates. I. n-Decane (n-C10H22), J. Phys. Chem. A, 121, 1261-1280  (2017).   (PDF)   (Supplemental Information)   (Data Files)

374.   S. Góbi, M. Förstel, P. Maksyutenko, R.I. Kaiser, A Reflectron Time-of-Flight Mass Spectrometric Study on the Degradation Pathways of Glycine on Mars in the Presence of Perchlorates and Ionizing Radiation, Astrophys. J., 835, 241  (2017).   (PDF)   (Data Files)

373.   D.S.N. Parker, R.I. Kaiser, On the Formation of Nitrogen-Substituted Polycyclic Aromatic Hydrocarbons (NPAHs) in Circumstellar and Interstellar Environments, Chem. Soc. Rev., 46, 452-463  (2017).   (PDF)

372.   T. Yang, B.B. Dangi, R.I. Kaiser, K-H Chao, B-J Sun, A.H.H. Chang, T.L. Nguyen, J.F. Stanton, Gas-Phase Formation of the Disilavinylidene (H2SiSi) Transient, Angew. Chem., Int. Ed., 56, 1264-1268  (2017).   (PDF)   (Supplemental Information)   (Data Files)

371.   T. Yang, B.B. Dangi, A. M. Thomas, R.I. Kaiser, B-J Sun, M. Stas, A.H.H. Chang, Gas-Phase Synthesis of the Elusive Trisilicontetrahydride Species (Si3H4), J. Phys. Chem. Lett., 8, 131-136  (2017).   (PDF)   (Supplemental Information)   (Data Files)

370.   A. Bergantini, R.I. Kaiser. In Situ Detection of Organics in the Comet 67P/Churyumov-Gerasimenko, Chem 1(6), 822-829  (2016).   (PDF)

369.   A. M. Thomas, T. Yang, B.B. Dangi, R.I. Kaiser, G-S Kim, A.M. Mebel Oxidation of the para-Tolyl Radical by Molecular Oxygen under Single-Collison Conditions: Formation of the para-Toloxy Radical, J. Phys. Chem. Lett., 7, 5121-5127  (2016).   (PDF)   (Data Files)

368.   S. Góbi, A. Bergantini, R. I. Kaiser, In Situ Detection of Chlorine Dioxide (ClO2) in the Radiolysis of Perchlorates and Implications for the Stability of Organics on Mars, Astrophys. J., 832, 164  (2016).   (PDF)   (Data Files)

367.   T. Yang, T.P. Troy, B. Xu, O. Kostko, M. Ahmed, A.M. Mebel, R.I. Kaiser, Hydrogen-Abstraction/Acetylene-Addition Exposed, Angew. Chem., Int. Ed., 55, 14983-14987  (2016).   (PDF)   (Supplemental Information)   (Data Files)

366.   B.M. McMurtry, S.E.J. Saito, A.M. Turner, H.K. Chakravarty, R.I. Kaiser, On the Formation of Benzoic Acid and Higher-Order Benzene Carboxylic Acids in Interstellar Model Ice Grains, Astrophys. J., 831, 174  (2016).   (PDF)   (Data Files)

365.   E.H. Wilson, S.K. Atreya, R.I. Kaiser, Perchlorate Formation on Mars through Surface Radiolysis Initiated Atmospheric Chemistry : A Potential Mechanism, Journal of Geophysical Research – Planets, 121, 1472-1487  (2016).   (PDF)

364.   T. Yang, A. M. Thomas, B.B. Dangi, R.I. Kaiser, M-H Wu, B-J Sun, A.H.H. Chang, Formation of the 2,3-Dimethyl-1-silacycloprop-2-enylidene Molecule via the Crossed Beam Reaction of the Silylidyne Radical (SiH; X2Π) with Dimethylacetylene (CH3CCH3; X1A1g), J. Phys. Chem. A, 120, 7262-7268  (2016).   (PDF)   (Supplemental Information)   (Data Files)

363.   G. Tarczay, M. Förstel, P. Maksyutenko, R.I. Kaiser, Formation of Higher Silanes in Low-Temperature Silane (SiH4) ices, Inorg. Chem., 55, 8776-8785  (2016).   (PDF)   (Data Files)

362.   M.J. Abplanalp, R. I. Kaiser, Complex hydrocarbon chemistry in interstellar and solar system ices revealed: a combined infrared spectroscopy and reflectron time-of-flight mass spectrometry analysis of ethane (C2H6) and D6-ethane (C2D6) ices exposed to ionizing radiation, Astrophys. J., 827, 132  (2016).   (PDF)   (Data Files)

361.   M. Förstel, Y.A. Tsegaw, P. Maksyutenko, A.M. Mebel, W. Sander, R.I. Kaiser, On the Formation of N3H3 Isomers in Irradiated Ammonia Bearing Ices: Triazene (H2NNNH) or Triimide (HNHNNH), ChemPhysChem 17, 2726-2735  (2016).   (PDF)   (Data Files)

360.   T. Yang, B.B. Dangi, R.I. Kaiser, L.W. Bertels, M. Head-Gordon, A Combined Experimental and Theoretical Study on the Formation of the 2-Methyl-1-silacycloprop-2-enylidene Molecule via Crossed Beam Reactions of the Silylidyne Radical (SiH; X2Π) with Methylacetylene (CH3CCH; X1A1) and D4-Methylacetylene(CD3CCD; X1A1), J. Phys. Chem. A, 120, 4872-4883  (2016).   (PDF)   (Supplemental Information)   (Data Files)

359.   M.J. Abplanalp, S. Gozem, A.I. Krylov, C.N. Shingledecker, E. Herbst, R.I. Kaiser, A study of interstellar aldehydes and enols as tracers of a cosmic ray-driven nonequilibrium synthesis of complex organic molecules, PNAS 113, 7727-7732  (2016).   (PDF)   (Supplemental Information)   (Nature Research Highlight)   (Data Files)

358.   T. Yang, B.B. Dangi, A. M. Thomas, B-J Sun, T-J Chou, A.H.H. Chang, R.I. Kaiser, Gas-Phase Synthesis of 1-Silacyclopenta-2,4-diene, Angew. Chem., Int. Ed, 55, 7983-7987  (2016).   (PDF)   (Supplemental Information)   (Data Files)

357.   P. Maksyutenko, M. Förstel, P. Crandall, B-J Sun, M.H. Wu, A.H.H. Chang, R.I. Kaiser, An isomer-specific study of solid nitromethane decomposition pathways - Detection of aci-nitromethane (H2CNO(OH)) and nitrosomethanol (HOCH2NO) intermediates, Chem. Phys. Lett., 658, 20-29  (2016).   (PDF)   (Supplemental Information)   (Data Files)

356.   T. Yang, B.B. Dangi, A. M. Thomas, R.I. Kaiser, Untangling the Reaction Dynamics of the Silylidyne Radical (SiH; X2Π) with Acetylene (C2H2; X1Σg+), Chem. Phys. Lett., 654, 58-62  (2016).   (PDF)   (Data Files)

355.   S. Góbi, M.J. Abplanalp, R.I. Kaiser, Effect of Perchlorates on Electron Radiolysis of Glycine with Application to Mars, Astrophys. J. 822, 8  (2016).   (PDF)   (Data Files)

354.   B.M. McMurtry, A.M. Turner, S.E.J. Saito, R.I. Kaiser, On the formation of Niacin (Vitamin B3) and Pyridine Carboxylic Acids in Interstellar Model Ices, Chem. Phys. 472, 173  (2016).   (PDF)   (Data Files)

353.   A.M. Turner, M.J. Abplanalp, R.I. Kaiser, Mechanistic Studies on the Radiolytic Decomposition of Perchlorates on the Martian Surface, Astrophys. J. 820, 127  (2016).   (PDF)   (Data Files)

352.   M. Förstel, P. Maksyutenko, B.M. Jones, B-J Sun, H.C. Lee, A.H.H. Chang, R.I. Kaiser, On the Formation of Amide Polymers via Carbonyl-Amino Group Linkages in Energetically Processed Ices of Astrophysical Relevance, Astrophys. J. 820, 117  (2016).   (PDF)   (Data Files)

351.   Y.A. Tsegaw, W. Sander, R.I. Kaiser, Electron Paramagnetic Resonance Spectroscopic Study on Nonequilibrium Reaction Pathways in the Photolysis of Solid Nitromethane (CH3NO2) and D3-Nitromethane (CD3NO2), J. Phys. Chem. A. 120, 1577-1587  (2016).   (PDF)   (Data Files)

350.   A.M. Turner, M.J. Abplanalp, R.I. Kaiser, Probing the Carbon-phosphorus Bond Coupling in Low-temperature Phosphine (PH3)-Methane (CH4) Interstellar Ice Analogues, Astrophys. J. 819, 97  (2016).   (PDF)   (Data Files)

349.   M. Förstel, P. Maksyutenko, A.M. Mebel, R.I. Kaiser, Pentacarbon dioxide (C5O2) formation and its role as a tracer of solar system evolution, Astrophys. J., Lett. 818:L30, 1-6  (2016).   (PDF)   (Data Files)

348.   M. Förstel, P. Maksyutenko, B.M. Jones, B-J Sun, A.H.H. Chang, R. I. Kaiser, Synthesis of urea in cometary model ices and implications for Comet 67P/Churyumov-Gerasimenko, Chem. Comm. 52, 741-744  (2016).   (PDF)   (Supplemental Information)   (Data Files)

347.   M.J. Abplanalp, M. Förstel, and R.I. Kaiser, Exploiting single photon vacuum ultraviolet photoionization to unravel the synthesis of complex organic molecules in interstellar ices, Chem. Phys. Letters, 644, 79-98  (2016).   (PDF)   (Data Files)

346.   D.S.N. Parker, T. Yang, B.B. Dangi, R.I. Kaiser, P.P. Bera, and T.J. Lee, Low Temperature Formation of Nitrogen-substituted Polycyclic Aromatic Hydrocarbons (PANHs)- Barrierless Routes to Dihydro(iso)quinolines, Astrophys. J., 815, 11  (2015).   (PDF)   (Data Files)

345.   T. Yang, B.B. Dangi, P. Maksyutenko, R.I. Kaiser, L.W. Bertels, and M. Head-Gordon, Combined Experimental and Theoretical Study on the Formation of the Elusive 2-Methyl-1-silacycloprop-2-enylidene Molecule under Single Collision Conditions via Reactions of the Silylidyne Radical (SiH; X2Π) with Allene (H2CCCH2; X1A1) and D4-Allene (D2CCCD2; X1A1), J. Phys. Chem. A, 119, 12562-12578  (2015).   (PDF)   (Supplemental Information)   (Data Files)

344.   D.S.N. Parker, R.I. Kaiser, O. Kostko, T.P. Troy, M. Ahmed, B-J Sun, S-H Chen, A.H.H. Chang, On the formation of pyridine in the interstellar medium, Phys. Chem. Chem. Phys., 17, 32000-32008  (2015).   (PDF)   (Data Files)

343.   M.J. Abplanalp, A. Borsuk, B.M. Jones, R.I. Kaiser, On the Formation and Isomer Specific Detection of Propenal (C2H3CHO) and Cyclopropanone (c-C3H4O) in Interstellar Model Ices-A Combined FTIR and Reflectron Time-of-Flight Mass Spectroscopic Study, Astrophys. J., 814, 45  (2015).   (PDF)   (Data Files)

342.   M. Förstel, P. Maksyutenko, B.M. Jones, B-J Sun, S-H Chen, A.H.H. Chang, R.I. Kaiser, Detection of the Elusive Triazane Molecule (N3H5) in the Gas Phase, ChemPhysChem 16, 3139-3142  (2015).   (PDF)   (Supplemental Information)   (Data Files)

341.   A.M. Mebel, R.I. Kaiser, Formation of resonantly stabilised free radicals via the reactions of atomic carbon, dicarbon, and tricarbon with unsaturated hydrocarbons: theory and crossed molecular beams experiments, International Reviews in Physical Chemistry. 17, 21564-21575  (2015).   (PDF)

340.   T. Yang, L. Muzangwa, R.I. Kaiser, A. Jamal, and K. Morokuma, A Combined Crossed Molecular Beam and Theoretical Investigation of the Reaction of the Meta-tolyl Radical with Vinylacetylene- toward the Formation of Methylnaphthalenes, Phys. Chem. Chem. Phys. 34, 461-514  (2015).   (PDF)   (Supplemental Information)   (Data Files)

339.   A.M. Turner, M.J. Abplanalp, S.Y. Chen, Y.T. Chen, A.H.H. Chang, R.I. Kaiser A Photoionization Mass Spectroscopic Study on the Formation of Phosphanes in Low Temperature Phosphine Ices, Phys. Chem. Chem. Phys. 17, 27281-27291  (2015).   (PDF)   (Supplemental Information)   (Data Files)

338.   D.S.N. Parker, R.I. Kaiser, T.P. Troy, O. Kostko and M. Ahmed, Toward the Oxidation of the Phenyl Radical and Prevention of PAH Formation in Combustion Systems, J. Phys. Chem. A 119, 7145-7154  (2015).   (PDF)   (Data Files)

337.   D.S.N. Parker, R.I. Kaiser, O. Kostko and M. Ahmed, Selective Formation of Indene through the Reaction of Benzyl Radicals with Acetylene, ChemPhysChem 16, 2091-2093  (2015).   (PDF)   (Data Files)

336.   R.I. Kaiser, P. Maksyutenko, Novel Reaction Mechanisms Pathways in the Electron Induced Decomposition of Solid Nitromethane (CH3NO2) and D3- Nitromethane (CD3NO2), J. Phys. Chem. C 119, 14653-14668  (2015).   (PDF)   (Data Files)

335.   S. Thorwirth, R.I. Kaiser, K.N. Crabtree, M. C. McCarthy, Spectroscopic and structural characterization of three silaisocyanides: exploring an elusive class of reactive molecules at high resolution, Chem. Comm. 51, 11305  (2015).   (PDF)   (Data Files)

334.   B. B. Dangi, Y.S. Kim, S.A. Krasnokutski, R.I. Kaiser, C.W. Bauschlicher Jr, Toward the Formation of Carbonaceous Refractory Matter in High Temperature Hydrocarbon-rich Atmospheres of Exoplanets Upon Micrometeoroid Impact, Astrophys. J., 805:76, 1-7  (2015).   (PDF)   (Data Files)

333.   R.I. Kaiser, P. Maksyutenko, A Mechanistical Study on Non-Equilibrium Reaction Pathways in Solid Nitromethane (CH3NO2) and D3-nitromethane (CD3NO2) upon Interaction with Ionizing Radiation, Chem. Phys. Lett. 631-632, 59-65  (2015).   (PDF)   (Data Files)

332.   D.S.N. Parker, R.I. Kaiser, B. Bandyopadhyay, O. Kostko, T.P. Troy, M. Ahmed, Unexpected Chemistry from the Reaction of Naphthyl and Acetylene at Combustion-Like Temperatures, Angew. Chem., Int. Ed. 54, 5421-5424  (2015).   (PDF)   (Data Files)

331.   D.S.N. Parker, R.I. Kaiser, O. Kostko, T.P. Troy, M. Ahmed, A.M. Mebel, A.G.G.M. Tielens, Gas Phase Synthesis of (Iso)Quinoline and Its Role in the Formation of Nucleobases in the Interstellar Medium, Ap J., 803:53, 1-10  (2015).   (PDF)   (Data Files)

330.   T. Yang, D.S.N. Parker, B.B. Dangi, R.I. Kaiser and A.M. Mebel, Formation of 5- and 6-methyl-1H-indene (C10H10) via the Reactions of the Para-tolyl Radical (C6H4CH3) with Allene (H2CCCH2) and Methylacetylene (HCCCH3) under Single Collision Conditions, Phys. Chem. Chem. Phys., 17, 10510-10519 (2015).   (PDF)   (Data Files)

329.   S. Maity, B.B. Dangi, D.S.N. Parker, R.I. Kaiser, H-M Lin, H-P E, B-J Sun, A.H.H. Chang, Combined Crossed Molecular Beam and ab Initio Investigation of the Reaction of Boron Monoxide (BO; X2Σ+) with 1,3-Butadiene (CH2CHCHCH2; X1Ag) and its Deuterated Counterparts , J. Phys. Chem. A,119, 1094-1107  (2015).   (PDF)

328.   L. Muzangwa, T. Yang, D.S.N. Parker, R.I. Kaiser, A.M. Mebel, A. Jamal, M. Ryazantsev, K. Morokuma, A Crossed Molecular Beam and Ab Initio Study on the Formation of 5- and 6-Methyl-1,4-Dihydronaphthalene (C11H12) via the Reaction of Meta-Tolyl (C7H7) with 1,3-Butadiene (C4H6), Phys. Chem. Chem. Phys., 17, 7699-7706  (2015).   (PDF)

327.   P. Maksyutenko, L.G Muzangwa, B.M. Jones, R.I. Kaiser, Lyman α Photolysis of Solid Nitromethane (CH3NO2) and D3-Nitromethane (CD3NO2) - Untangling the Reaction Mechanisms Involved in the Decomposition of Model Energetic Materials, Phys. Chem. Chem. Phys. 17, 7514 - 7527  (2015).   (PDF)   (Data Files)

326.   S. Maity, R.I. Kaiser, and B.M. Jones, Formation of complex organic molecules in methanol and methanol-carbon monoxide ice exposed to ionizing radiation - a combined FTIR and reflectron time-of-flight mass spectrometry study, Phys. Chem. Chem. Phys., 17, 3081 - 3114  (2015).   (PDF)   (Supplemental Information)

325.   R.I. Kaiser, S. Maity, B.M. Jones, Synthesis of Prebiotic Glycerol in Interstellar Ices, Angew. Chem., Int. Ed., 54, 195-200 (2015).   (PDF)

324.   T. Yang, L. Muzangwa, D.S.N. Parker, R.I. Kaiser, A.M. Mebel, Formation of 2- and 1-Methyl-1,4-Dihydronaphthalene Isomers via the Crossed Beam Reactions of Phenyl Radicals (C6H5) with Isoprene (CH2C(CH3)CHCH2) and 1,3-Pentadiene (CH2CHCHCHCH3), Phys. Chem. Chem. Phys., 17, 530-540  (2015).   (PDF)   (Supplemental Information)   (Data Files)

323.   R.I. Kaiser, D. S. N. Parker, A. M. Mebel, Reaction Dynamics in Astrochemistry: Low-Temperature Pathways to Polycyclic Aromatic Hydrocarbons in the Interstellar Medium, Annual Reviews of Physical Chemistry. 66, 43-47  (2015).   (PDF)

322.   D.S.N. Parker, B.B. Dangi, R.I. Kaiser, A. Jamal, M. Ryazantsev and K. Morokuma, Formation of 6-Methyl-1,4-dihydronaphthalene in the Reaction of the p-Tolyl Radical with 1,3-Butadiene under Single-Collision Conditions, J. Phys. Chem. A, 118, 12111-12119 (2014).   (PDF)   (Supplemental Information)

321.   S. Maity, B.B. Dangi, D.S.N. Parker, R.I. Kaiser , Y. An, B.J. Sun, A.H.H. Chang, Combined Crossed Molecular Beam and ab Initio Investigation of the Multichannel Reaction of Boron Monoxide (BO; X2Σ+) with Propylene (CH3CHCH2; X1A'): Competing Atomic Hydrogen and Methyl Loss Pathways, J. Phys. Chem. A,118, 9632-9645  (2014).   (PDF)

320.   B.J. Sun, C.H. Huang, S.Y. Chen, S.H. Chen, R.I. Kaiser, A.H.H. Chang, Theoretical Study on Reaction Mechanism of Ground-State Cyano Radical with 1,3-Butadiene: Prospect of Pyridine Formation, J. Phys. Chem. A, 118, 7715-7724  (2014).   (PDF)

319.   C.J. Bennett, C.P. Ennis, R.I. Kaiser, Implantation of Energetic D+ Ions into Carbon Dioxide Ices and Implications to our Solar System: Formation of D2O and D2CO3, Astrophys. J., 794, 57  (2014).   (PDF)

318.   R.I. Kaiser, B.B. Dangi, T. Yang, D.S.N. Parker, A.M. Mebel, Reaction Dynamics of the 4-Methylphenyl Radical (p-Tolyl) with 1,2-Butadiene (1-Methylallene): Are Methyl Groups Purely Spectators?, J. Phys. Chem. A, 118, 6181-6190  (2014).   (PDF)   (Data Files)

317.   S. Maity, R.I. Kaiser, B.M. Jones, Infrared and Reflectron Time-of-Flight Mass Spectroscopic Study on the Synthesis of Glycolaldehyde in Methanol (CH3OH) and Methanol-Carbon Monoxide (CH3OH-CO) Ices Exposed to Ionization Radiation, Faraday Discussions, 168, 485-516  (2014).   (PDF)   (Supplemental Information)

316.   T. Yang, B.B. Dangi, D.S.N. Parker, R.I. Kaiser, Y. An, A.H.H. Chang, A Combined Crossed Molecular Beams and ab initio Investigation on the Formation of Vinylsulfidoboron (C2H311B32S), Phys. Chem. Chem. Phys., 16, 17580-17587  (2014).   (PDF)   (Supplemental Information)   (Data Files)

315.   D.S.N. Parker, R.I. Kaiser, T.P. Troy, M. Ahmed, Hydrogen Abstraction/Acetylene Addition Revealed, Angew. Chem., Int. Ed., 53, 7740-7744  (2014).   (PDF)

314.   B.B. Dangi, T. Yang, R.I. Kaiser, A.M. Mebel, Reaction Dynamics of the 4-Methylphenyl Radical (C6H4CH3; p-tolyl) with Isoprene (C5H8) - Formation of Dimethyldihydronaphthalenes, Phys. Chem. Chem. Phys., 16, 16805-16814  (2014).   (PDF)   (Data Files)

313.   L. Zhou, S. Maity, M.J. Abplanalp, A.M. Turner, R.I. Kaiser, On the Radiolysis of Ethylene Ices by Energetic Electrons and Implications to the Extraterrestrial Hydrocarbon Chemistry, Astrophys. J., 790, 38  (2014).   (PDF)

312.   T. Yang, D.S.N. Parker, B.B. Dangi, R.I. Kaiser, V.V. Kislov, A.M. Mebel, Crossed Beam Reactions of the Phenyl (C6H5; X2A1) and Phenyl-d5 Radical (C6D5; X2A1) with 1,2-Butadiene (H2CCCHCH3; X1A'), J. Phys. Chem. A, 118, 4372-4381  (2014).   (PDF)   (Data Files)

311.   S. Maity, R.I. Kaiser, B.M. Jones, Formation of Ketene (H2CCO) in Interstellar Analogous Methane (CH4) - Carbon Monoxide (CO) Ices: A Combined FTIR and Reflectron Time-of-Flight Mass Spectroscopic Study, Astrophys. J., 789, 36  (2014).   (PDF)

310.   B.M. Jones, R.I. Kaiser, G. Strazzulla, Carbonic Acid as a Reserve of Carbon Dioxide on Icy Moons: The Formation of Carbon Dioxide (CO2) in a Polar Environment, Astrophys. J., 788, 170  (2014).   (PDF)

309.   B.B. Dangi, D.S.N. Parker, R.I. Kaiser, D. Belisario-Lara, A.M. Mebel, An experimental and theoretical investigation of the formation of C7H7 isomers in the bimolecular reaction of dicarbon molecules with 1,3-pentadiene, Chem. Phys. Lett., 607, 92-99  (2014).   (PDF)   (Data Files)

308.   T. Yang, D.S.N. Parker, B.B. Dangi, R.I. Kaiser, D. Stranges, Y.H. Su, S.Y. Chen, A.H.H. Chang, A.M. Mebel, Directed Gas-Phase Formation of the Ethynylsulfidoboron Molecule, J. Am. Chem. Soc., 136, 8387-8392  (2014).   (PDF)   (Supplemental Information)   (Data Files)

307.   D.S.N. Parker, S. Maity, B.B. Dangi, R.I. Kaiser, A. Landera, A.M. Mebel, Understanding the chemical dynamics of the reactions of dicarbon with 1-butyne, 2-butyne, and 1,2-butadiene - toward the formation of resonantly stabilized free radicals, Phys. Chem. Chem. Phys., 16, 12150-12163  (2014).   (PDF)

306.   S. Maity, D.S.N. Parker, R.I. Kaiser, B. Ganoe, S. Fau, A. Perera, R.J. Bartlett, Gas-Phase Synthesis of Boronylallene (H2CCCH(BO)) under Single Collision Conditions: A Cross Molecular Beams and Computational Study, J. Phys. Chem. A, 118, 3810-3819  (2014).   (PDF)

305.   B.B. Dangi, D.S.N. Parker, T. Yang, R.I. Kaiser, A.M. Mebel, Gas Phase Synthesis of the Benzyl Radical (C6H5CH2), Angew. Chem., Int. Ed., 53, 4608-4613  (2014).   (PDF)   (Data Files)

304.   D.S.N. Parker, B.B. Dangi, R.I. Kaiser, A. Jamal, M.N. Ryazantsev, K. Morokuma, A. Korte, W. Sander, An Experimental and Theoretical Study on the Formation of 2-Methylnaphthalene (C11H10 /C11H3D7) in the Reactions of the Para-Tolyl (C7H7) and Para-Tolyl-d7 (C7D7) with Vinylacetylene (C4H4), J. Phys. Chem. A, 118, 2709-2718  (2014).   (PDF)

303.   D.S.N. Parker, R.I. Kaiser, A.M. Mebel, The role of isovalency in the reactions of the cyano (CN), boron monoxide (BO), silicon nitride (SiN), and ethynyl (C2H) radicals with unsaturated hydrocarbons acetylene (C2H2) and ethylene (C2H4), Chem. Soc. Rev., 43, 2701-2713  (2014).   (PDF)

302.   D.S.N. Parker, T. Yang, R.I. Kaiser, A. Landera, A.M. Mebel, On the formation of ethynylbiphenyl (C14D5H5; C6D5C6H4CCH) isomers in the reaction of D5-phenyl radicals (C6D5; X2A1) with phenylacetylene (C6H5C2H; X1A1) under single collision conditions, Chem. Phys. Lett., 595-596, 230-236  (2014).   (PDF)

301.   R.I. Kaiser, S. Maity, B.M. Jones, Infrared and ReflectronTtime-of-Flight Mass Spectroscopic Analysis of Methane (CH4)-Carbon Monoxide (CO) Ices Exposed to Ionization Radiation - Toward the Formation of Carbonyl Bearing Molecules in Extraterrestrial Ices, Physical Chemistry Chem. Phys., 16, 3399-3424  (2014).   (PDF)

300.   C.J. Bennett, C.P. Enis, R.I. Kaiser, Experimental Studies on the Formation of D2O and D2O2 by Implantation of Energetic D+ Ions into Oxygen Ices, Astrophys. J., 782, 63  (2014).   (PDF)

299.   B.M. Jones, R.I. Kaiser, G. Strazzulla, UV-VIS, Infrared, and Mass Spectroscopy of Electron Irradiated Frozen Oxygen and Carbon Dioxide Mixtures with Water, Astrophys. J., 781, 85  (2014).   (PDF)

298.   R.I. Kaiser, S. Maity, B.B. Dangi, Y.S. Su, B-J Sun, A.H.H. Chang, A crossed molecular beam and ab initio investigation of the exclusive methyl loss pathway in the gas phase reaction of boron monoxide (BO; X2Σ+) with dimethylacetylene (CH3CCCH3; X1A1g), Phys. Chem. Chem. Phys., 16, 989-997  (2014).   (PDF)

297.   D.S.N. Parker, B.B. Dangi, N. Balucani, D. Stranges, A.M. Mebel, R.I. Kaiser, Gas-Phase Synthesis of Phenyl Oxoborane (C6H5BO) via the Reaction of Boron Monoxide with Benzene, JOC, 78, 11896-11900  (2013).   (PDF)

296.   B.B. Dangi, S. Maity, R.I. Kaiser, A.M. Mebel, A Combined Crossed Beam and Ab Initio Investigation of the Gas Phase Reaction of Dicarbon Molecules (C2; X1Σg+/a3Πu) with Propene (C3H6; X1A'): Identification of the Resonantly Stabilized Free Radicals 1- and 3-Vinylpropargyl, J. Phys. Chem. A., 117, 11783-11793  (2013).   (PDF)   (Data Files)

295.   S. Maity, D.S.N. Parker, B.B. Dangi, R.I. Kaiser, S. Fau, A. Perera, R.J. Bartlett, A Crossed Molecular Beam and Ab-Initio Investigation of the Reaction of Boron Monoxide (BO; X2Σ+) with Methylacetylene (CH3CCH; X1A1): Competing Atomic Hydrogen and Methyl Loss Pathways, J. Phys. Chem. A., 117, 11794-11807  (2013).   (PDF)

294.   D.S.N. Parker, N. Balucani, D. Stranges, R.I. Kaiser, A.M. Mebel, A Crossed Beam and ab Initio Investigation on the Formation of Boronyldiacetylene (HCCCC11BO; X1Σ+) via the Reaction of the Boron Monoxide Radical (11BO; X2Σ+) with Diacetylene (C4H2; X1Σg+), J. Phys. Chem. A., 117, 8189-8198  (2013).   (PDF)

293.   S. Maity, R.I. Kaiser, Electron Irradiation of Carbon Disulfide - Oxygen Ices: Toward the Formation of Sulfur-Bearing Molecules in Interstellar Ices, Astrophys. J. 773, 184/1-184/8  (2013).   (PDF)

292.   B.B. Dangi, D.S.N. Parker, R.I. Kaiser, A. Jamal, A.M. Mebel, A Combined Experimental and Theoretical Study on the Gas-Phase Synthesis of Toluene under Single Collision Conditions, Angew. Chem., Int. Ed., 52, 7186-7189  (2013).   (PDF)   (Data Files)

291.   C.J. Bennett, S.J. Brotton, B.M. Jones, A.K. Misra, S. Sharma, R.I. Kaiser, High Sensitivity Raman Spectrometer to Study Pristine and Irradiated Interstellar Ice Analogs, Analytical Chemistry 85, 5659-5665  (2013).   (PDF)

290.   S. Maity, Y.S. Kim, R.I. Kaiser, H.C.C. Chang, On the Detection of Higher Order Carbon Sulfides (CSx ; x = 4-6) in Low Temperature Carbon Disulfide Ices, Chem. Phys. Lett. 577, 42-47  (2013).   (PDF)

289.   S.J. Brotton, R.I. Kaiser, Novel high-temperature and pressure-compatible ultrasonic levitator apparatus coupled to Raman and Fourier transform infrared spectrometers, Rev. Sci. Instrum. 84, 055114  (2013).   (PDF)

288.   B.M. Jones, R.I. Kaiser, Application of Reflectron Time-of-Flight Mass Spectroscopy in the Analysis of Astrophysically Relevant Ices Exposed to Ionization Radiation: Methane (CH4) and D4-Methane (CD4) as a Case Study, J. Phys Chem. Lett. 4, 1965-1971  (2013).   (PDF)

287.   D.S.N. Parker, A.V. Wilson, R.I. Kaiser, N.J. Mayhall, M. Head-Gordon, A.G.G.M. Tielens, On the Formation of Silacyclopropenylidene (c-SiC2H2) and its Role in the Organosilicon Chemistry in the Interstellar Medium, Astrophys. J., 770, 33  (2013).   (PDF)

286.   Y.S. Kim, K.P. Wo, S. Maity, S.K. Atreya, and R.I. Kaiser, Radiation-Induced Formation of Chlorine Oxides and Their Potential Role in the Origin of Martian Perchlorates, J. Am. Chem. Soc., 135, 4910-4913  (2013).   (PDF)

285.   S.J. Brotton, and R.I. Kaiser, In Situ Raman Spectroscopic Study of Gypsum (CaSO4 ⋅ 2H2O) and Epsomite (MgSO4 ⋅ 7H2O) Dehydration Utilizing an Ultrasonic Levitator, J. Phys. Chem. Lett., 4, 669-673  (2013).   (PDF)

284.   R.I. Kaiser, A.M. Stockton, Y.S. Kim, E.C. Jensen, R.A. Mathies, On the Formation of Dipeptides in Interstellar Model Ices, Astrophys. J., 765, 111  (2013).   (PDF)

283.   A. Golan, M. Ahmed, A.M. Mebel, R.I. Kaiser, A VUV Photoionization Study on the Multichannel Reaction of Phenyl Radicals with 1,3-butadiene Under Combustion Relevant Conditions, Phys. Chem. Chem. Phys., 15, 341-347  (2013).   (PDF)

282.   A.E. Tomosada, Y.S. Kim, A.H.H. Chang, R.I. Kaiser, First Detection of the Silylgermylene (H3SiGeH) and D4-Silylgermylene (D3SiGeD) Molecules in Low Temperature Silane-Germane Ices, Chem. Phys., 409, 49-60  (2012).   (PDF)

281.   R.I. Kaiser, S.P. Krishtal, A.M. Mebel, O. Kostko, M. Ahmed, An Experimental and Theoretical Study of the Ionization Energies of SiC2Hx (x = 0, 1, 2) Isomers. Astrophys. J., 761, 178  (2012).   (PDF)

280.   D.S.N. Parker, A.V. Wilson, R.I. Kaiser, T. Labrador, A.M. Mebel, Gas-Phase Synthesis of the Silaisocyanoethylene Molecule (C2H3NSi), JOC, 77, 8574  (2012).   (PDF)

279.   Y.S. Kim, R.I. Kaiser, Electron Irradiation of Kuiper Belt Surface Ices: Ternary N2 - CH4 - CO Mixtures As A Case Study, Astrophys. J., 758, 37  (2012).   (PDF)

278.   D.S.N. Parker, A.W. Wilson, R.I. Kaiser, T. Labrador, A.M. Mebel, Synthesis of the Silaisocyanoacetylene Molecule, J. Am. Chem. Soc., 134, 13896-13901  (2012).   (PDF)

277.   R.I. Kaiser, A.M. Mebel, On the Formation of Polyacetylenes and Cyanopolyacetylenes in Titans Atmosphere and their Role in Astrobiology, Chem. Rev. Soc. 41, 5490-5501  (2012).   (PDF)

276.   D.S.N. Parker, F. Zhang, P. Matsuyenko, R.I. Kaiser, S.H. Chen, A.H.H. Chang, A Crossed Beam and Ab Initio Investigation On The Formation of Vinyl Boron Monoxide (C2H3BO; X1A') via Reaction of Boron Monoxide (11BO; X2Σ+) with ethylene (C2H4; X1Ag), Phys. Chem. Chem. Phys., 14, 11099-11106  (2012).   (PDF)

275.   R.I. Kaiser, D.S.N. Parker, F. Zhang, A. Landera, V.V. Kislov, A.M. Mebel, PAH Formation under Single Collision Conditions: Reaction of Phenyl Radical and 1,3-Butadiene to Form 1,4-Dihydronaphthalene, J. Phys. Chem. A, 116, 4248-4258  (2012).   (PDF)

274.   F. Zhang, R.I. Kaiser, A. Golan, M. Ahmed, H. Hansen, A VUV Photoionization Study of the Combustion-Relevant Reaction of the Phenyl Radical (C6H5) with Propylene (C3H6) in a High Temperature Chemical Reactor, J. Phys. Chem. A, 116, 3541-3546  (2012).   (PDF)

273.   H. Khari, R.I. Kaiser, J. Head, A theoretical investigation of the relative stability of hydrated glycine and methylcarbamic acid-from water clusters to interstellar ices, Phys. Chem. Chem. Phys, 14, 4942-4958  (2012).   (PDF)

272.   D.S.N. Parker, F. Zhang, Y.S. Kim, R.I. Kaiser, A. Landera, A.M. Mebel, On the Formation of Phenyldiacetylene (C6H5CCCCH) and D5-Phenyldiacetylene (C6D5CCCCH) Studied Under Single Collision Conditions, Phys. Chem. Chem. Phys, 14, 2997-3003  (2012).   (PDF)

271.   C. Ennis, R.I. Kaiser, On the Formation of Ozone in Solar System Oxygen Ices Exposed to Heavy Ions, Astrophys. J., 745, 103-110  (2012).   (PDF)

270.   D.S.N. Parker, F. Zhang, Y.S. Kim, R.I. Kaiser, A. Landera, V.V. Kislov, A.M. Mebel, A.G.G.M. Tielens, Low Temperature Formation of Naphthalene and its Role in the Synthesis of PAHs (Polycyclic Aromatic Hydrocarbons) in the Interstellar Medium, PNAS, 109, 53-58  (2012).   (PDF)   (SI)

269.   R.I. Kaiser, D.S.N. Parker, M. Goswami, F. Zhang, V.V. Kislov, A.M. Mebel, J. Aguilera-Iparraguirre, W.H. Green, Crossed Beam Reaction of Phenyl and D5-Phenyl Radicals with Propene and Deuterated Counterparts-Competing Atomic Hydrogen and Methyl Loss Pathways, Phys. Chem. Chem. Phys, 14, 720-729  (2012).   (PDF)

268.   R.I. Kaiser, X. Gu, F. Zhang, P. Maksyuntenko, Crossed Beam Reaction of Methylidyne [CH(X2Π)] with D2-Acetylene [C2D2(X1Σg+)] and D1-Methylidyne [CD(X2Π)] with Acetylene [C2D2(X1Σg+)], Phys. Chem. Chem. Phys, 14, 575-588  (2012).   (PDF)

267.   F. Zhang, P. Maksyuntenko, R.I. Kaiser, Chemical Dynamics of the CH(X2Π)] + C2H4(X1A1g), CH(X2Π) + C2D4(X1A1g), and CD(X2Π) + C2H4(X1A1g) Reactions Studied Under Single Collision Conditions, Phys. Chem. Chem. Phys, 14, 529-537  (2012).   (PDF)

266.   A.V. Wilson, D.S.N. Parker, F. Zhang, R.I. Kaiser, Crossed Beam Study of the Atom-Radical Reaction of Ground State Carbon Atoms (C(3P)) with the Vinyl Radical (C2H3(X2A')), Phys. Chem. Chem. Phys, 14, 477-481  (2012).   (PDF)

265.   S.B. Morales, C.J. Bennett, S.D. Le Picard, A. Canosa, I.R. Sims, B-J Sun, P.H. Chen, A.H.H. Chang, V.V. Kislov, A.M. Mebel, X. Gu, F. Zhang, P. Maksyutenko, R.I. Kaiser, A Crossed Molecular Beam, Low-Temperature Kinetics, and Theoretical Inverstigation of the Reaction of the Cyano Radical (CN) with 1,3-Butandiene (C4H6). A Route to Complex Nitrogen-Bearing Molecules in Low-Temperature Extraterrestrial Environments, Astrophys. J., 742, 26-35  (2011).   (PDF)

264.   D.S.N. Parker, F. Zhang, R.I. Kaiser, V. Kislov, A.M. Mebel, Indene Formation under Single-Collision Conditions from Reaction of Phenyl Radicals with Allene and Methylacetylene - A Crossed Molecular Beam and Ab Initio Study, Chem. Asian J., 6, 3035-3042  (2011).   (PDF)

263.   D.S.N. Parker, F. Zhang, R.I. Kaiser, Phenoxy Radical (C6H5O) Formation under Single Collision Conditions from Reaction of the Phenyl Radical (C6H5, X2A1) with Molecular Oxygen (O2, X3Σg-): The Final Chapter?, J. Phys. Chem. A, 115, 11515-11518  (2011).   (PDF)

262.   C. Ennis, H. Yuan, S.J. Sibener, R.I. Kaiser, On The Chemical Processing of Hydrocarbon Surfaces by Fast Oxygen Ions, Phys. Chem. Chem. Phys., 13, 17870-17884  (2011).   (PDF)

261.   R.I. Kaiser, M. Goswami, P. Maksyutenko, F. Zhang, Y.S. Kim, A. Landera, A.M. Mebel, A Crossed Molecular Beams and Abm Initio Study on the Formation of C6H3 Radicals. An Interface between Resonantly Stabilized and Aromatic Radicals, J. Phys. Chem. A., 115, 10251-10258  (2011).   (PDF)

260.   P. Maksyutenko, D.S.N. Parker, F. Zhang, R.I. Kaiser, An LIF Characterization of Supersonic BO (X2Σ+) and CN (X2Σ+) Radical Sources for Crossed Beam Studies, RSI, 82, 083107/1-7  (2011).   (PDF)

259.   R.I. Kaiser, W. Zheng, Y. Osumura, A.H.H. Chang, Low Temperature Spectroscopy and Irradiation Effects on Solar System Ices - Kuiper Belt Objects as a Case Study, Phys. Chem. Chem. Phys., 13, 15747-15748  (2011).   (PDF)

258.   H. Kayi, R.I. Kaiser, J.D. Head, A Theoretical Investigation of the Low Energy Conformers of the Isomers Glycine and Methylcarbamic Acid and Their Role in the Interstellar Medium, Phys. Chem. Chem. Phys., 13, 15774-15784  (2011).   (PDF)

257.   Y.S. Kim, F. Zhang, R.I. Kaiser, Laboratory Simulation of Kuiper Belt Object Volatile Ices under Ionizing Radiation: CO-N2 Ices as a Case Study, Phys. Chem. Chem. Phys., 13, 15766-15773  (2011).   (PDF)

256.   W. Zheng, Y.S. Kim, R.I. Kaiser, Formation of Nitric Oxide and Nitrous Oxide in electron-irradiated H218O/N2 Ice Mixtures-Evidence for the Existence of Free Oxygen Atoms in interstellar and Solar System Analog Ices, Phys. Chem. Chem. Phys., 13, 15749-15754  (2011).   (PDF)

255.   F. Zhang, R.I. Kaiser, V.V. Kislov, A.M. Mebel, A. Golan, M. Ahmed, A VUV Photoionization Study of the Formation of the Indene Molecule and Its Isomers, J. Phys. Chem. Lett., 2, 1731-1735  (2011).   (PDF)

254.   H. Kayi, R.I. Kaiser, J.D. Head, A Computational Study on the Structures of Methylamine-Carbon Dioxide-Water Clusters: Evidence for the Barrier Free Formation of the Methylcarbamic Acid Zwitterion (CH3NH2+COO-) in Interstellar Water Ices, Phys. Chem. Chem. Phys. 13, 11083-11098  (2011).   (PDF)

253.   B.M. Jones, C.J. Bennett, R.I. Kaiser, Mechanistical Studies on the Production of Formamide (H2NCHO) within Interstellar Ice Analogs, Astrophys. J. 734:78, 1-12  (2011).   (PDF)

252.   C.P. Ennis, C.J. Bennett, B.M. Jones, R.I. Kaiser, Formation of D2-Water and D2-Carbonic Acid in Oxygen-Rich Solar System Ices via D2+ Irradiation, Astrophys. J. 733:79, 1-11  (2011).   (PDF)

251.   C.P. Ennis, C.J. Bennett, R.I. Kaiser, On the Formation of Ozone in Oxygen-rich Solar System Ices via Ionizing Radiation, Phys. Chem. Chem. Phys. 13, 9469-9482  (2011).   (PDF)

250.   D.S.N. Parker, F. Zhang, P. Maksyutenko, R.I. Kaiser, A.H.H. Chang, A Crossed Beam and ab initio Investigation of the Reaction of Boron Monoxide (11BO; X2Σ+) with Acetylene (C2H2; X1Σg+), Phys. Chem. Chem. Phys. 13, 8560-8570  (2011).   (PDF)

249.   N.L. Evans, S. Ullrich, C.J. Bennett, R.I. Kaiser, On the Interaction of Adenine with Ionizing Radiation: Mechanistical Studies and Astrobiological Implications, Astrophys. J. 730:69, 1-10  (2011).   (PDF)

248.   Y.S. Kim, R.I. Kaiser, On the Formation of Amines (RNH2) and the Cyanide Anion (CN-) in Electron-Irradiated Ammonia-Hydrocarbon Interstellar Model Ices, Astrophys. J. 729:68, 1-7  (2011).   (PDF)

247.   D.S.N. Parker, F. Zhang, Y.S. Kim, R.I. Kaiser, A.M. Mebel, On the Formation of Resonantly Stabilized C5H3 Radicals - A Crossed Beam and Ab Initio Study of the Reaction of Ground State Carbon Atoms with Vinylacetylene, J. Phys. Chem. A 115, 593-601  (2011).   (PDF)

246.   F. Zhang, D.S.N. Parker, Y.S. Kim, R.I. Kaiser, A.M. Mebel, On the Formation of Ortho-benzyne (o-C6H4) Under Single Collision Conditions and its Role in Interstellar Chemistry, Astrophys. J. 728:141, 1-10  (2011).   (PDF)

245.   A. Quinto-Hernandez, A.M. Wodtke, C.J. Bennett, Y.S. Kim, R.I. Kaiser, On the Interaction of Methyl Azide (CH3N3) Ices with Ionizing Radiation: Formation of Methanimine (CH2NH), Hydrogen Cyanide (HCN), and Hydrogen Isocyanide (HNC), J. Phys. Chem. A 115, 250-264  (2011).   (PDF)

244.   A. Landera, R.I. Kaiser, A.M. Mebel, Addition of One and Two Units of C2H to Styrene: A Theoretical Study of the C10H9 and C12H9 Systems and Implications towards Growth of Polycyclic Aromatic Hydrocarbons at Low Temperatures, J. Chem. Phys. 134, 024302/1-13  (2011).   (PDF)

243.   B.M. Jones, F. Zhang, R.I. Kaiser, A. Jamal, A.M. Mebel, M.A. Cordiner, S.B. Charnley, Formation of Benzene in the Interstellar Medium, PNAS 108, 452-457  (2011).   (PDF)

242.   C.J. Bennett, T. Hama, Y.S. Kim, M. Kawasaki, R.I. Kaiser, Laboratory Studies on the Formation of Formic Acid (HCOOH) in Interstellar and Cometary Ices, Astrophys. J. 727, 27-37  (2011).   (PDF)

241.   B. Sivaraman, A.M. Mebel, N.J. Mason, D. Babikov, R.I. Kaiser, On the Electron-Induced Isotope Fractionation in Low Temperature 32O2/36O2 Ices - Ozone as a Case Study, Phys. Chem. Chem. Phys. 13, 421-427  (2011).   (PDF)

240.   P. Maksyutenko, F. Zhang, X. Gu, R.I. Kaiser, A Crossed Molecular Beam Study on the Reaction of Methylidyne Radicals [CH(X2Π)] with Acetylene [C2H2(X1Σg+)] - Competing C3H2 + H and C3H + H2 Channels, Phys. Chem. Chem. Phys. 13, 240-252  (2011).   (PDF)

239.   R.I. Kaiser, P. Maksyutenko, C. Ennis, F. Zhang, X. Gu, A.M. Mebel, O. Kostko, M. Ahmed, Untangling the Chemical Evolution of Titan's Atmosphere and Surface - From Homogeneous to Heterogeneous Chemistry, Faraday Discussion 147: Chemistry of the Planets, 429-478  (2010).   (PDF)

238.   Y.S. Kim, R.I. Kaiser, Abiotic Formation of Carboxylic Acids (RCOOH) in Interstellar and Solar System Model Ices, Astrophys. J. 725, 1002-1010  (2010).   (PDF)

237.   F. Zhang, P. Maksyutenko, R.I. Kaiser, A.M. Mebel, A. Gregusova, S. Ajith Perera, R.J. Bartlett, Gas Phase Synthesis of the Imidoborane Molecule (HNBH) - An Isoelectronic Molecule of Acetylene (HCCH), J. Phys. Chem. A 114, 12148-12154  (2010).   (PDF)

236.   C.P. Ennis, R.I. Kaiser, Mechanistical Studies on the Electron-Induced Degradation of Polymers: polymethylmethacrylate and Kapton, Phys. Chem. Chem. Phys. 12, 14902-14915  (2010).   (PDF)

235.   C.P. Ennis, R.I. Kaiser, Mechanistical Studies on the Electron-Induced Degradation of Polymers: Polyethylene, Polytetrafluoroethylene, and Polystyrene, Phys. Chem. Chem. Phys. 12, 14884-14901  (2010).   (PDF)

234.   C.J. Bennett, B. Jones, E. Knox, J. Perry, Y.S. Kim, R.I. Kaiser, Mechanistical Studies on the Formation and Nature of the "XCN" (OCN-) Species in Interstellar Ices, Astrophys. J. 723, 641-648  (2010).   (PDF)

233.   P. Maksyutenko, F. Zhang, Y.S. Kim, R.I. Kaiser, S.H. Chen, C.C. Wu, A.H.H. Chang, Untangling the Chemical Dynamics of the Reaction of Boron Atoms, 11B(2Pj), with Diacetylene, C4H2(X1Σg+) - A Crossed Molecular Beams and Ab Initio Study, J. Phys. Chem. A 114, 10936-10943  (2010).   (PDF)

232.   J. He, K. Gao, G. Vidali, C.J. Bennett, R.I. Kaiser, Formation of Molecular Hydrogen from Methane Ice, Astrophys. J., 721, 1656-1662  (2010).   (PDF)

231.   N. Balucani, F. Zhang, R.I. Kaiser, Elementary Reactions of Boron Atoms with Hydrocarbons - Toward the Formation of Organo-Boron Compounds, Chem. Rev. 110, 5107-5127  (2010).   (PDF)

230.   B. Jones, P. Matsyutenko N.C. Su, A.H.H. Chang, R.I. Kaiser, Crossed Molecular Beam Study on the Ground State Reaction of Atomic Boron [B(2Pj)] with Hydrogen Cyanide [HCN(X1Σ+)], J. Phys. Chem. A 114, 8999-9006  (2010).   (PDF)

229.   R.I. Kaiser, B-J Sun, H.M. Lin, A.H.H. Chang, A.M. Mebel, O. Kostko, M. Ahmed, An Experimental and Theoretical Study on the Ionization Energies of Polyynes (H(CC)nH; n = 1-9), Astrophys. J. 719, 1884-1889  (2010).   (PDF)

228.   A.D. Estillore, L.M. Visger, R.I. Kaiser, A.G. Suits, Crossed-Beam Imaging of the H Abstraction Channel in the Reaction of CN with 1-Pentene, J. Phys. Chem. Lett. 1, 2417-2421  (2010).   (PDF)

227.   C.J. Bennett, S.B. Morales, S.D. Le Picard, A. Canosa, I.R. Sims, Y.H. Shih, A.H.H. Chang, X. Gu, F. Zhang, R.I. Kaiser, A chemical dynamics, kinetics, and theoretical study on the reaction of the cyano radical (CN; X2Σ+) with phenylacetylene (C6H5CCH; X1A1), Phys. Chem. Chem. Phys. 12, 8737-8749  (2010).   (PDF)

226.   L. Zhou, W. Zheng, R.I. Kaiser, A. Landera, A.M. Mebel, M.C. Liang, Cosmic-Ray-Mediated Formation of Benzene on the Surface of Saturn's Moon Titan, Astrophys. J. 718, 1243-1251  (2010).   (PDF)

225.   O. Kostko, J. Zhou, B-J Sun, J.S. Lie, A.H.H. Chang, R.I. Kaiser, M. Ahmed, Determination of Ionization Energies of CnN (n = 4 - 12): Vacuum Ultraviolet Photoionization Experiments and Theoretical Calculations, Astrophys. J. 717, 674-682  (2010).   (PDF)

224.   R.I. Kaiser, W. Carrier, Y. Osamura, R.M. Mahfouz, Infrared Spectroscopic Detection of the Methylgermyl (H2GeCH3) Radical and its Perdeuterated Counterpart in Low Temperature Matrices, Chem. Phys. Lett. 492, 226-234  (2010).   (PDF)

223.   C. Huang, F. Zhang, R.I. Kaiser, V.V. Kislov, A.M. Mebel, R. Silva, W.K. Gichuhi, A.G. Suits, Photodissociation of the Diacetylene Dimer and Implications for Hydrocarbon Growth in Titan's Atmosphere, Astrophys. J. 714, 1249-1255  (2010).   (PDF)

222.   B. Jones, F. Zhang, P. Maksyutenko, A.M. Mebel, R.I. Kaiser, Crossed Molecular Beam Study on the Formation of Phenylacetylene and Its Relevance to Titan's Atmosphere, J. Phys. Chem. A 114, 5256-5262  (2010).   (PDF)

221.   W. Zheng, R.I. Kaiser, Formation of Hydroxylamine (NH2OH) in Electron-Irradiated Ammonia-Water Ices, J. Phys. Chem. A 114, 5251-5255  (2010).   (PDF)

220.   C.J. Bennett, C.S. Jamieson, R.I. Kaiser, Mechanistical Studies on the Formation and Destruction of Carbon Monoxide (CO), Carbon Dioxide (CO2), and Carbon Trioxide (CO3) in Interstellar Ice Analog Samples, Phys. Chem. Chem. Phys. 12, 4032-4050  (2010).   (PDF)

219.   F. Zhang, B. Jones, P. Maksyutenko, R.I. Kaiser, C. Chin, V.V. Kislov, A.M. Mebel, Formation of the Phenyl Radical [C6H5(X2A1)] under Single Collision Conditions: A Crossed Molecular Beam and Ab Initio Study, J. Am. Chem. Soc. 132, 2672-2683  (2010).   (PDF)

218.   Y.S. Kim, C.J. Bennett, L. Sheng, O'Brian, R.I. Kaiser, Laboratory Study on the Irradiation of Solid Ethane Analog Ices and Implications to Titan's Chemistry, Astrophys. J. 711, 744-756  (2010).   (PDF)

217.   R.I. Kaiser, Reaction Dynamics of Carbon-Centered Radicals in Extreme Environments Studied by the Crossed Molecular Beams Technique, Carbon-Centered Radicals: Structure, Dynamics and Reactivity. Malcolm D. E. Forbes, Editor, Wiley, p. 221-248  (2010).

216.   R.I. Kaiser, A.M. Mebel, O. Kostko, M. Ahmed. On the Ionization Energies of C4H3 Isomers, Chem. Phys. Lett. 485, 281-285  (2010).   (PDF)

215.   C.H. Huang, R.I. Kaiser, A.H.H. Chang, Theoretical Study on the Reaction of Ground State Cyano Radical with Propylene in Titan's Atmosphere, J. Phys. Chem. A 113, 12675-12685  (2009).   (PDF)

214.   S. Krishtal, A.M. Mebel, R.I. Kaiser, A Theoretical Study of the Reaction Mechanism and Product Branching Ratios of C2H + C2H4 and Related Reactions on the C4H5 Potential Energy Surface, J. Phys. Chem. A (Special Issue) 113, 11112-11128  (2009).   (PDF)

213.   F. Zhang, S. Kim, R.I. Kaiser, S.P. Krishtal, A.M. Mebel, Crossed Molecular Beams Study on the Formation of Vinylacetylene in Titan's Atmosphere, J. Phys. Chem. A (Special Issue) 113, 11167-11173  (2009).   (PDF)

212.   W. Zheng, D.C. Jewitt, R.I. Kaiser, On the State of Water Ice on Saturn's Moon Titan and Implications to Icy Bodies in the Outer Solar System, J. Phys. Chem. A (Special Issue) 113, 11174-11181  (2009).   (PDF)

211.   R.I. Kaiser, F. Zhang, X. Gu, V.V. Kislov, A.M. Mebel, Reaction Dynamics of the Phenyl Radical (C6H5) with 1-Butyne (HCCC2H5) and 2-Butyne (CH3CCCH3), Chem. Phys. Lett. 481, 46-53  (2009).   (PDF)

210.   X. Gu, Y.S. Kim, R.I. Kaiser, A.M. Mebel, M.C. Liang, Y.L. Yung, Chemical Dynamics of Triacetylene Formation and Implications to the synthesis of polyynes in Titan's Atmosphere, PNAS 106, 16078-16083  (2009).   (PDF)

209.   R.I. Kaiser, X. Gu, Chemical Dynamics of the Formation of the Ethynylsilylidyne Radical (SiCCH(X2Π)) in the Crossed Beam Reaction of Ground State Silicon Atoms (Si(3P)) with Acetylene (C2H2(X1Σg+)), J. Chem. Phys. 131, 104311/1-6  (2009).   (PDF)

208.   J. Sun, C.H. Huang,, M.F. Tsai, H.L. Sun, L.G. Gao, Y.S. Wang, Y.Y. Yeh, Y.H. Shih, Z.F. Sia, P.H. Chen, R.I. Kaiser, A.H.H. Chang, Synthesis of Interstellar 1,3,5-Heptatriynylidyne, C7H(X2Π), via the Neutral-Neutral Reaction of Ground State Carbon Atom, C(3P) with Triacetylene, HC6H.(X1Σg+), J. Chem. Phys. 131, 104305/1-13  (2009).   (PDF)

207.   X. Gu, R.I. Kaiser, A.M. Mebel, V.V. Kislov, S.J. Klippenstein, L.B. Harding, M.C. Liang, Y.L. Yung, A Crossed Molecular Beams Study on the Formation of the Exotic Cyanoethynyl Radical in Titan's Atmosphere, Astrophys. J. 701 1797-1803  (2009).   (PDF)

206.   F. Zhang, S. Kim, R.I. Kaiser, A.M. Mebel, A Crossed Beams and Ab Initio Investigation on the Formation of Cyanodiacetylene in the Reaction of Cyano Radicals with Diacetylene, J. Chem. Phys. 130 234308  (2009).   (PDF)

205.   F. Zhang, S. Kim, R.I. Kaiser, A Crossed Molecular Beams Study of the Reaction of the Ethynyl Radical (C2H(X2Σ+) with Allene (H2CCCH2(X1A1)), Phys. Chem. Chem. Phys. 11, 4707-4714  (2009).   (PDF)

204.   C.J. Bennett, C.S. Jamieson, R.I. Kaiser, Mechanistical Studies on the Formation of Carbon Dioxide in Extraterrestrial, Carbon Monoxide Ice Analog Samples, Phys. Chem. Chem. Phys. 11, 4210-4218  (2009).   (PDF)

203.   X. Gu, F Zhang, R.I. Kaiser, V.V. Kislov, A.M. Mebel, Reaction Dynamics of the Phenyl Radical with 1,2-Butadiene, Chem. Phys. Lett. 474, 51-56  (2009).   (PDF)

202.   L. Zhou, R.I. Kaiser, A.T. Tokunaga, Infrared Spectroscopy of Crystalline and Amorphous Diacetylene (C4H2) and Implications to Titan's Atmospheric Conditon, Planet. Space Sciences 57, 830-835  (2009).   (PDF)

201.   C.J. Bennett, C.S. Jamieson, R.I. Kaiser, An Experimental Investigation of the Decomposition of Carbon Monoxide and Formation Routes to Carbon Dioxide in Interstellar Ices, Astrophys. J. Suppl. Ser. 182, 1-11  (2009).   (PDF)

200.   C.S. Jamieson, A.H.H. Chang, R.I. Kaiser, A laboratory study on the thermally induced transformation of hydrogen cyanide (HCN) to the cyanogen anion (CN-) in Solar System analog ices, Advances in Space Research 43 1446-1450  (2009).   (PDF)

199.   Y.S. Kim, R.I. Kaiser, An Infrared Spectroscopic Study of Amorphous and Crystalline Ices of Vinylacetylene and Implications for Saturn's Satellite Titan, Astrophys. J. Suppl. Ser. 181, 543-547  (2009).   (PDF)

198.   W. Zheng, D.C. Jewitt, R.I. Kaiser, Infrared Spectra of Ammonia-Water Ices, Astrophys. J. Suppl. Ser. 181, 53-61  (2009).   (PDF)

197.   X. Gu, R.I. Kaiser, Reaction Dynamics of Phenyl Radicals in Extreme Environments: A Crossed Molecular Beam Study, Acc. Chem. Res. 42, 290-302  (2009).   (PDF)

196.   F. Zhang, Y.S. Kim, R.I. Kaiser, A.M. Mebel, On the Formation of the 1,3,5-Hexatriynyl Radical (C6H(X2Π)) via the Crossed Beams Reaction of Dicarbon (C2(X1Σg+/a3Πu)), with Diacetylene (C4H2(X1Σg+)), J. Phys. Chem. A 113, 1210-1217  (2009).   (PDF)

195.   X. Gu, F. Zhang, R.I. Kaiser, A Crossed Molecular Beam Study of the Phenyl Radical Reaction with 1,3-Butadiene and its Deuterated Isotopomers, J. Phys. Chem. A 113, 998-1006  (2009).   (PDF)

194.   R.I. Kaiser, A.M. Mebel, On the Formation of Higher Carbon Oxides in Extreme Environments, Invited Frontiers Article. Chem. Phys. Lett. 465, 1-9  (2008).   (PDF)

193.   L. Zhou, R.I. Kaiser, L.G. Gao, A.H.H. Chang, M.C. Liang, Y.Y. Yung, Pathways to Oxygen-Bearing Molecules in the Interstellar Medium and in Planetary Atmospheres: Cylopropenone (c-C3H2O) and Propynal (HCCCHO), Astrophys. J. 686, 1493-1502  (2008).   (PDF)

192.   F. Zhang, Y.S. Kim, L. Zhou, A.H.H. Chang, R.I. Kaiser, Directed Gas Phase Synthesis of the Interstellar 2,4-Pentadiynylidyne Radical (HCCCCC), J. Chem. Phys. 129, 134313  (2008).   (PDF)

191.   A. M. Mebel, V.V. Kislov, R.I. Kaiser, Photoinduced Mechanism of Formation and Growth of Polycyclic Aromatic Hydrocarbons in Low-Temperature Environments via Successive Ethynyl Radical Additions, J. Am. Chem. Soc. 130, 13618-13629  (2008).   (PDF)

190.   X. Gu, F. Zhang, R.I. Kaiser, Reaction Dynamics on the Formation of 1- and 3-Cyanopropylene in the Crossed Beams Reaction of Ground State Cyano Radicals (CN) with Propylene (C3H6) and Its Deuterated Isotopologues, J. Phys. Chem. A 112, 9607-9613  (2008).   (PDF)

189.   C.J. Bennett, C.S. Jamieson, R.I. Kaiser, Mechanistical Studies on the Decomposition of Carbon Suboxide in a Cometary Ice Analog, Planet. Space Sciences 56, 1181-1189  (2008).   (PDF)

188.   A. Landera, A.M. Mebel, R.I. Kaiser, Theoretical Study of the Reaction Mechanism of Ethynyl Radical with Benzene and Related Reactions on the C8H7 Potential Energy Surface, Chem. Phys. Lett. 459, 54-59  (2008).   (PDF)

187.   C.Y. Huang, B-J. Sun, H.H. Kuo, K.T. Chen, H.L. Sun, C.H. Huang, M.F. Tsai, C.H. Kao, Y.S. Wang, L.G. Gao, R.I. Kaiser, Formation of Interstellar 4-Pentadiynylidene,HCCCCC(X2Π), via the Neutral-Neutral Reaction of Ground State Carbon, C(3P) with Diacetylene, HCCCCH(X1Σg+), J. Chem. Phys. 128, 244303/1-16  (2008).   (PDF)

186.   A. Landera, S.P. Krishtal, V.V. Kislov, A.M. Mebel, R.I. Kaiser, Theoretical Study of the C6H3 Potential Energy Surface and Rate Constants and Product Branching Ratios of the C2H(2Σ+) + C4H2(1Σg+) and C4H(2Σ+) + C2H2(1Σ+) Reactions, J. Chem. Phys. 128, 214301/1-12  (2008).   (PDF)

185.   F. Zhang, X. Gu, R.I. Kaiser, N. Balucani, A.H.H. Chang, A Crossed Beam and Ab Initio Study of the Reaction of Atomic Boron with Ethylene, J. Phys. Chem. A 112, 3837-3845  (2008).   (PDF)

184.   F. Zhang, X. Gu, Y. Guo, R.I. Kaiser, Reaction Dynamics of Phenyl Radicals (C6H5) with Propylene (CH3CHCH2) and Its Deuterated Isotopologues, J. Phys. Chem. A 112, 3284-3290  (2008).   (PDF)

183.   F. Zhang, X. Gu, R.I. Kaiser, Formation of the Diphenyl Molecule in the Crossed Beam Reaction of Phenyl Radicals with Benzene, J. Chem. Phys. 128, 084315/1-5  (2008).   (PDF)

182.   X. Gu, R.I. Kaiser, A.M. Mebel, Chemistry of Energetically Activated Cumulenes - From Allene (H2CCCH2) to Hexapentaene (H2CCCCCCH2), Invited Review. ChemPhysChem 9, 350-369  (2008).   (PDF)

181.   W. Zheng, D.C. Jewitt, Y. Osamura, R.I. Kaiser, Formation of Nitrogen and Hydrogen-Bearing Molecules in Solid Ammonia and Implications for Solar System and Interstellar Ices, Astrophys. J. 674, 1242-1250  (2008).   (PDF)

180.   F. Zhang, C.H. Kao, A.H.H. Chang, X. Gu, Y. Guo, R.I Kaiser, A Crossed Molecular Beam Study on the Reaction of Boron Atoms with Methylacetylene and Partially Deuterated Methylacetylene, ChemPhysChem 9, 95-105  (2008).   (PDF)

179.   C.S. Jamieson, A.M. Mebel, R.I. Kaiser, First detection of the Cs Symmetric Isomer of Carbon Hexaoxide (CO6) at 10 K, Chem. Phys. Lett 450, 312-317  (2008).   (PDF)

178.   F. Zhang, X. Gu, R.I. Kaiser, H.F. Bettinger, A Reinvestigation of the Gas Phase Reaction of Boron Atoms, 11B(2Pj)/10B(2Pj) with Acetylene, C2H2(X1Σg+), Chem. Phys. Lett. 450 178-185  (2008).   (PDF)

177.   F. Zhang, A.H.H. Chang, X. Gu, R.I. Kaiser, A Crossed Molecular Beam Study on the Reaction of Boron Atoms, B(2Pj), with Allene, H2CCCH2(X1A1), J. Phys. Chem. A 111, 13305-13310  (2007).   (PDF)

176.   M.J. Mottl, B.T. Glazer, R.I. Kaiser, K.J. Meech, Water and Astrobiology, Geochemistry 67, 253-282  (2007).   (PDF)

175.   W. Zheng, R.I. Kaiser, On the Formation of Carbonic Acid (H2CO3) in Solar System Ices, Chem. Phys. Lett. 450, 55-60  (2007).   (PDF)

174.   X. Gu, Y. Guo, A.M. Mebel, R.I. Kaiser, A Crossed Beams Investigation of the Reactions of Tricarbon Molecules, C3(X1Σg+), with Acetylene, C2H2(X1Σg+), Ethylene, C2H4(X1Ag), and Benzene C6H6(X1A1g), Chem. Phys. Lett. 449, 44-52  (2007).   (PDF)

173.   A.M. Mebel, V. V. Kislov, R.I. Kaiser, Theoretical Studies of Potential Energy Surfaces and Product Branching Ratios for the Reactions of C2 with Small Unsaturated Hydrocarbons (Acetylene, Ethylene, Methylacetylene, and Allene), Gas Phase Molecular Reaction and Photodissociation Dynamics, Editors: K.C. Lin and P.D. Kleiber, Transworld Research Network, pp. 113-159  (2007).   (PDF)

172.   X. Gu, F. Zhang, Y. Guo, R.I. Kaiser, Reaction Dynamics of Phenyl Radicals (C6H5, X2A') with Methylacetylene (CH3CCH(X1A1)), Allene (H2CCCH2(X1A1)), and Their D4-Isotopomers, J. Phys. Chem. A 111, 11450-11459  (2007).   (PDF)

171.   B. Sivaraman, C.S. Jamieson, N.J. Mason, R.I. Kaiser, Temperature-Dependent Formation of Ozone in Solar Oxygen by 5 keV Electron Irraditation and Implications for System Ices, Astrophys. J. 669, 1414-1421  (2007).   (PDF)

170.   X. Gu, F. Zhang, R.I. Kaiser, A Crossed Beam Reaction of the Phenyl Radical, (C6H5, X2A1) with Molecular Oxygen (O2; X3Σg-): Observation of the Phenoxy Radical, (C6H5O, X2A'), Chem. Phys. Lett. 448, 7-10  (2007).   (PDF)

169.   F. Zhang, X. Gu, Y. Guo, R.I. Kaiser, Reaction Dynamics on the Formation of Styrene: A Crossed Molecular Beam Study of the Reaction of Phenyl Radicals with Ethylene, J. Organic Chem. 72, 7597-7604  (2007).   (PDF)

168.   X. Gu, F. Zhang, Y. Guo, R.I. Kaiser, A Crossed Molecular Beam Study on the Formation of Phenylacetylene from Phenyl Radicals and Acetylene, Angew. Chem., Int. Ed., 46, 6866-6869  (2007).   (PDF)

167.   X. Gu, Y. Guo, F. Zhang, A.M. Mebel, R.I. Kaiser, Unimolecular Decomposition of Chemically Activated Singlet and Triplet D3-Methyldiacetylene Molecules, Chem. Phys. Lett. 444, 220-225  (2007).   (PDF)

166.   C.S. Jamieson, A.M. Mebel, R.I. Kaiser, First detection of the C2 symmetric Isomer of Carbon Pentaoxide (CO5) at 10 K, Chem. Phys. Lett. 443, 49-54  (2007).   (PDF)

165.   A.M. Mebel, G.S. Kim, V.V. Kislov, R.I. Kaiser, The Reaction of Tricarbon with Acetylene: An Ab Initio/RRKM Study of the Potential Energy Surface and Product Branching Ratios, J. Phys. Chem. A 111, 6704-6712  (2007).   (PDF)

164.   J.G. Longenecker, A.M. Mebel, R.I. Kaiser, First Infrared Spectroscopic Detection of the Monobridged (B2H5; C2v) Diboranyl Radical in Low Temperature Diborane Ices, Inorg. Chem. 46, 5739-2743  (2007).   (PDF)

163.   X. Gu, Y. Guo, F. Zhang, A.M. Mebel, R.I. Kaiser, A Crossed Molecular Beams Study on the Formation and Energetics of the Resonantly Stabilized Free i-C4H3(X2A1) radical, and its Isotopomers, Chem. Phys. 335, 95-108  (2007).   (PDF)

162.   C.J. Bennett, R.I. Kaiser, On the Formation of Glycolaldehyde (HCOCH2OH) and Methyl Formate (HCOOCH3) in Interstellar Ice Analogs, Astrophys. J. 661, 899-909  (2007).   (PDF)

161.   Y. Guo, A.M. Mebel, F. Zhang, X. Gu, R.I. Kaiser, Crossed Molecular Beam Studies of the Reactions of Allyl Radicals, C3H5(X2A2) with Methylacetylene (CH3CCH(X1A1)), Allene (H2CCCH2(X1A1)), and Their Isotopomers, J. Phys. Chem. A 111, 4914-4921  (2007).   (PDF)

160.   R.I. Kaiser, L. Belau, S.R. Leone, M. Ahmed, Y. Wang, B.J. Braams, J. Bowman, A Combined Experimental and Computational Study on the Ionization Energies of the Cyclic and Linear C3H Isomers, ChemPhysChem 8, 1236-1239  (2007).   (PDF)

159.   W. Zheng, R.I. Kaiser, An Infrared Spectroscopy Study of the Phase Transition in Solid Ammonia, Chem. Phys. Lett. 440, 229-234  (2007).   (PDF)

158.   W. Zheng, D.C. Jewitt, R.I. Kaiser, Mechanistical Studies on the Formation of Hydrogen Peroxide (HOOH), Hydrotrioxy (HOOO), and Dihydro gentrioxide (HOOOH) in Electron-Irradiated H218O/O2 Ice Mixtures, Phys. Chem. Chem. Phys. 20, 2556-2563  (2007).   (PDF)

157.   F. Zhang, Y. Guo, X. Gu, R.I. Kaiser, A Crossed Molecular Beam Study on the Reaction of Boron Atoms, B(2Pj), with Benzene, C6H6 (X1A1g), and D6-bezene C6D6(X1A1g), Chem. Phys. Lett. 440, 56-63  (2007).   (PDF)

156.   C.S. Jamieson, R. I. Kaiser, Isotopic Study of the Formation of the Azide Radical (N3), Chem. Phys. Lett. 440, 98-104  (2007).   (PDF)

155.   C.S. Jamieson, A.M. Mebel, R.I. Kaiser, Novel Detection of the C2v Isomer of Carbon Tetraoxide (CO4), Chem. Phys. Lett. 440, 105-109  (2007).   (PDF)

154.   C.J. Bennett, S.H.Chen, B-J Sun, A.H.H. Chang, R.I. Kaiser, Mechanistical Studies on the Irradiation of Methanol in Extraterrestrial Ices, Astrophys. J. 660, 1588-1608  (2007).   (PDF)

153.   C.J. Bennett, R.I. Kaiser, The Formation of Acetic Acid (CH3COOH) in Interstellar Ice Analogs, Astrophys. J. 660, 1289-1295  (2007).   (PDF)

152.   Y. Guo, X. Gu, F. Zhang, A.M. Mebel, R.I. Kaiser, A Crossed Molecular Beam Study on the Formation of Hexenediynyl Radicals (H2CCCCCCH; C6H3 (X2A')) via Reactions of Tricarbon Molecules, C3(X1 Σg+), with Allene (H2CCCH2; X1A1) and Methylacetylene (CH3CCH; X1A1), Phys. Chem. Chem. Phys, 9, 1972-1979  (2007).   (PDF)

151.   Y. Guo, X. Gu, F. Zhang, B-J Sun, M.F. Tsai, A.H.H. Chang, R.I. Kaiser, Unraveling the Formation of HCPH (X2A') Molecules in Extraterrestrial Environments: Crossed Molecular Beam Study of the Reaction of Carbon Atoms, C(3Pj), with Phosphine, PH3(X1A1), J. Phys. Chem. A. 111, 3241-3247  (2007).   (PDF)

150.   X. Gu,Y. Guo, F. Zhang, R.I. Kaiser, Investigating the Chemical Dynamics of the Reaction of Ground-State Carbon Atoms with Acetylene and Its Isotopomers, J. Phys. Chem. A. 111, 2980-2992  (2007).   (PDF)

149.   X. Gu,Y. Guo, R.I. Kaiser, Mass Spectra of the 2,4-Pentadiynylidyne (C5H; X2П) and the 2,4-Pentadiynyl-1 (n-C5H3; X2B1) Radicals, Int. J. Mass Spectrometry 261, 100-107  (2007).   (PDF)

148.   X. Gu,Y. Guo, F. Zhang, A.M. Mebel, R.I. Kaiser, A Crossed Molecular Beams Study of the Reaction of Dicarbon Molecules with Benzene, Chem. Phys. Lett 436, 7-14  (2007).   (PDF)

147.   W. Carrier, C.S.Jamieson, R.I. Kaiser, Mechanistic Studies on the Formation of Trifluoromethyl Sulfur Pentafluoride, SF5CF3 - A Greenhouse Gas, Inorg. Chem. 46, 1332-1336  (2007).   (PDF)

146.   W. Zheng, D.C. Jewitt, R.I. Kaiser, Electron Irradiation of Crystalline and Amorphous D2O Ice, Chem. Phys. Lett. 435, 289-294  (2007).   (PDF)

145.   W. Carrier, W. Zheng, Y. Osamura, R.I. Kaiser, Laboratory Investigations on the Infrared Absorptions of Germanium-Bearing Molecules--Directing the Identification of Organo-Germanium Molecules in the Atmospheres of Jupiter and Saturn, Astrophys. J., 654, 687-692  (2007).   (PDF)

144.   Y. Guo, X. Gu, F. Zhang, A.H.H. Chang, R.I. Kaiser, A Crossed Beams Study of the Reaction of Carbon Atoms, C(3Pj), with Vinyl Cyanide, C2H3CN(X1A') - Investigating the Formation of Cyano Propargyl Radicals, Phys. Chem. Chem. Phys, 8, 5454 - 5461  (2006).   (PDF)

143.   C.S. Jamieson, Y. Guo, X. Gu, F. Zhang, C.J. Bennett, R.I. Kaiser, Laboratory Studies on the Formation of Carbon-Bearing Molecules in Extraterrestrial Environments - From the Gas Phase to the Solid State, Proceedings of the NASA Laboratory Astrophysics Workshop; NASA Special Issue, CP - 2006, 214549, 68-71  (2006).

142.   Y. Guo, X. Gu, F. Zhang, A.M. Mebel, R. I. Kaiser, Reaction Dynamics of Small Carbon Clusters with Unsaturated Hydrocarbons in the Interstellar Medium, in: Astrochemistry - From Laboratory Studies to Observations. American Institute of Physics, 855, 42-54  (2006).

141.   C.S. Jamieson, A.M. Mebel, R.I. Kaiser Investigating the Formation of Intermediates in the Reactions of Carbon dioxide (CO2) with Suprathermal Oxygen and Nitrogen Atoms, in: Astrochemistry - From Laboratory Studies to Observations. American Institute of Physics, 855, 100-106  (2006).

140.   Y. Guo, V.V. Kislov, X. Gu, F. Zhang, A.M. Mebel, R.I. Kaiser, A Combined Experimental and Theoretical Study of the Reaction of Dicarbon (C2) with D1-Acetylene (HCCD): Possible Mechanisms for Deuterium enrichment in the interstellar D1-Butadiynyl Radical, (CCCCD(X2Σ+)), Astrophys. J., 653, 1577-1582  (2006).   (PDF)

139.   Y. Chin, R.I. Kaiser, C. Lemme, C. Henkel, Detection of Interstellar Cyanoallene and its implications for Astrochemistry in: Astrochemistry - From Laboratory Studies to Observations, American Institute of Physics, 855, 149-153  (2006).

138.   C.S. Jamieson, A.M. Mebel, R.I. Kaiser, Identification of the D3h isomer of carbon trioxide (CO3) and its implications for atmospheric chemistry, ChemPhysChem, 7, 2508-2513  (2006).   (PDF)

137.   Y. Ge, K. Olsen, R.I. Kaiser, J.D. Head, The potential energy surface of the H2O2 system, in: Astrochemistry - From Laboratory Studies to Observations, American Institute of Physics, 855, 253-259  (2006).

136.   Y. Osamura, R.I. Kaiser, A Computational study of Si2H and Si2H2 species as candidates of interstellar molecules in: Astrochemistry - From Laboratory Studies to Observations, American Institute of Physics, 855, 289-295  (2006).

135.   N.J. Mason, A. Dawes, P.D. Holtom, R.J. Mukerji, M. P. Davis, B. Sivaraman, R.I. Kaiser, S.V. Hoffmann, D.A. Shaw, VUV Spectroscopy of Extraterrestrial Ices in: Astrochemistry - From Laboratory Studies to Observations, American Institute of Physics, 855, 128-142  (2006).

134.   A. M. Mebel, V. V. Kislov, R. I. Kaiser, Ab Initio/RRKM Study of the Singlet C4H4 Potential Energy Surface and of the Reactions of C2(X1 Σg+) with C2H4(X1A1g) and C(1D) with C3H4 (Allene and Methylacetylene), J. Chem. Phys. 125, 133113-1/15(2006).   (PDF)

133.   N.J. Mason, A. Dawes, P.D. Holtom, R.J. Mukerji, M.P. Davis, B. Sivaraman, R.I. Kaiser, S.V. Hoffman, D.A. Shaw, VUV spectroscopy and photo-processing of astrochemical ices: An experimental study, Faraday Discussion 133: Chemical Evolution of the Universe, 311-329  (2006).   (PDF)

132.   R.I. Kaiser, P. Bernath, Y. Osamura, S. Petrie, A.M. Mebel, Astrochemistry-From Laboratory Studies to Observations, Amwerican Institute of Physics, New York  (2006).

131.   C.J. Bennett, C.S. Jamieson, Y. Osamura, R.I. Kaiser, Laboratory studies on the irradiation of methane in interstellar, cometary, and solar system ices, Astrophys. J., 653, 792-811  (2006).   (PDF)

130.   W. Carrier, W. Zheng, Y. Osamura, R.I. Kaiser, Infrared spectroscopic identification of digermene, Ge2H4 (X1Ag), and of the digermenyl radical, Ge2H3(X2A"), together with their deuterated counterparts in low temperature germane matrices, Chem. Phys 330, 275-286  (2006).   (PDF)

129.   X. Gu, Y. Guo, F. Zhang, A.M. Mebel, R.I. Kaiser, Reaction Dynamics of Carbon-Bearing Radicals in Circumstellar Envelopes of Carbon Stars, Faraday Discussion 133: Chemical Evolution of the Universe, 245-275  (2006).   (PDF)

128.   Y. Guo, X. Gu, F. Zhang, A.M. Mebel, R.I. Kaiser, Unimolecular Decomposition of Chemically Activated Pentatetraene (H2CCCCCH2) Intermediates - A Crossed Beams Study of Dicarbon Molecule Reactions with Allene, J. Phys. Chem. A 110, 10699-10707  (2006).   (PDF)

127.   W. Zheng, D. Jewitt, R.I. Kaiser, Temperature Dependence on the Formation of Hydrogen, Oxygen, and Hydrogen Peroxide in Electron-Irradiated Crystalline Water Ice, Astrophys. J. 648, 753-761  (2006).   (PDF)

126.   X. Gu, Y. Guo, A.M. Mebel, R.I. Kaiser, Chemical Dynamics of the Formation of the 1,3-Butadiynyl Radical (C4H(X2 Σ+)) and its Isotopomers, J. Phys. Chem. A, 110, 11265-11278  (2006).   (PDF)

125.   W. Carrier, W. Zheng, Y. Osamura, R.I. Kaiser, First infrared spectroscopic characterization of digermyl (Ge2H5) and d5-digermyl (Ge2D5) radicals in low temperature germane matrices, Chem. Phys. 325, 499-508  (2006).   (PDF)

124.   Y. Guo, X. Gu, N. Balucani, R.I. Kaiser, Formation of the 2,4-pentadiynyl-1 radical (H2CCCCCH, X2B1) in the Crossed Beams Reaction of Dicarbon Molecules with Methylacetylene, J. Phys. Chem. A 110, 6245-6249  (2006).   (PDF)

123.   X. Gu, Y. Guo, E. Kawamura, R.I. Kaiser, Characteristics and Diagnostics of a Ultrahigh Vacuum Compatible Laser Ablation Source for Crossed Molecular Beam Experiments, J. Vac. Science & Technology A, 24, 505-511  (2006).   (PDF)

122.   C.S. Jamieson, A.M. Mebel, R.I. Kaiser, Understanding the kinetics and dynamics of radiation-induced reaction pathways in carbon monoxide ice at 10 K, Astrophys. J., Suppl. Ser. 163, 184-206  (2006).   (PDF)

121.   Y. Guo, X. Gu, E. Kawamura, R.I. Kaiser, Design of a modular and versatile interlock system for ultrahigh vacuum machines: A crossed molecular beam setup as a case study, Rev. Sci. Instr. 77, 034701-(1-9)  (2006).   (PDF)

120.   Y. Guo, X. Gu, R.I. Kaiser, Mass Spectrum of the 1-Butene-3-yne-2-yl Radical (i-C4H3; X2A'), Int. J. Mass Spectrometry 249-250, 420-425  (2006).   (PDF)

119.   W. Zheng, D. Jewitt, R.I. Kaiser, Formation of Hydrogen, Oxygen, and Hydrogen Peroxide in Electron-Irradiated Crystalline Water Ice, Astrophys. J. 639, 534-548  (2006).   (PDF)

118.   A.M. Mebel, V.V. Kislov, R.I. Kaiser, Potential Energy Surface and Product Branching Ratios for the Reaction of Dicarbon,C2(X1 Σg+), with Methylacetylene, CH3CCH(X1A1): An Ab Initio/RRKM Study, J. Phys. Chem. A 110, 2421-2433  (2006).   (PDF)

117.   H.Y. Li, W.C. Cheng, Y.L. Liu, B.J. Sun, C.Y. Huang, K.T. Chen, M.S. Tang, R.I. Kaiser, A. H. H. Chang, Reaction of cyanoacetylene HCCCN(X1Σ+) with ground-state carbon atoms C(3P) in cold molecular clouds, J. Chem. Phys, 124, 44307-1-19  (2006).   (PDF)

116.   C.S. Jamieson, A.M. Mebel, R.I. Kaiser, A Matrix Isolation Study of the Cs Symmetric OCNO(X2A″) Radical, Phys. Chem. Chem. Phys. 7, 4089-4095  (2005).   (PDF)

115.   C.J. Bennett, R.I. Kaiser, Laboratory studies on the formation of ozone (O3) on icy satellites and on interstellar and cometary ices, Astrophys. J. 635, 1362-1369  (2005).   (PDF)

114.   C.J. Bennett, Y. Osamura, M.D. Lebar, R.I. Kaiser, Laboratory studies on the formation of three C2H4O isomers- acetaldehyde (CH3CHO), ethylene oxide (c-C2H4O), and vinyl alcohol (CH2CHOH) - in interstellar and cometary ices, Astrophys. J. 634, 698-711  (2005).   (PDF)

113.   X. Gu, Y. Guo, H. Chan, E. Kawamura, R.I. Kaiser, Design and Characteristics of a High-Precision Chopper Wheel Motor Driver, Rev. Sci. Instr. 76, 116103-1-3  (2005).   (PDF)

112.   X. Gu, Y.Guo, R.I. Kaiser, Mass Spectrum of the Butadiynyl Radical (C4H; X2 Σ+), Int. J. Mass Spectr. 246, 29-34  (2005).   (PDF)

111.   X. Gu, Y. Guo, E. Kawamura, R.I. Kaiser, Design of a convection-cooled, cluster-based voltage divider chain for photomultiplier tubes, Rev. Sci. Instr. 76 083115-1-6  (2005).   (PDF)

110.   R.I. Kaiser, Y. Osamura, Laboratory Studies on the Infrared Absorptions of Hydrogenated Carbon-Silicon Clusters: Directing the Identification of Organometallic SiCHx Species toward IRC+10216, Astrophys. J. 630, 1217-1223  (2005).   (PDF)

109.   D.S. Sillars, C.J. Bennett, Y. Osamura, R.I. Kaiser, Infrared spectroscopic detection of the methylsilyl (CH3SiH2, X2A') and the silylmethyl (CH2SiH3, X2A') radicals and their partially deuterated counterparts in low temperature matrices, Chem. Phys. 315, 41-52  (2005).   (PDF)

108.   P.D. Holtom, C.J. Bennett, Y. Osamura, N.J. Mason, R.I. Kaiser, A Combined Experimental and Theoretical Study on the Formation of the Amino Acid Glycine (NH2CH2COOH) and its Isomer (CH3NHCOOH) in Extraterrestrial Ices, Astrophys. J. 626 940-952  (2005).   (PDF)

107.   C.J. Bennett, C.S. Jamieson, Y. Osamura, R.I. Kaiser, A combined experimental and computational investigation on the synthesis of acetaldehyde (CH3CHO(X1A')) in interstellar ices, Astrophys. J. 624, 1097-1115  (2005).   (PDF)

106.   C.S. Jamieson, C.J. Bennett, A.M. Mebel, R.I. Kaiser, Investigating the mechanism for the formation of nitrous oxide (N2O (X1 Σ+)) in extraterrestrial ices, Astrophys. J. 624, 436-447  (2005).   (PDF)

105.   N. Balucani, R.I. Kaiser, Cyanoalkynes and Cyanopolyynes: from Crossed Beam Experiments to Astrochemistry, Polyynes: Synthesis, Properties, and Applications, F. Cataldo, ed., CRS Press, New York, 285-322  (2005).

104.   R.I. Kaiser, Y. Osamura, Infrared Spectroscopic Studies of Hydrogenated Silicon Clusters: Guiding the Search for Si2Hx Species in the Circumstellar Envelope of IRC+10216, Astron. Astrophys. 432 559-566  (2005).   (PDF)

103.   H.F. Su, R.I. Kaiser, A.H.H. Chang, A theoretical study for the reaction of vinyl cyanide C2H3CN(X1A') with the ground state carbon atoms C(3P) in cold molecular clouds, J. Chem. Phys. 122, 074320/1-20  (2005).   (PDF)

102.   C.J. Bennett, D. Sillars, Y. Osamura, R.I. Kaiser, Infrared spectroscopic identification of the methylsilylidyne (SiCH3, X2A") and the silenyl (H2CSiH, X2A') radicals in methane-silane matrices, Chem. Phys. Lett. 404, 327-335  (2005).   (PDF)

101.   D. Sillars, C.J. Bennett, Y. Osamura, R.I. Kaiser, First infrared spectroscopic characterization of the disilyl (Si2H5) and d5-disilyl (Si2D5) radicals in low temperature silane matrices, Chem. Phys. 305, 141-153  (2004).   (PDF)

100.   D. Sillars, C.J. Bennett, Y. Osamura, R.I. Kaiser, Infrared spectroscopic detection of the disilenyl (Si2H3) and d3-disilenyl (Si2D3) radicals in silane and d4-silane matrices, Chem. Phys. Lett. 392, 541-548  (2004).   (PDF)

99.   C.J. Bennett, C. Jamieson, A.M. Mebel, R.I. Kaiser, Untangling the formation of the cyclic carbon trioxide isomer in low temperature carbon dioxide ices, Phys. Chem. Chem. Phys. 6, 735-746  (2004).   (PDF)

98.   H.F. Bettinger, R.I. Kaiser, Reaction of benzene and boron atom: Mechanism of Formation of Benzoborirene and Hydrogen Atom, J. Phys. Chem. A, 108, 4576-4586  (2004).   (PDF)

97.   R.I. Kaiser, N. Balucani, N. Galland, F. Caralp, M.T. Rayez, Y. Hannachi, Unraveling the chemical dynamics of bimolecular reactions of ground state boron atoms, B(2Pj), with acetylene, C2H2(X1Σg+). Phys. Chem. Chem. Phys., 6, 2205-2210  (2004).   (PDF)

96.   R.I. Kaiser, N. Balucani, D.O. Charkin, A.M. Mebel, A crossed beam and ab initio study of the C2(X1Σg+/a3Πu) + C2H2(X1 Σg+) reactions, Chem. Phys. Lett. 382, 112-119  (2003).   (PDF)

95.   R.I. Kaiser, L. Vereecken, J. Peeters, H.F. Bettinger, P.v.R. Schleyer, H.F. Schaefer III, Elementary reactions of the phenyl radical, C6H5, with C3H4 isomers, and of benzene, C6H6, with atomic carbon in extraterrestrial environments, Astron. Astrophys., 406, 385-391  (2003).   (PDF)

94.   D. Sillars, R.I. Kaiser, N. Galland, Y. Hannachi, Crossed-beam reaction of boron atoms, B(2Pj), with dimethylacetylene, CH3CCCH3(X1A1g): Untangling the reaction dynamics to form the 1,2-dimethylene-3-bora-cyclopropane molecule, J. Phys. Chem. A, 107, 5149-5156  (2003).   (PDF)

93.   R.J. Morton, R.I. Kaiser, Kinetics of suprathermal hydrogen atom reactions with saturated hydrides in planetary and satellite atmospheres, Planet. Space Sci.s, 51, 365-373  (2003).   (PDF)

92.   T. L. Nguyen, A. M. Mebel, R. I. Kaiser, Potential Energy Surface and Product Branching Ratios for the Reaction of C(3Pj) with the Allyl Radical: An Ab Initio/RRKM Study, J. Phys. Chem. A, 107, 2990-2999 (2003).   (PDF)

91.   M. Yamada, Y. Osamura, R.I. Kaiser, A comprehensive investigation on the formation of organo-sulfur molecules in dark clouds via neutral-neutral reactions, Astron. Astrophys. 395, 1031-1044  (2002).   (PDF)

90.   F. Stahl, P.v.R. Schleyer, H.F. Schaefer III, R.I. Kaiser, Reactions of ethynyl radicals as a source of C4 and C5 hydrocarbons in Titan's atmosphere, Planet. Space Sci. 50, 685-692  (2002).   (PDF)

89.   A.M. Mebel, R.I. Kaiser, An ab initio Study on the Formation of Interstellar Tricarbon Isomers 1-C3(X1 Σg+) and c-C3(X3A'2), Chem. Phys. Lett., 360, 139-143  (2002).   (PDF)

88.   R.I. Kaiser, F. Stahl, P.v.R. Schleyer, H.F. Schaefer III, Atomic and molecular hydrogen elimination in the crossed beam reaction of d1-ethinyl radicals C2D(X2Σ+) with acetylene,C2H2(X1 Σg+): Dynamics of d1-diacetylene (HCCCCD) and d1-butadiynyl (DCCCC) formation, Phys. Chem. Chem. Phys., 4, 2950-2958  (2002).   (PDF)

87.   R.I. Kaiser, A.M. Mebel, The reactivity of ground-state carbon atoms with unsaturated hydrocarbons in combustion flames and in the interstellar medium, Int. Rev. in Physical Chemistry, 21, 307-356  (2002).   (PDF)

86.   R.I. Kaiser, H.F. Bettinger, Gas-Phase Detection of the elusive Benzoborirene Molecule, Angew. Chem., Int. Ed., 41, 2350-2352  (2002).   (PDF)

85.   R.I. Kaiser, M. Yamada, Y. Osamura, A crossed beam and ab initio investigation of the reaction of hydrogen sulfide, H2S(X1A1), with dicarbon molecules, C2(X1 Σg+), J. Phys. Chem. A, 106, 4825-4832  (2002).   (PDF)

84.   R.I. Kaiser, Experimental Investigation on the Formation of Carbon-Bearing Molecules in the Interstellar Medium via Neutral-Neutral Reactions, Chem. Rev., 102, 1309-1358  (2002).   (PDF)

83.   N. Balucani, O. Asvany, R.I. Kaiser, Y. Osamura, Formation of three C4H3N isomers from the reaction of CN(X2Σ+) with allene, H2CCCH2 (X1A1), and methylacetylene, CH3CCH (X1A1): A combined crossed beam and ab initio study, J. Phys. Chem. A 106, 4301-4311  (2002).   (PDF)

82.   L. Vereecken, J. Peeters, H.F. Bettinger, R.I. Kaiser, P.v.R. Schleyer, H.F. Schaefer III, Reaction of phenyl radicals with propyne, J. Am. Chem. Soc. 124, 2781-2789  (2002).   (PDF)

81.   R.I. Kaiser, N. Balucani, Astrobiology - The final frontier in chemical reaction dynamics, Int. J. Astrobiology 1, 15-23  (2002).   (PDF)

80.   I. Hahndorf, Y.T. Lee, R.I. Kaiser, L. Vereecken, J. Peeters, H.F. Bettinger, P.R. Schreiner, P.v.R. Schleyer, W.D. Allen, H.F. Schaefer III, A combined crossed-beam, ab initio, and Rice-Ramsperger-Kassel-Marcus investigation of the reaction of carbon atoms C(3Pj) with benzene, C6H6(X1A1g) and d6-benzene, C6D6(X1A1g), J. Chem. Phys. 116, 3248-3262  (2002).   (PDF)

79.   R.I. Kaiser, T.L. Nguyen, A.M. Mebel, Y.T. Lee, Stripping dynamics in the reactions of electronically excited carbon atoms, C(1D), with ethylene and propylene - production of propargyl and methylpropargyl radicals, J. Chem. Phys. 116, 1318-1324  (2002).   (PDF)

78.   A.M. Mebel, R.I. Kaiser, The formation of interstellar C2N isomers in circumstellar envelopes of carbon stars: an ab initio study, Astrophys. J. 564, 787-791  (2002).   (PDF)

77.   R.I. Kaiser, Y.T. Lee, Laboratory chemical dynamics in hydrocarbon rich atmospheres of outer planets, Highlights of Astronomy, Astronomical Society of the Pacific, 12, 88-91  (2002).

76.   T.L. Nguyen, A.M. Mebel, S.H. Lin, R.I. Kaiser, Product branching ratios of the C(3P) + C2H3(2A')and CH(2Π) + C2H2 (1Σg+) reactions and photodissociation of H2CC=CH(2B1) at 193 and 242 nm: An ab initio/RRKM study, J. Phys. Chem. A, 43, 9813-9818  (2001).   (PDF)

75.   R.I. Kaiser, Molecular Symmetry and Group Theory, Phys. Science Educ. Reviews 3, 25  (2001).   (PDF)

74.   R.I. Kaiser, T.L. Nguyen, T.N. Le, A.M. Mebel, An ab initio investigation of reactions of carbon atoms, C(3Pj), with C2H4 and C3H6 in the interstellar medium, Astrophys. J. 561, 858-863  (2001).   (PDF)

73.   R.I. Kaiser et al. General Discussion, Faraday Discussions 119, 353-370  (2001).   (PDF)

72.   R.I. Kaiser et al. General Discussion, Faraday Discussions 119, 255-274  (2001).   (PDF)

71.   R.I. Kaiser et al. General Discussion, Faraday Discussions 119, 121-143  (2001).   (PDF)

70.   R.I. Kaiser, T.L. Lee, T.L. Nguyen, A.M. Mebel, N. Balucani, Y.T. Lee, F. Stahl, P.v.R. Schleyer, H.F. Schaefer III, A combined crossed molecular beam and ab initio investigation of C2 and C3 elementary reactions with unsaturated hydrocarbons - pathways to hydrogen deficient hydrocarbon radicals in combustion flames, Faraday Discussion 119, 51-66  (2001).   (PDF)

69.   N. Balucani, A. M. Mebel, Y.T. Lee, R.I. Kaiser, A Combined Crossed Molecular Beam and Ab Initio Study of the Reactions C2(X1Σg+,a3Πu) + C2H4 -> n-C4H3(X2A') + H(2S1/2), J. Phys. Chem. A, 43, 9813-9818  (2001).   (PDF)

68.   R.I. Kaiser, The role of cyano (CN) and Ethynyl (C2H) Radicals in astrobiology and implications to the origin of life on Earth, ESA -Special Publication 'Exo- and Astrobiology', 496, 145-153  (2001).   (PDF)

67.   R.I. Kaiser, N. Balucani, The Formation of Nitriles in Hydrocarbon-Rich Atmospheres of Planets and Their satellites: Laboratory Investigations by the Crossed Molecular Beam Technique, Acc. Chem. Res., 34, 699-706  (2001).   (PDF)

66.   R.I. Kaiser, A.M. Mebel, Y.T. Lee, A.H.H. Chang, Unimolecular decomposition of chemically activated triplet C4HD3 complexes: a combined crossed-beam and ab initio study, J. Chem. Phys., 115, 5117-5125 (2001).   (PDF)

65.   N. Balucani, H.Y. Lee, A.M. Mebel, Y.T. Lee, R.I. Kaiser, A combined crossed beam and ab initio investigation on the reaction of carbon species with C4H6 isomers. III. 1,2-butadiene, H2CCCH(CH3) (X1A') - a non-Rice-Ramsperger-Kassel-Marcus system?, J. Chem. Phys., 115, 5107-5116  (2001).   (PDF)

64.   T.N. Le, A.M. Mebel, R.I. Kaiser, Ab Initio Study of the C4H3 Potential Energy Surface and reaction of ground-state carbon atom with propargyl radical, J. Comp. Chem. (special issue in honor of Prof. Schleyers 70th birthday), 22, 1522-1535  (2001).   (PDF)

63.   N. Balucani, O. Asvany, Y.T. Lee, R.I. Kaiser, N. Galland, M.T. Rayez, Y. Hannachi, Gas-phase detection of the HBCC(X1Σ) molecule: A combined crossed beam and computational study of the B(2P) + C2H2(1Σg+) reaction, J. Comp. Chem. (special issue in honor of Prof. Schleyers 70th birthday), 22, 1359-1365  (2001).   (PDF)

62.   C.C. Chiong, O. Asvany, N. Balucani, Y.T. Lee, R.I. Kaiser, Nucleation of hydrogen deficient carbon clusters in circumstellar envelops of carbon stars, World Scientific Press, Proceedings of the 8th Asia-Pacific Physics Conference, APPC 2000, 167-169  (2001).

61.   T.L. Nguyen, A.M. Mebel, R.I. Kaiser, A theoretical investigation of the triplet carbon atom C(3P) + vinyl radical C2H3(2A') reaction and thermochemistry of C3Hn (n=1-4) species, J. Phys. Chem. A 105, 3284-3299  (2001).   (PDF)

60.   T.N. Lee, H.Y. Lee, A.M. Mebel, R.I. Kaiser, Ab initio MO study of the triplet C3H4 potential energy surface and the reaction of C(3Pj) with ethylene, C2H4, J. Phys. Chem. A. 105, 1847-1856  (2001).   (PDF)

59.   F. Stahl, P.v.R. Schleyer, H.F. Bettinger, R.I. Kaiser, Y.T. Lee, H.F. Schaefer III, Reaction of the ethynyl radical, C2H, with methylacetylene, CH3CCH, under single collision conditions: implications for astrochemistry, J. Chem. Phys. 114, 3476-3487  (2001).   (PDF)

58.   R.I. Kaiser, C.C. Chiong, O. Asvany, Y.T. Lee, F. Stahl, P.v.R. Schleyer, H.F. Schaefer III, Chemical dynamics of d1-methyldiacetylene (CH3CCCCD; X1A1) and d1-ethynylallene (H2CCCH(C2D); X1A') formation from reaction of C2D(X2Σ+) with methylacetylene CH3CCH(X1A1), J. Chem. Phys. 114, 3488-3496  (2001).   (PDF)

57.   R.I. Kaiser, H.Y. Lee, A.M. Mebel, Y. T. Lee, The formation of C5H5 isomers as potential key intermediates to polycyclic aromatic hydrocarbon-like molecules, Astrophys. J. 548, 852-860  (2001).   (PDF)

56.   R.I. Kaiser, A. Mebel, Y.T. Lee, Chemical dynamics of cyclopropynylidyne (c-C3H; X2B2) formation from the reaction of C(1D) with acetylene, C2H2(X1Σg+), J. Chem. Phys. 114, 231-239  (2001).   (PDF)

55.   N. Balucani, O. Asvany, L.C.L. Huang, Y. T. Lee, R.I. Kaiser, Y. Osamura, H.F. Bettinger, Formation of Nitriles in the Interstellar Medium via reactions of cyano radicals, CN(X2Σ+), with unsaturated hydrocarbons, Astrophys. J. 545, 892-906  (2000).   (PDF)

54.   N. Balucani, O. Asvany, Y. T. Lee, R. I. Kaiser, N. Galland, Y. Hannachi, Observation of borirene from crossed beam reaction of boron atoms with ethylene, J. Am. Chem. Soc. 122 11234-11235  (2000).   (PDF)

53.   L.C.L. Huang, O. Asvany, A.H.H. Chang, N. Balucani, S.H. Lin, Y.T. Lee, R.I. Kaiser, Y. Osamura, Crossed beam reaction of cyano radicals with hydrocarbon molecules. IV. Chemical dynamics of cyanoacetylene (HCCCN; X1Σ+) formation from reaction of CN(X2Σ+) with acetylene, C2H2(X1Σg+), J. Chem. Phys. 113, 8656-8666  (2000).   (PDF)

52.   N. Balucani, O. Asvany, A.H.H. Chang, S.H. Lin, Y.T. Lee, R.I. Kaiser, Y. Osamura, Crossed beam reaction of cyano radicals with hydrocarbon molecules. III. Chemical dynamics of vinylcyanide (C2H3CN;X1A') formation from reaction of CN(X2Σ+) with ethylene, C2H4(X1Ag), J. Chem. Phys 113, 8643-8655  (2000).   (PDF)

51.   L.C.L. Huang, H.Y. Lee, A.M. Mebel, S.H. Lin, Y.T. Lee, R.I. Kaiser, A combined crossed beam and ab initio investigation on the reaction of carbon species with C4H6 isomers. II. The dimethylacetylene molecule, H3CCCCH3 (X1A1g), J. Chem. Phys. 113, 9637-9648  (2000).   (PDF)

50.   I. Hahndorf, H.Y. Lee, A.M. Mebel,S.H. Lin, Y.T. Lee, R.I. Kaiser, A combined crossedbeam and ab initio investigation on the reaction of carbonspecies with C4H6 isomers. I. the 1 ,3-butadiene molecule, H2CCHCHCH2 (X1A'), J. Chem. Phys. 113, 9622-9636  (2000).   (PDF)

49.   H.F. Bettinger, P.v.R. Schleyer, H.F. Schaefer III, P.R. Schreiner, R.I. Kaiser,Y.T. Lee, The reaction of benzene with a ground state carbon atom, C(3Pj), J. Chem. Phys. 113, 4250-4263  (2000).   (PDF)

48.   R.I. Kaiser, N. Balucani, O. Asvany, Y.T. Lee, Astrochemistry: From molecular clouds to Planetary systems, Y.C.Minh, E.F. van Dishoeck (eds.), Crossed molecular beam experiments of radical-neutral reactions relevant to the formation of hydrogen deficient molecules in extraterrestrial environments, IAU Series 197, 251-264  (2000).

47.   N. Balucani, O. Asvany, Y. Osamura, L.C.L. Huang, Y.T. Lee, R.I. Kaiser, Laboratory investigation on the formation of unsaturated nitriles in Titan's atmosphere, Planet. Space Sci. 48, 447-462  (2000).   (PDF)

46.   R.I. Kaiser, O. Asvany, Y.T. Lee, Crossed beam investigation of elementary reactions relevant to the formation of polycyclic aromatic hydrocarbon (PAH)-like molecules in extraterrestrial environments, Planet. Space Sci. 48,483-492 (2000).   (PDF)

45.   R.I. Kaiser, O. Asvany, Y.T. Lee, H.F. Bettinger, P.v.R. Schleyer, H.F. Schaefer III, Crossed beam reaction of phenyl radicals with unsaturated hydrocarbon molecules. I. Chemical dynamics of phenylmethylacetylene (C6H5CCCH3; X1A') formation from reaction of C6H5(X2A1) with methylacetylene, CH3CCH(X1A1,), J. Chem. Phys 112, 4994-5001  (2000).   (PDF)

44.   A.M. Mebel, R.I. Kaiser, Y.T. Lee, Ab initio MO study of the global potential energy surface of C4H4 in triplet electronic state and the reactions of C(3Pj) with C3H4 (allene and propyne) and C2(A3Пu) with C2H4(X1A1g+), J. Am. Chem. Soc. 122, 1776-1788  (2000).   (PDF)

43.   R.I. Kaiser, Book review on 'Laboratory Astrophysics and Space Research', edited by P. Ehrenfreud, C. Krafft, H. Kochan, V. Pironello, Planet. Space Sci., 48, 113-114  (2000).   (PDF)

42.   R.I. Kaiser, J.W. Ting, L.C.L. Huang, N. Balucani, O. Asvany, Y.T. Lee, H. Chan, D. Stranges, D. Gee, A versatile source to produce high-intensity, pulsed supersonic radical beam for crossed-beams experiments: the cyanogen radical CN(X2Σ+) as a case study, Rev. Sci. Instrum. 70, 4185-4191  (1999).   (PDF)

41.   N. Balucani, O. Asvany, A.H.H. Chang, S.H. Lin, Y.T. Lee, R.I. Kaiser, H.F. Bettinger, P.v.R. Schleyer, H.F. Schaefer III, Crossed beam reaction of cyano radicals with hydrocarbon molecules. II. Chemical dynamics of 1-cyano-1-methylallene (CNCH3CCCH2; X1A') formation from reaction of CN(X2Σ+) with dimethylacetylene, CH3CCCH3 (X1A1'), J. Chem. Phys. 111, 7472-7479  (1999).   (PDF)

40.   N. Balucani, O. Asvany, A.H.H. Chang, S.H. Lin, Y.T. Lee, R.I. Kaiser, H.F. Bettinger, P.v.R. Schleyer, H.F. Schaefer III, Crossed beam reaction of cyano radicals with hydrocarbon molecules. I. Chemical dynamics of cyanobenzene (C6H5CN; X1A1) and perdeutero cyanobenzene (C6D5CN; X1A1) formation from reaction of CN(X2Σ+) with benzene, C6H6(X1A1g), and d6-benzene, C6D6(X1A1g), J. Chem. Phys. 111, 7457-7471  (1999).   (PDF)

39.   L.C.L. Huang, N. Balucani, Y.T. Lee, R.I. Kaiser, Y. Osamura, Crossed beam reaction of the cyano radical, CN(X2Σ+), with methylacetylene, CH3CCH (X1A1): Observation of cyanopropyne, CH3CCCN (X1A1), and cyanoallene, H2CCCHCN (X1A'), J. Chem. Phys. 111, 2857-2860  (1999).   (PDF)

38.   R.I. Kaiser, G. Eich, A. Gabrysch, K. Roessler, The hydrogen peroxyde radical, HO2 - a potential tracer of interstellar molecular oxygen, Astron. Astrophys. 346, 340-344  (1999).   (PDF)

37.   R.I. Kaiser, A.M. Mebel, A.H.H. Chang, S.H. Lin, Y.T. Lee, Crossed-beam reaction of carbon atoms with hydrocarbon molecules. V. Chemical dynamics of n-C4H3 formation from reaction of C(3Pj) with allene, H2CCCH2 (X1A1), J. Chem. Phys. 110, 10330 - 10344  (1999).   (PDF)

36.   C. Ochsenfeld, R.I. Kaiser, Y.T. Lee, M. Head-Gordon, Coupled-Cluster ab initio investigation of singlet/triplet CH2S isomers and the reaction of atomic carbon with hydrogen sulfide to HCS/HSC, J. Chem. Phys 110, 9982-9988  (1999).   (PDF)

35.   L.C.L. Huang, Y.T. Lee, R.I. Kaiser, Crossed beam reaction of the cyanogen radical,  CN(X2Σ+),   with acetylene, C2H2(X1Σg+): Observation of cyanoacetylene, HCCCN(X1Σ+), J. Chem. Phys. 110, 7119-7122  (1999).   (PDF)

34.   R.I. Kaiser, I. Hahndorf, L.C.L. Huang, Y.T. Lee, H.F. Bettinger, P.v.R. Schleyer, H.F. Schaefer III, P.R. Schreiner, Crossed beams reaction of atomic carbon, C(3Pj), with d6-benzene, C6D6(X1A1g): Observation of the per-deutero-1,2-didehydro-cycloheptatrienyl radical, C7D5(X2B2), J. Chem. Phys. 110, 6091-6094  (1999).   (PDF)

33.   R.I. Kaiser, C. Ochsenfeld, M. Head-Gordon, Y.T. Lee, Crossed-beam reaction of carbon atoms with sulfur containing molecules. I. Chemical dynamics of thioformyl (HCS X2A') formation from reaction of C(3Pj) with hydrogen sulfide, H2S(X1A1), J. Chem. Phys.110, 2391-2403  (1999).   (PDF)

32.   R.I. Kaiser, C. Ochsenfeld, M. Head-Gordon, Y.T. Lee, Neutral-Neutral reactions in the interstellar medium. II. isotope effects in the formation of linear and cyclic C3H and C3D radicals in interstellar environments, Astrophys. J. 510 784-788  (1999).   (PDF)

31.   R.I. Kaiser et al., General Discussion, Faraday Discussion 109, 493-516  (1998).   (PDF)

30.   R.I. Kaiser et al., General Discussion, Faraday Discussion 109, 217-256  (1998).   (PDF)

29.   R.I. Kaiser et al., General Discussion, Faraday Discussion 109, 83-108  (1998).   (PDF)

28.   R.I. Kaiser, C. Ochsenfeld, D. Stranges, M. Head-Gordon, Y.T. Lee, Combined Crossed Molecular Beams and ab initio Investigation of the Formation of Carbon-bearing Molecules in the interstellar medium via neutral-neutral reactions, Farad. Discussion 109, 183-204  (1998).   (PDF)

27.   R.I. Kaiser, K. Roessler, Theoretical and laboratory studies on the interaction of cosmic-ray particles with interstellar ices. III. Suprathermal chemistry-induced formation of hydrocarbon molecules in solid methane (CH4), ethylene (C2H4), and acetylene (C2H2), Astrophys. J. 503, 959-975  (1998).   (PDF)

26.   H. Habara, S. Yamamoto, C. Ochsenfeld, M. Head-Gordon, R.I. Kaiser, Y.T. Lee, Fourier transform millimeter-wave spectroscopy of the HCS radical in the 2A' ground electronic state, J. Chem. Phys. 108, 8859-8863  (1998).   (PDF)

25.   C. Lecluse, F. Robert, R.I. Kaiser, K. Roessler, C.T. Pillinger, M. Javoy, Carbon isotopes of irradiated methane ices: implications for cometary 12C/13C ratio, Astronomy and Astrophysics 330, 1175-1179  (1998).   (PDF)

24.   R.I. Kaiser, C. Ochsenfeld, M. Head-Gordon, Y.T. Lee, The formation of HCS and HCSH Molecules and Their Role in the Collision of Comet Shoemaker-Levy 9 with Jupiter, Science 279, 1181-1184  (1998).   (PDF)

23.   R.I. Kaiser, W. Sun, A.G. Suits, Y.T. Lee, Crossed beam reaction of atomic carbon, C(3Pj), with the propargyl radical, C3H3(X2B2): Observation of diacetylene, C4H2(X1Σg+), J. Chem. Phys. 107, 8713-8716  (1997).   (PDF)

22.   R.I. Kaiser, G. Eich, A. Gabrysch, K. Roessler, Theoretical and laboratory studies on the interaction of cosmic-ray particles with interstellar ices. II. Formation of atomic and molecular hydrogen in frozen organic molecules , Astrophys. J. 484, 487-498  (1997).   (PDF)

21.   R.I. Kaiser, W. Sun, A. G. Suits, Crossed beam reaction of atomic carbon C(3Pj) with hydrogen sulfide, H2S (X1A1): observation of the thioformyl radical, HCS(X2A'), J. Chem. Phys. 106, 5288-5291  (1997).   (PDF)

20.   R.I. Kaiser, D. Stranges, H.M. Bevsek, Y.T. Lee, A.G. Suits, Crossed-beam reaction of carbon atoms with hydrocarbon molecules. IV. Chemical dynamics of methylpropargyl radical formation, C4H5, from reaction of C(3Pj) with propylene, C3H6 (X1A'), J. Chem. Phys. 106, 4945-4953  (1997).   (PDF)

19.   R.I. Kaiser, Y.T. Lee, A.G. Suits, M. Head-Gordon, A Coupled-Cluster ab initio study of triplet C3H2 and the neutral-neutral reaction to interstellar C3H, J. Chem. Phys. 106, 4141-4151  (1997).   (PDF)

18.   R.I. Kaiser, D. Stranges, Y.T. Lee, A.G. Suits, Neutral-Neutral reactions in the interstellar medium. I. formation of carbon hydride radicals via reaction of carbon atoms with unsaturated hydrocarbons, Astrophys. J. 477, 982-989  (1997).   (PDF)

17.   R.I. Kaiser, C. Ochsenfeld, M. Head-Gordon, Y.T. Lee, A.G. Suits, Crossed-beam reaction of carbon atoms with hydrocarbon molecules. III: Chemical dynamics of propynylidyne (l-C3H; X2) and cyclopropynylidyne (c-C3H; X2B2) formation from reaction of C(3Pj) with acetylene, C2H2(X1Σg+), J. Chem. Phys. 106, 1729-1741  (1997).   (PDF)

16.   R.I. Kaiser, K. Roessler, Theoretical and laboratory studies on the interaction of cosmic-ray particles with interstellar ices. I. Synthesis of polycyclic aromatic hydrocarbons by a cosmic-ray-induced multicenter mechanism, Astrophys. J. 475, 144-154  (1997).   (PDF)

15.   R.I. Kaiser, C. Ochsenfeld, M. Head-Gordon, Y.T. Lee, A.G. Suits, A combined experimental and theoretical study on the formation of interstellar C3H isomers, Science 274, 1508-1511  (1996).   (PDF)

14.   R.I. Kaiser, D. Stranges, Y.T. Lee, A.G. Suits, Crossed-beam reaction of carbon atoms with hydrocarbon molecules. II. Chemical dynamics of n-C4H3 formation from reaction of C(3Pj) with methylacetylene, CH3CCH (X1A1), J. Chem. Phys. 105, 8721-8733  (1996).   (PDF)

13.   R.I. Kaiser, Y.T. Lee, A.G. Suits, Crossed-beam reaction of carbon atoms with hydrocarbon molecules. I. Chemical dynamics of the propargyl radical formation, C3H3 (X2B2), from reaction of C(3Pj) with ethylene, C2H4 (X1Ag), J.Chem. Phys. 105, 8705-8720  (1996).   (PDF)

12.   R.I. Kaiser, Y.T. Lee, A.G. Suits, Crossed Beam Reaction of C(3Pj) with C2H2(1Σg+): Observation of Tricarbon-Hydride C3H, J. Chem. Phys. 103,10395-10398  (1995).   (PDF)

11.   R.I. Kaiser, A.G. Suits, A High-Intensity, Pulsed Supersonic Carbon Source with C(3Pj) Kinetic Energies of 0.08 - 0.7 eV for Crossed Beam Experiments, Rev. Sci. Instrum. 66, 5405-5411  (1995).   (PDF)

10.   R.I. Kaiser, P. Jansen, K. Petersen, K. Roessler, On line and in situ quantification of gas mixtures by matrix interval algebra assisted quadrupole mass spectrometry, Rev. Sci. Instrum. 66, 5226-5231  (1995).   (PDF)

9.   R.I. Kaiser, A. Gabrysch, K. Roessler, Cosmic ray simulator: A versatile apparatus for quantitative studies on the interaction of cosmic rays with frozen solids by on line and in situ quadrupole mass spectrometry and Fourier transform infrared spectroscopy, Rev. Sci. Instrum. 66, 3058-3066  (1995).   (PDF)

8.   R.I. Kaiser, MeV-Ionen induzierte chemische Reaktionen in festem Methan, Ethen und Ethin. Theoretische und experimentelle Studien zur Wechselwirkung kosmischer Strahlung mit extraterrestrischen Eiskoerpern, Report-Juel-2856, 143 pp. (1993).

7.   K. Roessler, R.I. Kaiser, E. Langenscheidt, Strahlenchemie von Koerpern des Sonnensystems in Laborsimulationen, in Proceedings 8. Kometenwerkstatt, K. Roessler, K. Thiel eds., Forschungszentrum Juelich GmbH, Juelich  (1993), 127-137.

6.   R.I. Kaiser, K. Roessler, Modification of primordial ices by cosmic rays as simulated by cyclotron irradiation in: Asteroids, Comets, Meteors, A.W. Harris, E. Bowell eds., LPI, Houston, 293-295  (1993).

5.   R.I. Kaiser, K. Roessler, Cosmic ray modification of organic cometary matter as simulated by cyclotron irradiation, Ann. Geophys. 10, 222-225  (1992).

4.   R.M. Mahfouz, M. Sauer, S.T. Atwa, R.I. Kaiser, K. Roessler, Interaction of MeV ions and VUV photons with polymers and high molecular hydrocarbons, Nucl. Instr. Meth. B 65, 447-451  (1992).   (PDF)

3.   R.I. Kaiser, J. Lauterwein, P. Mueller, K. Roessler, Energy density effects in the formation of organic residues in frozen methane by MeV ions, Nucl. Instr. Meth. B 65, 463-467  (1992).   (PDF)

2.   R.I. Kaiser, R.M. Mahfouz, K. Roessler, Emission of organic products from the surface of frozen methane under MeV ion irradiation, Nucl. Instr. Meth. B 65, 468-471  (1992).   (PDF)

1.    R.I. Kaiser, Chemische Prozesse durch Zyklotronionen in festem Methan - Simulation der Wechselwirkung kosmischer Strahlung mit einfachen extraterrestrischen Eiskoerpern, Report-Juel-2492, 130pp  (1991).

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